A robust protocol for Pd(ii)-catalyzed C-3 arylation of (1H) indazoles and pyrazoles: total synthesis of nigellidine hydrobromide

CH Bond Functionalization: Emerging Synthetic Tools for Natural Products and Pharmaceuticals

(2012) Junichiro Yamaguchi et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Regioselective zincation of indazoles using TMP2Zn and Negishi cross-coupling with aryl and heteroaryl iodides

(2012) Andreas Unsinn et al.   CHEMICAL COMMUNICATIONS

Direct C-3-Arylations of 1H-Indazoles

(2012) Ali Ben-Yahia et al.   EUROPEAN JOURNAL OF ORGANIC CHEMISTRY

Transition-State Metal Aryl Bond Stability Determines Regioselectivity in Palladium Acetate Mediated C–H Bond Activation of Heteroarenes

(2012) Alban Petit et al.   ORGANIC LETTERS

Pd- and Cu-catalyzed C–H arylation of indazoles

(2012) Keika Hattori et al.   TETRAHEDRON

Direct Arylation of Simple Azoles Catalyzed by 1,10-Phenanthroline Containing Palladium Complexes: An Investigation of C4 Arylation of Azoles and the Synthesis of Triarylated Azoles by Sequential Arylation

(2011) Fumitoshi Shibahara et al.   JOURNAL OF ORGANIC CHEMISTRY

Synthesis of Dragmacidin D via Direct C–H Couplings

(2011) Debashis Mandal et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Ligand-Promoted C-3 Selective C–H Olefination of Pyridines with Pd Catalysts

(2011) Mengchun Ye et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Highly Convergent Total Synthesis of (+)-Lithospermic Acid via a Late-Stage Intermolecular C−H Olefination

(2011) Dong-Hui Wang et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Ligand-Promoted C3-Selective Arylation of Pyridines with Pd Catalysts: Gram-Scale Synthesis of (±)-Preclamol

(2011) Mengchun Ye et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Divergent C–H Functionalizations Directed by Sulfonamide Pharmacophores: Late-Stage Diversification as a Tool for Drug Discovery

(2011) Hui-Xiong Dai et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Exploitation of an additional hydrophobic pocket of σ1 receptors: Late-stage diverse modifications of spirocyclic thiophenes by C–H bond functionalization

(2011) Christina Meyer et al.   ORGANIC & BIOMOLECULAR CHEMISTRY

Regioselective Palladium-Catalyzed Arylation of 4-Chloropyrazoles

(2010) Carlos Mateos et al.   ORGANIC LETTERS

Transition-Metal-Catalyzed Direct Arylation of (Hetero)Arenes by CH Bond Cleavage

(2009) Lutz Ackermann et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

New and selective ryanodine receptor activators for insect control

(2009) George P. Lahm et al.   BIOORGANIC & MEDICINAL CHEMISTRY

Palladium-Catalyzed C3 or C4 Direct Arylation of Heteroaromatic Compounds with Aryl Halides by CH Bond Activation

(2009) Julien Roger et al.   ChemCatChem

Recent advances in aryl–aryl bond formation by direct arylation

(2009) Gerard P. McGlacken et al.   CHEMICAL SOCIETY REVIEWS

Efficient Routes to Pyrazolo[3,4-b]indoles and Pyrazolo[1,5-a]benzimidazoles via Palladium- and Copper-Catalyzed Intramolecular C−C and C−N Bond Formation†

(2009) Sarvesh Kumar et al.   JOURNAL OF ORGANIC CHEMISTRY

Total Synthesis of (±)-Rhazinal Using Novel Palladium-Catalyzed Cyclizations

(2009) Alfred L. Bowie et al.   JOURNAL OF ORGANIC CHEMISTRY

C−H Bonds as Ubiquitous Functionality: A General Approach to Complex Arylated Pyrazoles via Sequential RegioselectiveC-Arylation andN-Alkylation Enabled by SEM-Group Transposition

(2009) Roman Goikhman et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Direct Arylations of 2H-Indazoles On Water

(2009) Stephan A. Ohnmacht et al.   ORGANIC LETTERS

Recent advances in the synthesis of (hetero)aryl-substituted heteroarenes via transition metal-catalysed direct (hetero)arylation of heteroarene C–H bonds with aryl halides or pseudohalides, diaryliodonium salts, and potassium aryltrifluoroborates

(2009) Fabio Bellina et al.   TETRAHEDRON

Direct Functionalization of Nitrogen Heterocycles via Rh-Catalyzed C−H Bond Activation

(2008) Jared C. Lewis et al.   ACCOUNTS OF CHEMICAL RESEARCH

Synthesis of Rhazinicine by a Metal-Catalyzed CH Bond Functionalization Strategy

(2008) Elizabeth M. Beck et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Synthesis of Annulated 2H-Indazoles and 1,2,3- and 1,2,4-Triazoles via a One-Pot Palladium-Catalyzed Alkylation/Direct Arylation Reaction

(2008) Benoît Laleu et al.   JOURNAL OF ORGANIC CHEMISTRY

Synthesis and antiplatelet activity of ethyl 4-(1-benzyl-1H-indazol-3-yl)benzoate (YD-3) derivatives

(2007) Hua-Sin Chen et al.   BIOORGANIC & MEDICINAL CHEMISTRY