期刊
ORGANIC LETTERS
卷 12, 期 22, 页码 5206-5209出版社
AMER CHEMICAL SOC
DOI: 10.1021/ol102220e
关键词
-
资金
- Deutsche Forschungsgemeinschaft [SFB 749]
- A. v. Humboldt Foundation
Kinetics of the reactions of allylsilanes (1) and silyl enol ethers (2) with benzhydrylium ions (3) were studied by UV-vis spectroscopy in dichloromethane at 20 degrees C. The less than three times higher reaction rates of the tris(trimethylsilyl)silyl compounds in comparison to the corresponding trimethylsilyl compounds indicate that the previously reported strong electron-donating effect of the supersilyl group operates only in the a-position and not in the if-position.
作者
我是这篇论文的作者
点击您的名字以认领此论文并将其添加到您的个人资料中。
推荐
暂无数据