Article
Energy & Fuels
Bowen Liu, Xinan Shi, Wei Shao, Jiaxin Gao, Chenxi Zhao, Fuyan Chen, Dongdong Shen, Bingsuo Zou, Daocheng Pan
Summary: A novel and green ionic liquid-assisted ink is developed for the fabrication of highly efficient CIGSSe solar cells by inkjet printing. Compared to the conventional vacuum-based deposition and spin-coating solution methods, inkjet printing technology can remarkably improve the material utilization of copper indium gallium sulfur selenium (CIGS) and achieve a flat and continuous deposition of CIGS thin film. The inkjet-printed CIGSSe solar cells show an encouraging power conversion efficiency of 15.22%.
Article
Materials Science, Multidisciplinary
Shaohong Yang, Wencai Zhou, Jingjing Qu, Linrui Zhang, Xiaoyu Lv, Zilong Zheng, Xiaoqing Chen, Hui Yan, Ming Zhao, Daming Zhuang
Summary: Cu(In,Ga)(Se,S)(2) has distinct advantages as a photovoltaic material, allowing independent tuning of its conduction and valence bands, as well as its composition distribution. Through calculations and simulations, we achieved high-efficiency Cu(In,Ga)(Se,S)(2) solar cells with an efficiency of 23.29%, providing an understanding of tunable engineered band energy research.
Article
Multidisciplinary Sciences
Joo-Hyun Kim, Hyemi Han, Min Kyu Kim, Jongtae Ahn, Do Kyung Hwang, Tae Joo Shin, Byoung Koun Min, Jung Ah Lim
Summary: In this study, a solution-processed near-infrared photodetector based on CIGS was successfully developed, with the incorporation of potassium promoting Se uptake in the film to improve light absorption and charge carrier separation. The addition of potassium also enhanced chalcopyrite crystalline grain growth, increasing charge carrier mobility and ultimately improving photosensitivity and external quantum efficiency of the photodetector.
SCIENTIFIC REPORTS
(2021)
Article
Nanoscience & Nanotechnology
Aubin JC. M. Prot, Michele Melchiorre, Felix Dingwell, Anastasia Zelenina, Hossam Elanzeery, Alberto Lomuscio, Thomas Dalibor, Maxim Guc, Robert Fonoll-Rubio, Victor Izquierdo-Roca, Gunnar Kusch, Rachel A. Oliver, Susanne Siebentritt
Summary: The article discusses the achievement of record efficiency in chalcopyrite-based solar cells using a gallium gradient and reveals non-radiative recombination issues at the back contacts of industrial absorbers. The study proposes a model where discrete bandgap phases interlace to form an apparent gradient throughout the thickness of the absorber.
Review
Chemistry, Physical
Sunil Suresh, David J. Rokke, Amandine A. Drew, Essam Alruqobah, Rakesh Agrawal, Alexander R. Uhl
Summary: This article reviews the extrinsic doping concepts for CIGSSe-type absorbers fabricated by ink-based deposition routes, compares the performance of select high-efficiency ink-based devices, and offers an outlook for future process development. It suggests that the mechanisms of ink-based absorbers are fundamentally different from vacuum-based processes and require further investigation.
ADVANCED ENERGY MATERIALS
(2022)
Review
Chemistry, Physical
Sunil Suresh, Alexander R. Uhl
Summary: Photovoltaic technologies provide a sustainable solution to increasing energy demands, with chalcopyrite thin-film solar cells exhibiting high efficiency but typically fabricated using vacuum deposition methods. Research is shifting towards solution processing techniques to improve material usage, increase throughput, and lower commercialization barriers, but performance of current devices falls short of vacuum-processed counterparts.
ADVANCED ENERGY MATERIALS
(2021)
Article
Energy & Fuels
Ke Cheng, Xingfen Shen, Jingling Liu, Xinsheng Liu, Zuliang Du
Summary: A sequential route for low-cost fabrication of high quality Ag-alloyed CIGS absorbers is reported, where Ag-alloying is introduced into the CuInGa precursor to widen the band gap and improve the crystallinity of the ACIGS absorbers. Different Ag thin layer incorporation locations are schemed for deep understanding the band gap energy and crystallinity regulation mechanism of Ag alloying, leading to a notable improvement in Voc. Finally, the ACIGS absorbers are sulfurized to achieve a highest power conversion efficiency of 13.01%.
Article
Physics, Applied
Abdullah Karaca, Bulent M. Basol, M. Ali Olgar, Temel Buyuklimanli, Murat Tomakin, Tayfur Kucukomeroglu, Emin Bacaksiz
Summary: CIGTS thin films were fabricated using a two-stage technique with different atomic ratios. In the first stage, Cu, In, and Ga layers were deposited on a Mo coated stainless steel foil, forming a precursor structure. In the second stage, the precursor structures were reacted under different conditions to produce CIGTS films.
JOURNAL OF PHYSICS D-APPLIED PHYSICS
(2023)
Article
Nanoscience & Nanotechnology
Van Ben Chu, Daniel Siopa, Alice Debot, Damilola Adeleye, Mohit Sood, Alberto Lomuscio, Michele Melchiorre, Jerome Guillot, Nathalie Valle, Brahime El Adib, Jonathan Rommelfangen, Phillip J. Dale
Summary: Chemical bath methods for growing thin film semiconductors produce a lot of waste solvent and chemicals. This study successfully replaced the toxic chemical bath deposited CdS buffer layer with a benign inkjet-printed and annealed Zn(O,S) layer, greatly reducing solvent and chemical usage. The wetting and final performance of the Zn(O,S) layer on CIGS can be controlled by various factors, with the best device efficiency reaching 13.5% through optimization.
ACS APPLIED MATERIALS & INTERFACES
(2021)
Article
Chemistry, Physical
Gi Soon Park, SeungJe Lee, Da-Seul Kim, Sang Yeun Park, Jai Hyun Koh, Da Hye Won, Phillip Lee, Young Rag Do, Byoung Koun Min
Summary: Ultrathin solar cells (UTSCs) have attracted attention due to their low-cost production and potential applications. To achieve high efficiency, passivation of the rear-interface is crucial, especially for thinner absorbers. This study introduces amorphous TiO2 layers as passivating contacts for solution-processed UTSCs, which not only passivate defective rear-interfaces but also provide excellent electrical conduction. The amorphous nature of TiO2 layers enables desirable ohmic conduction over the entire area without any contact openings.
ADVANCED ENERGY MATERIALS
(2023)
Review
Engineering, Electrical & Electronic
Yatir Sadia, Itamar Lifshitz, Daniel Sebaoun, Yaniv Gelbstein
Summary: This study investigates the thermoelectric properties of materials based on the chalcopyrite structure. The properties can be controlled by doping with different types and concentrations of dopants. CuInS2 exhibits n-type behavior, which can be changed to p-type by doping with Cd and Ni. CuInSe2 shows n-type behavior, but can also be changed to p-type by doping with Cd and Ni. CuInTe2 has improved thermoelectric performance with low concentrations of Cd doping.
ACS APPLIED ELECTRONIC MATERIALS
(2023)
Article
Chemistry, Physical
Christopher P. Muzzillo, Stephen Glynn, Glenn Teeter, Lorelle M. Mansfield
Summary: This study investigates the effect of KF post-deposition treatments (PDTs) on the performance of Cu(In,Ga)Se-2 (CIGS) solar cells using air-free transfer of multiple samples. The results show that KF PDTs can improve cell efficiency, enhance minority carrier lifetime, and modify the alignment of the surface valence band.
ACS APPLIED ENERGY MATERIALS
(2022)
Article
Chemistry, Physical
Oana Cojocaru-Miredin, Elaheh Ghorbani, Mohit Raghuwanshi, Xiaowei Jin, Dipak Pandav, Jens Keutgen, Reinhard Schneider, Dagmar Gerthsen, Karsten Albe, Roland Scheer
Summary: Research has shown that intense sulphurization processes in Cu(In,Ga)Se-2 thin-film solar cells, combined with Ga-grading, can lead to improved electrical properties of the buffer/absorber heterojunction by reducing p-doping and altering the band diagram. This process results in the formation of a S-rich compound at the absorber surface, ultimately offering new possibilities for synthesizing high-performance Cu(In,Ga)(Se,S)(2) solar cells.
Article
Chemistry, Physical
Polyxeni Tsoulka, Sylvie Harel, Ludovic Arzel, Alfons Weber, Thomas Niesen, Pablo Reyes-Figueroa, Hossam Elanzeery, Thomas Dalibor, Nicolas Barreau
Summary: The chalcogen atmosphere during alkali fluoride post-deposition treatment (PDT) on Cu(In,Ga)(S,Se)2 (CIGSSe) absorbers plays a crucial role in determining the surface properties. The study focused on RbF-PDTs, examining the effects of Se and S atmosphere and the impact of In and RbF co-evaporation. The results showed that under Se atmosphere, a Cu-poor chalcopyrite phase was enhanced, while under S atmosphere, Cu-poor chalcopyrite phases were hindered.
APPLIED SURFACE SCIENCE
(2023)
Article
Nanoscience & Nanotechnology
Yuxian Li, Daming Zhuang, Ming Zhao, Chen Wang, Hao Tong, Liangzheng Dong, Shengye Tao, Hanpeng Wang
Summary: We developed a novel process for fabricating oxygen-rich Zn(O,S) buffer layers suitable for industrial production. By precisely controlling the composition of Zn(O,S), we investigated its effects on film quality, p-n junction properties, and CIGSSe solar cell performance. We observed that the appropriate content of ZnSO4 and ZnSO3 secondary phases improved the band alignment of oxygen-rich Zn(O,S). By establishing a crucial correlation between device performance and interfacial properties, we found that the band alignment matching at the heterojunction plays a primary role in CIGSSe device performance. An excellent oxygen-rich Zn(O,S) buffer can be obtained with 10% Zn(O,S) deposition oxygen partial pressure.
ACS APPLIED MATERIALS & INTERFACES
(2022)
Article
Materials Science, Multidisciplinary
Lukas Kinner, Martin Bauch, Rachmat Adhi Wibowo, Giovanni Ligorio, Emil J. W. List-Kratochvil, Theodoros Dimopoulos
MATERIALS & DESIGN
(2019)
Article
Chemistry, Multidisciplinary
Young-Ill Kim, Kee-Jeong Yang, Se-Yun Kim, Jin-Kyu Kang, Juran Kim, William Jo, Hyesun Yoo, JunHo Kim, Dae-Hwan Kim
JOURNAL OF INDUSTRIAL AND ENGINEERING CHEMISTRY
(2019)
Article
Chemistry, Physical
Jiwon Lee, Temujin Enkhbat, Gyuho Han, Md Hamim Sharif, Enkhjargal Enkhbayar, Hyesun Yoo, Jin Hyeok Kim, SeongYeon Kim, JunHo Kim
Article
Nanoscience & Nanotechnology
Myeng Gil Gang, Vijay C. Karade, Mahesh P. Suryawanshi, Hyesun Yoo, Mingrui He, Xiaojing Hao, In Jae Lee, Byeong Hoon Lee, Seung Wook Shin, Jin Hyeok Kim
Summary: Introducing a thin Ag layer on a metallic precursor in kesterite solar cells effectively improves device characteristics and performance in ACZTSSe solar cells, reducing the Voc-deficit and enhancing efficiency.
ACS APPLIED MATERIALS & INTERFACES
(2021)
Article
Nanoscience & Nanotechnology
Vijay Karade, Eunyoung Choi, Myeng Gil Gang, Hyesun Yoo, Abhishek Lokhande, Pravin Babar, Jun Sung Jang, Jan Seidel, Jae Sung Yun, Jongsung Park, Jin Hyeok Kim
Summary: This study investigates the surface potential and the impact of compositional ratios on the device performance of kesterite-based thin-film solar cells. The findings suggest that at the optimal compositional ratio of Cu/(Zn+Sn) ≈ 0.6, there is a significant improvement in power conversion efficiency.
ACS APPLIED MATERIALS & INTERFACES
(2021)
Article
Nanoscience & Nanotechnology
Hyesun Yoo, Jun Sung Jang, Seung Wook Shin, Jiwon Lee, JunHo Kim, Dong Myeong Kim, In Jae Lee, Byeong Hoon Lee, Jongsung Park, Jin Hyeok Kim
Summary: This study reveals the correlation between the reaction pathway and the point defects in the CZTSe film, showing that different reaction pathways lead to different device performances and defect energy levels. Additionally, the growth rates of different binary selenides during the annealing process have a significant impact on the formation of point defects.
ACS APPLIED MATERIALS & INTERFACES
(2021)
Article
Materials Science, Multidisciplinary
Selina Goetz, Rachmat Adhi Wibowo, Martin Bauch, Neha Bansal, Giovanni Ligorio, Emil List-Kratochvil, Christian Linke, Enrico Franzke, Joerg Winkler, Markus Valtiner, Theodoros Dimopoulos
Summary: Dielectric/metal/dielectric (DMD) transparent electrodes have emerged as a compelling alternative to indium-tin-oxide (ITO) for solar cells and optoelectronic devices, especially on flexible substrates. The study investigates MoOx/metal/MoOx DMD electrodes with Ag and Au, showing higher figure-of-merit on PET substrates compared to evaporated electrodes. The electrodes with MoOx layers exhibit low stability in water but are stable in other solvents, and demonstrate enhanced mechanical stability compared to ITO in tensile bending tests.
JOURNAL OF MATERIALS SCIENCE
(2021)
Article
Chemistry, Physical
Kuldeep Singh Gour, Vijay Karade, Jun Sung Jang, Eunae Jo, Pravin Babar, Sumit Korade, Hyesun Yoo, Sugil Kim, Dongmyung Kim, Jongsung Park, Jin Hyeok Kim
Summary: The addition of a p-type CuAlO2 (CAO) intermediate layer between molybdenum (Mo) and the absorber in CZTSSe devices improves device performance by improving absorber bulk quality, reducing Mo(S,Se)(2) layer thickness, and decreasing series resistance. This leads to an increase in short-circuit current density (J(SC)) and power conversion efficiency, compared to reference devices.
ACS APPLIED ENERGY MATERIALS
(2021)
Article
Energy & Fuels
Anies Mutiari, Theodoros Dimopoulos, Martin Bauch, Ankit Mittal, Matthias Weil, Rachmat Adhi Wibowo
Summary: The study demonstrated the implementation of ultrathin dielectric/metal/dielectric layers of AZO/Ag/AZO as a transparent electrode in CZTS photovoltaic device, achieving high CZTS absorption without substrate heating. The optical simulations were used to design the optimum thickness of the layers, resulting in a transparent electrode with high transmittance, low sheet resistance, and high figure-of-merit.
SOLAR ENERGY MATERIALS AND SOLAR CELLS
(2021)
Article
Chemistry, Multidisciplinary
Rachmat Adhi Wibowo, Katharina Rauchenwald, Stefan Edinger, Neha Bansal, Stefan Diebald, Daniel Habenbacher, Theodoros Dimopoulos
Summary: A flexible transparent heater with high transmittance and good conductivity is developed by using a sprayed composite architecture of silver nanowires and indium-doped zinc oxide layers. The low-temperature spray-pyrolysis process used for the zinc oxide layers ensures the thermal stability of the transparent polyimide substrate and the formation of compact and transparent layers. The resulting heater exhibits high temperature stability and fast heating response, and maintains good mechanical stability under different stresses. This research demonstrates the feasibility of large-scale and cost-effective production of high-performance transparent heaters using all-sprayed composite coatings.
Article
Materials Science, Multidisciplinary
Selina Goetz, Rachmat Adhi Wibowo, Martin Bauch, Neha Bansal, Giovanni Ligorio, Emil List-Kratochvil, Christian Linke, Enrico Franzke, Joerg Winkler, Markus Valtiner, Theodoros Dimopoulos
Summary: Recently, a transparent electrode called dielectric/metal/dielectric (DMD) based on MoO3 has been applied in solar cells and organic light-emitting diodes (OLEDs). However, the MoO3 layer is easily dissolved in water, which hinders its processing with water-based solutions. In this study, a DMD electrode based on mixed molybdenum-titanium-oxide (MTO) was introduced to improve the stability in water. The addition of titanium greatly increased the stability in water while maintaining the desirable electronic properties of MoO3. The DMD electrodes with a silver (Ag) metal layer were fabricated on both glass and polyethylene terephthalate (PET) substrates, showing low sheet resistance and high transmittance. The MTO stability enabled processing with water-based solutions without electrode degradation. The DMDs were also successfully produced on a wide PET foil using a roll-to-roll process, demonstrating its compatibility for large-scale industrial production.
JOURNAL OF MATERIALS SCIENCE
(2022)
Article
Chemistry, Physical
Siwon Oh, Soo Yeon Lim, Dae-Ho Son, Jin-Kyu Kang, Hyesun Yoo, Dae-Hwan Kim, Hyeonsik Cheong
Summary: This study investigated the influence of the SnSe2 secondary phase on the performance of a solar cell. The research found that even with a small amount, the SnSe2 secondary phase has a critical impact on the characteristics of the solar cell. Controlling the formation of the SnSe2 secondary phase is identified as a crucial factor in obtaining high-efficiency CZTSSe solar cells.
ACS APPLIED ENERGY MATERIALS
(2022)
Article
Chemistry, Physical
Hyesun Yoo, Jongsung Park, Mahesh P. Suryawanshi, Jiwon Lee, JunHo Kim, Kiryung Eom, Hyungtak Seo, HyoRim Jung, Dong Myeong Kim, Seung Wook Shin, Jin Hyeok Kim
Summary: This study presents new insights into surface and interface engineering of CZTSe/CdS buffer in solar cells by in situ formed ZnSe nanoparticles, leading to improved device characteristics and junction qualities. The favorable band alignment and formation mechanism of in situ formed ZnSe NPs offer a simple and source-free interface engineering strategy to enhance the performance of kesterite solar cell devices.
JOURNAL OF MATERIALS CHEMISTRY A
(2021)
Article
Chemistry, Physical
Jongsung Park, Hyesun Yoo, Vijay Karade, Kuldeep Singh Gour, Eunyoung Choi, Moonyong Kim, Xiaojing Hao, So Jeong Shin, JunHo Kim, Hongjae Shim, Dongmyung Kim, Jong H. Kim, Jaesung Yun, Jin Hyeok Kim
JOURNAL OF MATERIALS CHEMISTRY A
(2020)
Article
Materials Science, Multidisciplinary
Byeong Hoon Lee, Hyesun Yoo, Jun Sung Jang, InJae Lee, Jihun Kim, Eunae Jo, Jin Hyeok Kim
KOREAN JOURNAL OF MATERIALS RESEARCH
(2019)