期刊
ORGANIC LETTERS
卷 14, 期 23, 页码 5984-5987出版社
AMER CHEMICAL SOC
DOI: 10.1021/ol3028913
关键词
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资金
- MICINN [CTQ-2011.22455]
- Regional Government of Andalucia
A versatile Ti/Ni multimetallic protocol is described for the efficient catalysis of two different reactions, namely a Heck- and reductive-type cyclization of alkyl iodides, in the absence or presence of water, respectively. Noteworthy, the versatility of Ti(III) chemistry allows an oxidative ending step under reductive conditions to give Heck-type products, and the good H-atom transfer capabilities of Ti(III)-aqua complexes ensure reductive-type cyclizations.
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