Article
Chemistry, Multidisciplinary
Yi-Ran Yao, Ya-Jun Jin, Xin Jia, Yang Yang
Summary: The porous nano-sized metal-organic framework, with proper surface modification, enhances drug loading capability and introduces biocompatibility, biodegradability, and targeting functions in nano-drug delivery systems. The obtained nanoMOF nanoparticle is stable in physiological fluids and can effectively load chemotherapeutic drugs for controlled release in tumor tissues.
CHEMISTRY-A EUROPEAN JOURNAL
(2021)
Article
Chemistry, Physical
Pierre Tignol, Vanessa Pimenta, Anne-Laurence Dupont, Silvia Carvalho, Abeer Al Mohtar, Maria Ines Severino, Farid Nouar, Moises L. Pinto, Christian Serre, Bertrand Lavedrine
Summary: Porous solids are of great interest in various fields. However, they are usually synthesized as powders and need to be shaped without altering their intrinsic properties. This study reports a new method using softwood bleached kraft pulp fibers and nano-fibrillated cellulose to produce high loading porous solids paper sheets. The composite exhibits good porosity and mechanical strength, making it suitable for applications such as air purification.
Article
Chemistry, Physical
Xinbo Wang, Li Li, Kai Li, Ruyue Su, Yue Zhao, Song Gao, Wenhan Guo, Zhiqiang Luan, Guojie Liang, Hailing Xi, Ruqiang Zou
Summary: The hierarchically porous metal hydroxide/metal-organic framework composite nanoarchitectures show broad-spectrum removal activity for three chemically distinct toxic gases. The inclusion of M(OH)4 enhances the material's ability for toxic chemical mitigation, with high breakthrough uptake for SO2, NH3, and NO2. Post-breakthrough characterization reveals abundant M-OH groups and unsaturated M (IV) centers, providing extra adsorption sites for irreversible toxic chemical capture.
JOURNAL OF COLLOID AND INTERFACE SCIENCE
(2022)
Article
Polymer Science
Kiyoshi Matsuyama, Yuka Kawahara, Ayano Shoji, Takafumi Kato, Tetsuya Okuyama
Summary: Metal-organic frameworks (MOFs) are used as efficient adsorbents for the removal of hazardous materials. Cu-3(BTC)(2)-loaded microporous polystyrene membranes are prepared via phase separation using supercritical CO2. After activation with scCO2, Cu-3(BTC)(2) has increased internal surface area and improved MB adsorption. The prepared membranes can effectively remove MB from aqueous solutions with a removal efficiency of 92.8%.
JOURNAL OF APPLIED POLYMER SCIENCE
(2023)
Article
Chemistry, Inorganic & Nuclear
Zi-Ming Ye, Kai-Ping Xie, Chao Wang, Xue-Wen Zhang, Hao-Long Zhou, Jie-Peng Zhang
Summary: The solvothermal reaction yielded a porous coordination polymer with a fence-like coordination framework and remarkable thermal expansion properties, which were significantly enhanced by inclusion of toluene.
INORGANIC CHEMISTRY
(2021)
Editorial Material
Chemistry, Physical
Satoshi Horike, Susumu Kitagawa
Summary: Metal-organic frameworks, composed of metal ions and organic molecules, have developed into an innovative chemistry that offers solutions to the challenges in environment, resources, energy, and health faced by humanity in the past 20 years.
Article
Multidisciplinary Sciences
Yan Su, Ken-ichi Otake, Jia-Jia Zheng, Satoshi Horike, Susumu Kitagawa, Cheng Gu
Summary: Efficient separation of water isotopologues at room temperature has been achieved by constructing porous coordination polymers with flip-flop molecular motions to regulate the diffusion rates of water isotopologues. This method shows promise for high-performance vapor separation.
Review
Chemistry, Multidisciplinary
Hannah F. Drake, Gregory S. Day, Zhifeng Xiao, Hong-Cai Zhou, Matthew R. Ryder
Summary: Efficient capture and release of gas molecules remains a challenge in porous materials, with research focusing on advances such as photoresponsive organic units for light-induced switchable adsorption. The use of light to trigger structural or electronic changes to alter gas uptake and working capacity is a relatively recent but significant development in controlling gas storage performance.
TRENDS IN CHEMISTRY
(2022)
Article
Engineering, Environmental
Elizabeth G. Rasmussen, John Kramlich, Igor Novosselov
Summary: This study presents a rapid synthesis of high-quality copper-based MOFs in a continuous flow supercritical carbon dioxide reactor, evaluating the effects of different conditions on the properties of MOFs. The experiments demonstrated that high-quality MOFs can be obtained with a residence time in the range of 70-170 seconds using scCO(2) assisted synthesis.
CHEMICAL ENGINEERING JOURNAL
(2022)
Article
Chemistry, Physical
Huijie Zheng, Yawei Chen, Jiajia Yang, Peiyan Hao, Lijun Ren, Huiyun Zhou
Summary: A hierarchically porous ZIF-8 (HZIF-8) with pH-responsive and antibacterial activity was constructed using bicomponent hydrogel as a template. The synthesized HZIF-8 was applied to load the antibacterial drug berberine hydrochloride (BBH). In vitro release studies showed that BBH@ZIF-8 and BBH@HZIF-8 displayed sustained drug release profiles, and the drug release rate increased with decreasing pH value.
JOURNAL OF MOLECULAR STRUCTURE
(2023)
Article
Multidisciplinary Sciences
Simon Krause, Jack D. Evans, Volodymyr Bon, Stefano Crespi, Wojciech Danowski, Wesley R. Browne, Sebastian Ehrling, Francesco Walenszus, Dirk Wallacher, Nico Grimm, Daniel M. Tobbens, Manfred S. Weiss, Stefan Kaskel, Ben L. Feringa
Summary: The study explores the application of photoswitches as light-responsive triggers for phase transitions of porous materials. By incorporating an azobenzene photoswitch in the backbone of a metal-organic framework, the researchers achieve light-induced structural contraction and gas adsorption control in the porous network. The complex mechanism of light-gated breathing is established, revealing a novel light-induced deformation mechanism of constrained azobenzene photoswitches.
NATURE COMMUNICATIONS
(2022)
Article
Chemistry, Multidisciplinary
Li-Li Ling, Long Jiao, Xiaoshuo Liu, Yun Dong, Weijie Yang, Hongjun Zhang, Bangjiao Ye, Jun Chen, Hai-Long Jiang
Summary: A K+-assisted synthetic strategy is developed to fabricate porous carbon with abundant intrinsic defects and complete elimination of heteroatom via direct pyrolysis of K+-confined metal-organic frameworks. The resulted carbon material exhibits ultrahigh CO Faradaic efficiency in CO2 electroreduction, which surpasses the performance of MOF-derived carbon. Theoretical calculations suggest that the carbon defects in the K-defect-C favor CO2 adsorption and accelerate the rate-determining COOH* intermediate formation.
ADVANCED MATERIALS
(2022)
Article
Chemistry, Multidisciplinary
Aeri J. Gosselin, Alexandra M. Antonio, Kyle J. Korman, Meaghan M. Deegan, Glenn P. A. Yap, Eric D. Bloch
Summary: A large library of novel porous salts based on charged coordination cages was synthesized through straightforward salt metathesis reactions, allowing for highly tunable metal identity, pore size, ligand functional groups, and surface area. The design principles outlined are expected to be widely applicable for the synthesis of new porous salts based on a variety of charged porous molecular precursors.
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
(2021)
Review
Chemistry, Inorganic & Nuclear
Xiao Feng, Yanwei Ren, Huanfeng Jiang
Summary: The article reviews the recent research progress of M(bpy)/M(phen)-functionalized metal-organic frameworks (MOFs) and covalent organic frameworks (COFs), focusing on the synthetic strategies of these porous materials and their catalytic performances in thermocatalysis, photocatalysis and electrocatalysis.
COORDINATION CHEMISTRY REVIEWS
(2021)
Article
Chemistry, Multidisciplinary
Yao Fu, Zhengzhong Kang, Weicheng Cao, Jinglin Yin, Yaoquan Tu, Jianhua Li, Hanxi Guan, Yiran Wang, Qi Wang, Xueqian Kong
Summary: Understanding drug-carrier interactions in metal-organic frameworks (MOFs) is crucial for designing drug-delivery systems. This study found that defects in MOFs play a key role in loading pharmaceuticals with phosphate or phosphonate groups, enhancing capacity due to Coulombic attraction. Solid-state NMR spectroscopy and molecular simulations were used to elucidate the mechanisms of drug-carrier interactions at defects.
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION
(2021)
Article
Chemistry, Physical
Kiyoshi Matsuyama, Yu-ki Maeda, Takaaki Matsuda, Tetsuya Okuyama, Hiroyuki Muto
JOURNAL OF SUPERCRITICAL FLUIDS
(2015)
Article
Chemistry, Applied
Kiyoshi Matsuyama, Momoe Motomura, Takafumi Kato, Tetsuya Okuyama, Hiroyuki Muto
MICROPOROUS AND MESOPOROUS MATERIALS
(2016)
Article
Agronomy
Koichiro Tanamachi, Masayuki Miyazaki, Kazuhiro Matsuo, Chetphilin Suriyasak, Aina Tamada, Kiyoshi Matsuyama, Mari Iwaya-Inoue, Yushi Ishibashi
PLANT PRODUCTION SCIENCE
(2016)
Article
Chemistry, Physical
Kiyoshi Matsuyama, Shota Tanaka, Takafumi Kato, Tetsuya Okuyama, Hiroyuki Muto, Riichi Miyamoto, Hong-zhi Bai
JOURNAL OF SUPERCRITICAL FLUIDS
(2017)
Article
Chemistry, Physical
Kiyoshi Matsuyama
JOURNAL OF SUPERCRITICAL FLUIDS
(2018)
Article
Engineering, Environmental
Kiyoshi Matsuyama, Satoshi Tanaka, Tetsuya Okuyama
CHEMICAL ENGINEERING JOURNAL
(2014)
Article
Chemistry, Physical
Kiyoshi Matsuyama, Kenji Mishima, Takafumi Kato, Keiichi Irie, Kenichi Mishima
JOURNAL OF COLLOID AND INTERFACE SCIENCE
(2012)
Article
Chemistry, Physical
Kiyoshi Matsuyama, Neil Ihsan, Keiichi Irie, Kenichi Mishima, Tetsuya Okuyama, Hiroyuki Muto
JOURNAL OF COLLOID AND INTERFACE SCIENCE
(2013)
Article
Multidisciplinary Sciences
Sei Higuchi, Keiichi Irie, Ryuji Yamaguchi, Mai Katsuki, Maiko Araki, Makiko Ohji, Kazuhide Hayakawa, Shohei Mishima, Yoshiharu Akitake, Kiyoshi Matsuyama, Kenji Mishima, Kenichi Mishima, Katsunori Iwasaki, Michihiro Fujiwara
Article
Chemistry, Multidisciplinary
Kenji Mishima, Ryo Kawakami, Haruo Yokota, Takunori Harada, Takafumi Kato, Keiichi Irie, Kenichi Mishima, Michihiro Fujiwara, Kiyoshi Matsuyama, Salim Mustofa, Agus Salim
SOLVENT EXTRACTION RESEARCH AND DEVELOPMENT-JAPAN
(2013)
Article
Chemistry, Multidisciplinary
Kenji Mishima, Ryo Kawakami, Haruo Yokota, Takunori Harada, Takafumi Kato, Hirofumi Kawamura, Kiyoshi Matsuyama, Salim Mustofa, Fauziyah Hasanah, Yusraini Dian Inayati Siregar, Lily Surayya Eka Putri, Agus Salim
SOLVENT EXTRACTION RESEARCH AND DEVELOPMENT-JAPAN
(2014)
Article
Chemistry, Physical
Kiyoshi Matsuyama, Kanae Morotomi, Sakura Inoue, Megumi Nakashima, Hiroyuki Nakashima, Tetsuya Okuyama, Takafumi Kato, Hiroyuki Muto, Hiroyuki Sugiyama
JOURNAL OF SUPERCRITICAL FLUIDS
(2019)
Article
Materials Science, Multidisciplinary
Kiyoshi Matsuyama, Tomohiro Tsubaki, Takafumi Kato, Tetsuya Okuyama, Hiroyuki Muto
Article
Polymer Science
Kiyoshi Matsuyama, Yuka Kawahara, Ayano Shoji, Takafumi Kato, Tetsuya Okuyama
Summary: Metal-organic frameworks (MOFs) are used as efficient adsorbents for the removal of hazardous materials. Cu-3(BTC)(2)-loaded microporous polystyrene membranes are prepared via phase separation using supercritical CO2. After activation with scCO2, Cu-3(BTC)(2) has increased internal surface area and improved MB adsorption. The prepared membranes can effectively remove MB from aqueous solutions with a removal efficiency of 92.8%.
JOURNAL OF APPLIED POLYMER SCIENCE
(2023)
Article
Materials Science, Biomaterials
Izabela Stupka, Artur P. Biela, Bernard Piette, Agnieszka Kowalczyk, Karolina Majsterkiewicz, Kinga Borzecka-Solarz, Antonina Naskalska, Jonathan G. Heddle
Summary: Artificial protein cages, such as TRAP-cages, have potential applications in vaccines and drug delivery. TRAP-cages have the ability to control the disassembly conditions by modifying the interface between their building blocks. By using TRAP rings with different numbers of monomers, it is possible to predict the formation of other cages.
JOURNAL OF MATERIALS CHEMISTRY B
(2024)
Article
Materials Science, Biomaterials
Guo Zhang, Yu Wang, Hua Qiu, Lei Lu
Summary: This study presents a one-pot synthesis method for flower-like AMPs@EAMP particles by combining antimicrobial peptides with ellagic acid, offering enlarged surface area, excellent biocompatibility, and broad-spectrum antibacterial activity. In vivo studies indicate their potential for tissue repair and immune barrier reconstruction.
JOURNAL OF MATERIALS CHEMISTRY B
(2024)
Article
Materials Science, Biomaterials
Jiamei Zhang, Lingshuang Wang, Cheng Xu, Yingui Cao, Shengsheng Liu, Rui L. Reis, Subhas C. Kundu, Xiao Yang, Bo Xiao, Lian Duan
Summary: Pluronic F127 modified silk fibroin film with different types of antibacterial agents could accelerate wound recovery by promoting fibroblast adhesion, eradicating bacteria, and facilitating angiogenesis and re-epithelialization.
JOURNAL OF MATERIALS CHEMISTRY B
(2024)
Article
Materials Science, Biomaterials
Yinsheng Liu, Mingyue Wang, Yinfei Hui, Lei Sun, Yanrui Hao, Henlong Ren, Hao Guo, Wu Yang
Summary: In this study, a rare-earth hybrid luminescent material was developed for the detection of a biomarker for anthrax. The material showed excellent selectivity and high sensitivity, allowing for the determination of the biomarker in saliva and urine. Additionally, a convenient point-of-care testing method using fluorescent test paper and a smartphone was established for the initial diagnosis of anthrax.
JOURNAL OF MATERIALS CHEMISTRY B
(2024)
Review
Materials Science, Biomaterials
Wenshuai Yang, Jingsi Chen, Ziqian Zhao, Meng Wu, Lu Gong, Yimei Sun, Charley Huang, Bin Yan, Hongbo Zeng
Summary: Injectable hydrogels with shear-thinning and/or in situ formation properties offer distinct advantages in bioengineering applications, as they can be directly delivered to target sites, possess self-healing abilities, and simplify the implantation process.
JOURNAL OF MATERIALS CHEMISTRY B
(2024)
