Cooperativity between steric repulsion and crossed diene coordination governs the enantioselectivity in rhodium(i)/chiral, 1,4- and 1,5-diene-catalysed 1,4-addition reaction: a DFT study

Chiral bicyclic [2.2.2] octadiene ligands for Rh-catalysed catalytic asymmetric conjugate additions to acyclic enones: a quantitative structure–property relationship

(2012) Yunfei Luo et al.   CHEMICAL COMMUNICATIONS

Expanding the C1-Symmetric Bicyclo[2.2.1]heptadiene Ligand Family: Highly Enantioselective Synthesis of Cyclic β-Aryl-Substituted Carbonyl Compounds

(2012) Chia-Chen Liu et al.   EUROPEAN JOURNAL OF ORGANIC CHEMISTRY

Rhodium/diene-catalyzed tandem 1,4-shift/1,4-addition of (E)-1,2-diphenylethenylboronic acid to enones: density functional theory modeling and asymmetric catalysis

(2012) Keigo Sasaki et al.   Chemical Science

Synthesis of Chiral Olefin Ligands and their Application in Asymmetric Catalysis

(2012) Xiangqing Feng et al.   Asian Journal of Organic Chemistry

The origin of regio- and enantioselectivity in the Rh/chiral 1,4-diene-catalyzed addition of phenylboronic acid to enones: insights from DFT

(2011) Eric Assen B. Kantchev   CHEMICAL COMMUNICATIONS

The Origins of Enantioselectivity in Rh-Diene Complex Catalysed Arylation of Cyclohex-2-enones

(2011) Silvia Gosiewska et al.   CHEMISTRY-A EUROPEAN JOURNAL

Highly Enantioselective Rhodium-Catalyzed Asymmetric 1,4-Addition Reactions of Arylboronic Acids to Acyclic α,β-Unsaturated Compounds: The Formal Synthesis of (−)-Indatraline

(2011) Wei-Ting Wei et al.   CHEMISTRY-A EUROPEAN JOURNAL

Mechanism of the Palladium-Catalyzed Addition of Arylboronic Acids to Enones: A Computational Study

(2011) Yu Lan et al.   JOURNAL OF ORGANIC CHEMISTRY

Readily Accessible Chiral Diene Ligands for Rh-Catalyzed Enantioselective Conjugate Additions of Boronic Acids

(2011) Barry M. Trost et al.   ORGANIC LETTERS

Density Functional Theory Study on the Mechanism of Rh-Catalyzed Decarboxylative Conjugate Addition: Diffusion- and Ligand-Controlled Selectivity toward Hydrolysis or β-Hydride Elimination

(2011) Fu-Qiang Shi   ORGANIC LETTERS

α,β-Divinyl Tetrahydropyrroles as Chiral Chain Diene Ligands in Rhodium(I)-Catalyzed Enantioselective Conjugated Additions

(2011) Qian Li et al.   ORGANIC LETTERS

Rhodium-Catalyzed Asymmetric Arylation

(2011) Ping Tian et al.   ACS Catalysis

One Step Synthesis of Chiral OlefinsviaAsymmetric Diamination and their Applications as Ligands for Rhodium(I)-Catalyzed 1,4-Additions

(2010) Xichao Hu et al.   ADVANCED SYNTHESIS & CATALYSIS

Chemoenzymatic Synthesis and Application of Bicyclo[2.2.2]octadiene Ligands: Increased Efficiency in Rhodium-Catalyzed Asymmetric Conjugate Additions by Electronic Tuning

(2010) Yunfei Luo et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Synthetic applications of rhodium catalysed conjugate addition

(2010) Hannah J. Edwards et al.   CHEMICAL SOCIETY REVIEWS

C2-Symmetric Chiral Disulfoxide Ligands in Rhodium-Catalyzed 1,4-Addition: From Ligand Synthesis to the Enantioselection Pathway

(2010) Ronaldo Mariz et al.   CHEMISTRY-A EUROPEAN JOURNAL

Comparing the Enantioselective Power of Steric and Electrostatic Effects in Transition-Metal-Catalyzed Asymmetric Synthesis

(2010) Albert Poater et al.   CHEMISTRY-A EUROPEAN JOURNAL

Rhodium(I) mediated arylation of aldehydes with arylboronic acids under base and water free conditions: A computational study☆

(2010) Alma Itzel Olivos Suarez et al.   JOURNAL OF MOLECULAR CATALYSIS A-CHEMICAL

Enantioselective Rhodium-Catalyzed Addition of Arylboronic Acids to Alkenylheteroarenes

(2010) Graham Pattison et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Development of Binaphthyl-Based Chiral Dienes for Rhodium(I)-Catalyzed Asymmetric Arylation ofN,N-Dimethylsulfamoyl-Protected Aldimines

(2010) Ziping Cao et al.   ORGANIC LETTERS

C1-Symmetric Dicyclopentadienes as New Chiral Diene Ligands for Asymmetric Rhodium-Catalyzed Arylation ofN-Tosylarylimines

(2010) Cheng Shao et al.   ORGANIC LETTERS

An N-Linked Bidentate Phosphoramidite Ligand (N-Me-BIPAM) for Rhodium-Catalyzed Asymmetric Addition of Arylboronic Acids to N-Sulfonylarylaldimines

(2009) Kazunori Kurihara et al.   ADVANCED SYNTHESIS & CATALYSIS

Electron-Poor Chiral Diphosphine Ligands: High Performance for Rh-Catalyzed Asymmetric 1,4-Addition of Arylboronic Acids at Room Temperature

(2009) Toshinobu Korenaga et al.   ORGANIC LETTERS

Simple Chiral Chain Dienes as Ligands for Rh(I)-Catalyzed Conjugated Additions

(2009) Xichao Hu et al.   ORGANIC LETTERS

Catalytic Enantioselective Formation of Chiral-Bridged Dienes Which Are Themselves Ligands for Enantioselective Catalysis

(2009) M. Kevin Brown et al.   ORGANIC LETTERS

C1-Symmetric Monosubstituted Chiral Diene Ligands in Asymmetric Rhodium-Catalyzed 1,4-Addition Reactions

(2008) Thomas Gendrineau et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Chiral Olefins as Steering Ligands in Asymmetric Catalysis

(2008) Christian Defieber et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Metal-Catalyzed Reactions of Organoboronic Acids and Esters

(2008) Norio Miyaura   BULLETIN OF THE CHEMICAL SOCIETY OF JAPAN

Chiral Tetrafluorobenzobarrelenes as Highly Efficient Ligands for the Rhodium-catalyzed Asymmetric 1,4-Addition of Arylboronic Acids

(2008) Takahiro Nishimura et al.   CHEMISTRY LETTERS

Easily AccessibleC2-Symmetric Chiral Bicyclo[3.3.0] Dienes as Ligands for Rhodium-Catalyzed Asymmetric 1,4-Addition

(2008) Chen-Guo Feng et al.   Chemistry-An Asian Journal

Tuning the Chiral Environment ofC2-Symmetric Diene Ligands: Development of 3,7-Disubstituted Bicyclo[3.3.1]nona-2,6-dienes

(2008) Ryo Shintani et al.   JOURNAL OF ORGANIC CHEMISTRY

Access to Enantioenriched α-Amino Esters via Rhodium-Catalyzed 1,4-Addition/Enantioselective Protonation

(2008) Laure Navarre et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Computational prediction of small-molecule catalysts

(2008) K. N. Houk et al.   NATURE

Synthesis and rhodium complexation of enantiomerically enriched bicyclo[3.3.1]nona-2,6-diene

(2008) Monika Mayr et al.   TETRAHEDRON-ASYMMETRY

More than Bystanders: The Effect of Olefins on Transition-Metal-Catalyzed Cross-Coupling Reactions

(2007) Jeffrey B. Johnson et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION