Recent applications of Cp2TiCl in natural product synthesis

Umpolung of Hemiaminals: Titanocene-Catalyzed Dehydroxylative Radical Coupling Reactions with Activated Alkenes

(2013) Xiao Zheng et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Convenient Titanium(III)-Catalyzed Synthesis of Cyclic Aminoketones and Pyrrolidinones-Development of a Formal [4+1] Cycloaddition

(2013) Georg Frey et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

I2–PPh3 mediated spiroannulation of unsaturated β-dicarbonyl compounds. The first synthesis of (±)-negundoin A

(2013) Rubén Tapia et al.   CHEMICAL COMMUNICATIONS

Titanocene(III)-Catalyzed 6-exoVersus 7-endoCyclizations of Epoxypolyprenes: Efficient Control and Synthesis of Versatile Terpenic Building Blocks

(2013) José Justicia et al.   CHEMISTRY-A EUROPEAN JOURNAL

Structural Diversity from the Transannular Cyclizations of Natural Germacrone and Epoxy Derivatives: A Theoretical-Experimental Study

(2013) M. Carmen Pérez Morales et al.   CHEMISTRY-A EUROPEAN JOURNAL

Total Synthesis of Entecavir

(2013) Javier Velasco et al.   JOURNAL OF ORGANIC CHEMISTRY

Synthesis of the BCDE Molecular Fragment of Azadiradione Mediated by Titanocene(III)

(2013) A. Fernández-Mateos et al.   JOURNAL OF ORGANIC CHEMISTRY

A Unified Strategy to ent-Kauranoid Natural Products: Total Syntheses of (−)-Trichorabdal A and (−)-Longikaurin E

(2013) John T. S. Yeoman et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

First total synthesis of (+)-apotrisporin E and (+)-apotrientriols A–B: a cyclization approach to apocarotenoids

(2013) José A. González-Delgado et al.   ORGANIC & BIOMOLECULAR CHEMISTRY

The Electron-Way: Metal-Catalyzed Reductive Umpolung Reactions of Saturated and α,β-Unsaturated Carbonyl Derivatives

(2013) Jan Streuff   SYNTHESIS-STUTTGART

Stereoselective synthesis of zoanthenol ABC-ring by radical strategy

(2013) Shuji Yamashita et al.   TETRAHEDRON LETTERS

Ti(iii)-mediated radical cyclization of epoxy-β-aminoacrylate in the synthesis of the substituted pyrrolidine core of necine bases: synthesis of 2-epi-rosmarinecine

(2013) Sandip Basu et al.   RSC Advances

Enantioselective Titanium(III)-Catalyzed Reductive Cyclization of Ketonitriles

(2012) Jan Streuff et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Combining the Power of TiIII-Mediated Processes for Easy Access to Hydroxylated Polycyclic Terpenoids: Synthesis of Sesterstatin 1 and C-D Rings of Aspergilloxide

(2012) Tania Jiménez et al.   CHEMISTRY-A EUROPEAN JOURNAL

New Advances in Titanium-Mediated Free Radical Reactions

(2012) Bianca Rossi et al.   MOLECULES

Synthesis of CDE molecular fragments related to sendanin mediated by titanocene(iii)

(2012) A. Fernández-Mateos et al.   ORGANIC & BIOMOLECULAR CHEMISTRY

Synthesis of C-Glycoside Analogues of α-Galactosylceramide via Linear Allylic C–H Oxidation and Allyl Cyanate to Isocyanate Rearrangement

(2012) Zheng Liu et al.   ORGANIC LETTERS

Water Control over the Chemoselectivity of a Ti/Ni Multimetallic System: Heck- or Reductive-Type Cyclization Reactions of Alkyl Iodides

(2012) Alba Millán et al.   ORGANIC LETTERS

Adding Aliphatic C-H Bond Oxidations to Synthesis

(2012) M. C. White   SCIENCE

Titanocene-promoted stereoselective eliminations on epoxy alcohols derived from R-(−)-carvone

(2012) A. Fernández-Mateos et al.   TETRAHEDRON

Titanocene(III) chloride mediated formal synthesis of magnofargesin and 7′-epimagnofargesin

(2012) Pushkin Chakraborty et al.   TETRAHEDRON LETTERS

Evaluation of ‘east-to-west’ ether-forming strategies for the total synthesis of maoecrystal V

(2012) Kiel E. Lazarski et al.   TETRAHEDRON LETTERS

Ti(iii)-Catalyzed, concise synthesis of marine furanospongian diterpenes

(2012) Antonio Rosales et al.   RSC Advances

If CH Bonds Could Talk: Selective CH Bond Oxidation

(2011) Timothy Newhouse et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Ti/Pd-promoted intramolecular Michael-type addition of allylic carboxylates to activated alkenes

(2011) Alba Millán et al.   CHEMICAL COMMUNICATIONS

Bioinspired terpene synthesis: a radical approach

(2011) José Justicia et al.   CHEMICAL SOCIETY REVIEWS

Ti/Pd Bimetallic Systems for the Efficient Allylation of Carbonyl Compounds and Homocoupling Reactions

(2011) Alba Millán et al.   CHEMISTRY-A EUROPEAN JOURNAL

Total Synthesis of (+)-seco-C-Oleanane via Stepwise Controlled Radical Cascade Cyclization

(2011) Victoriano Domingo et al.   JOURNAL OF ORGANIC CHEMISTRY

Protecting-Group-Free Synthesis of Chokols

(2011) Carmen Pérez Morales et al.   JOURNAL OF ORGANIC CHEMISTRY

Titanocene(III) Chloride Mediated Radical Induced Allylation of Aldimines: Formal Synthesis of C-Linked 4′-Deoxy Aza-disaccharide

(2011) Sumit Saha et al.   JOURNAL OF ORGANIC CHEMISTRY

A Concise Total Synthesis of (−)-Maoecrystal Z

(2011) Jacob Y. Cha et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Diverting non-haem iron catalysed aliphatic C–H hydroxylations towards desaturations

(2011) Marinus A. Bigi et al.   Nature Chemistry

Total Synthesis of (±)-Platencin

(2011) Takehiko Yoshimitsu et al.   ORGANIC LETTERS

Total synthesis of pyripyropene A

(2011) Atsuki Odani et al.   TETRAHEDRON

Radical reactions on pinene-oxide derivatives induced by Ti(III)

(2011) A. Fernández-Mateos et al.   TETRAHEDRON

Synthesis of polycyclic ?-lactams. Evolution of tertiary radicals generated by Cp2TiCl from 1,5- and 1,6-epoxynitriles

(2011) Laura M. Monlen et al.   TETRAHEDRON

Ti(III)-mediated opening of 2,3-epoxy alcohols to build five-membered carbocycles with multiple chiral centres

(2011) Midde Sreekanth et al.   TETRAHEDRON LETTERS

Titanocene(III) chloride mediated radical induced asymmetric synthesis of α-methylene bis-γ-butyrolactone

(2011) Sumit Saha et al.   TETRAHEDRON LETTERS

Titanium/Palladium-Mediated Regioselective Propargylation of Ketones using Propargylic Carbonates as Pronucleophiles

(2010) Alba Millán et al.   ADVANCED SYNTHESIS & CATALYSIS

Synthesis of (±)-Merrilactone A and (±)-Anislactone A

(2010) Lei Shi et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Unprecedented H-atom transfer from water to ketyl radicals mediated by Cp2TiCl

(2010) Miguel Paradas et al.   DALTON TRANSACTIONS

Asymmetric Synthesis and in vivo Biological Inactivity of the Right-Hand Terpenoid Fragment of Terpendole E

(2010) Masato Oikawa et al.   EUROPEAN JOURNAL OF ORGANIC CHEMISTRY

Radical Reduction of Epoxides Using a Titanocene(III)/Water System: Synthesis of β-Deuterated Alcohols and Their Use as Internal Standards in Food Analysis

(2010) Tania Jiménez et al.   EUROPEAN JOURNAL OF ORGANIC CHEMISTRY

Understanding the Exceptional Hydrogen-Atom Donor Characteristics of Water in TiIII-Mediated Free-Radical Chemistry

(2010) Miguel Paradas et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Synthesis of Microcin SF608 through Nucleophilic Opening of an Oxabicyclo[2.2.1]heptane

(2010) Stefan Diethelm et al.   ORGANIC LETTERS

Combined Effects on Selectivity in Fe-Catalyzed Methylene Oxidation

(2010) M. S. Chen et al.   SCIENCE

Titanocene (III) chloride mediated radical induced synthesis of (−)-methylenolactocin and (−)-protolichesterinic acid

(2010) Sumit Saha et al.   TETRAHEDRON

Strain Release in CH Bond Activation?

(2009) Ke Chen et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

4-exoCyclizations by Template Catalysis

(2009) Andreas Gansäuer et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Ti-Catalyzed Barbier-Type Allylations and Related Reactions

(2009) Rosa E. Estévez et al.   CHEMISTRY-A EUROPEAN JOURNAL

Enantioselective Total Synthesis of the Potent Anti-inflammatory (+)-Myrrhanol A

(2009) Victoriano Domingo et al.   JOURNAL OF ORGANIC CHEMISTRY

Unexpected TiIII/Mn-Promoted Pinacol Coupling of Ketones

(2009) Miguel Paradas et al.   JOURNAL OF ORGANIC CHEMISTRY

Weakening C−O Bonds: Ti(III), a New Reagent for Alcohol Deoxygenation and Carbonyl Coupling Olefination

(2009) Horacio R. Diéguez et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Titanocene-Catalyzed Conjugate Reduction of α,β-Unsaturated Carbonyl Derivatives

(2009) Andrew D. Kosal et al.   ORGANIC LETTERS

Mixed disproportionation versus radical trapping in titanocene(III)-promoted epoxide openings

(2009) José Justicia et al.   TETRAHEDRON

Formal total synthesis of (±)-fragranol via template catalyzed 4-exo cyclization

(2009) Andreas Gansäuer et al.   TETRAHEDRON

Total synthesis of fomitellic acid B

(2009) Makoto Yamaoka et al.   TETRAHEDRON LETTERS

Titanium-Catalyzed Enantioselective Synthesis of α-Ambrinol

(2008) José Justicia et al.   ADVANCED SYNTHESIS & CATALYSIS

Divergent Titanium-Mediated Allylations with Modulation by Nickel or Palladium

(2008) Araceli G. Campaña et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Ti-Catalyzed Reformatsky-Type Coupling between α-Halo Ketones and Aldehydes

(2008) Rosa E. Estévez et al.   JOURNAL OF ORGANIC CHEMISTRY

First Total Synthesis of (−)-Achilleol B: Reassignment of Its Relative Stereochemistry

(2008) Jesús F. Arteaga et al.   ORGANIC LETTERS

Stereoselective Synthesis of Branched Cyclopentitols by Titanium(III)-Promoted Reductive Cyclization of 4-Oxiranylaldehydes and 4-Oxiranyl Ketones Derived from Hexoses

(2008) Jose Chiara et al.   SYNTHESIS-STUTTGART

Ti-catalyzed transannular cyclization of epoxygermacrolides. Synthesis of antifungal (+)-tuberiferine and (+)-dehydrobrachylaenolide

(2008) José Justicia et al.   TETRAHEDRON

Titanocene catalyzed opening of oxetanes

(2008) Andreas Gansäuer et al.   TETRAHEDRON

Titanocene(III) chloride mediated radical-induced synthesis of 3,4-dihydroisocoumarins: synthesis of (±)-hydrangenol, (±)-phyllodulcin, (±)-macrophyllol and (±)-thunberginol G

(2008) Samir Kumar Mandal et al.   TETRAHEDRON

Titanium(III)-induced intramolecular radical cyclization of epoxyallene ethers: an efficient method for synthesis of multifunctional tetrahydrofurans

(2007) Lubin Xu et al.   TETRAHEDRON LETTERS