Article
Chemistry, Physical
E. S. Marchenko, G. A. Baigonakova, K. M. Dubovikov, Yu. F. Yasenchuk, S. V. Gunther
Summary: The study found that the reaction synthesis of Ti-Ni-Ti nanolaminate at different temperatures has different effects on the Ti and Ni layers. A dense two-layer gradient coating can be formed at 900 degrees Celsius, which reliably protects the matrix from further diffusion of interstitial impurities and segregation of Ni atoms onto the surface.
SURFACES AND INTERFACES
(2021)
Article
Materials Science, Multidisciplinary
C. C. Meloa, L. S. Silvac, A. Cremascob, R. Caram
Summary: This study investigated the formation and crystallization of a nanostructured oxide layer on the surface of Ti-35Nb and Ti-35Nb-5Ta samples using heat treatments. The results showed the formation of anatase within a certain temperature range, with a transformation to rutile at higher temperatures. A doped Nb2O5 phase was also detected at higher temperatures. The presence of Ta in the Ti-Nb-Ta substrate supported the crystallization of anatase and (Nb)2O5 at lower temperatures compared to the Ti-Nb substrate.
Article
Materials Science, Multidisciplinary
Hryhorii Makarov, Leonid Satrapinskyy, Marek Vidis, Tomas Roch, Gustav Plesch, Marian Mikula
Summary: This study introduces a method for growing titanium molybdenum oxide (TMO) nanotubes directly from a metallic precursor solid state solution and provides their structural and chemical characterization. Precursor films with molybdenum content ranging from 32 to 82 at% were prepared using co-deposition magnetron sputtering. By optimizing the deposition parameters, a continuous nanotube array with a length of up to 700 nm +/- 10% was grown through anodic oxidation.
Article
Materials Science, Multidisciplinary
Hye-Ri Cho, Han-Cheol Choe
Summary: This study investigated the morphology of hydroxyapatite and Sr coatings deposited on nanotube formed Ti-6Al-4V alloy using radio frequency-magnetron sputtering method. It was found that the diameter and thickness of the nanotubes increased with applied voltage, and an increased number of anatase phases was observed on the surface with higher voltages. The HA and Sr coating layer was thicker than the HA coating layer, and the surface roughness of the alloy increased with voltage, while the contact angle decreased for non-coating and HA coating, but increased for HA and Sr coating with higher voltages.
Article
Materials Science, Coatings & Films
J. A. Lenis, Elbert Contreras Romero, Abel Hurtado Macias, P. Rico, J. L. Gomez Ribelles, M. A. Pacha-Olivenza, M. L. Gonzalez-Martin, F. J. Bolivar
Summary: In this study, the surface of Ti6Al4V alloy, commonly used in implant fabrication, was modified with a novel biocompatible and antibacterial coating composed of multiple layers of hydroxyapatite (HA) and Ag. The coatings were characterized for their chemical and phase compositions, as well as their structural, topographical, and morphological properties. Mechanical properties were determined, and the biological response was evaluated using cell viability tests and bacterial viability tests. The results show excellent chemical and compositional control of the coatings, as well as high antibacterial potential and biocompatibility.
SURFACE & COATINGS TECHNOLOGY
(2022)
Article
Chemistry, Physical
Baktiyar Soltabayev, Ahmad Ajjaq, Gani Yergaliuly, Yerkebulan Kadyrov, Amanzhol Turlybekuly, Selim Acar, Almagul Mentbayeva
Summary: This study aims to explore the advantages of titanium doping and magnetron sputtering over chemical-based methods on the surficial and electrical characteristics of ZnO films, specifically on their gas sensing performance. Pure ZnO nanofilm and Ti-doped ZnO nanofilms with different Ti contents were synthesized using RF magnetron sputtering. The nanofilms exhibited a pure hexagonal wurtzite structure, with relatively flat and homogenous surfaces and a clear distribution of nanoparticles in the Ti-doped samples. The enhanced properties of the nanofilms were reflected in the gas sensor's ultimate performance, with the 1 wt% Ti content sensor showing the best gas sensing performance.
JOURNAL OF ALLOYS AND COMPOUNDS
(2023)
Article
Chemistry, Physical
B. Subramanian, P. Sasikumar, S. Thanka Rajan, K. Gopal Shankar, Murugan Veerapandian
Summary: This study developed a novel ternary amorphous alloy (Zr54Ti35Si11) coating using DC magnetron sputtering technique, which exhibited excellent corrosion resistance and bioactivity for biomedical implant application.
JOURNAL OF ALLOYS AND COMPOUNDS
(2023)
Review
Materials Science, Ceramics
Mir Saman Safavi, Maria A. Surmeneva, Roman A. Surmenev, Jafar Khalil-Allafi
Summary: This review examines the development of hydroxyapatite-based composite and multilayer bio-coatings fabricated using radio frequency magnetron sputtering. It highlights the importance of assessing variables such as chemical composition, reinforcing phase(s), operating conditions, and treatments in determining the final characteristics of the bio-coatings. Challenges and future prospects of these systems are also discussed in detail.
CERAMICS INTERNATIONAL
(2021)
Article
Engineering, Environmental
Umair Baig, M. F. Al-Kuhaili, M. A. Dastageer
Summary: A zinc oxide-coated alumina ceramic membrane with super-wettable and photo-responsive self-cleaning features was fabricated using radio frequency magnetic sputtering and was used in a dead-end filtration system for oily water treatment. The membrane demonstrated unique surface wettability and efficient self-cleaning under light irradiation due to the properties of the materials used.
PROCESS SAFETY AND ENVIRONMENTAL PROTECTION
(2023)
Article
Chemistry, Physical
Weiwei Shi, Qiang Miao, Wengping Liang, Yangyang Liu, Mengjuan Yin, Xiao Xu, Lin Xue
Summary: The study shows that CrAl/CrAlN duplex layer coatings significantly improve erosion resistance by enhancing adhesion strength and preventing peeling off of the coating.
SURFACES AND INTERFACES
(2021)
Review
Chemistry, Physical
Yuxin Ju, Ling Ai, Xiaopeng Qi, Jia Li, Weijie Song
Summary: This review comprehensively examines the scalable and highly reproducible nature of magnetron sputtering for depositing hydrophobic thin films. It outlines the fundamental mechanism of hydrophobicity and summarizes recent advances in the preparation, characteristics, and applications of thin films derived from oxides, polytetrafluoroethylene (PTFE), and diamond-like carbon (DLC). The review also discusses the future applications, current challenges, and development of hydrophobic thin films, providing a brief perspective on future research directions.
Article
Materials Science, Coatings & Films
C. da Silva Oliveira, D. Martinez-Martinez, L. Cunha, S. Lanceros-Mendez, P. Martins, E. Alves, N. P. Barradas, M. Apreutesei
Summary: In this study, Zr-O-N films containing Ti were prepared by adding Ti ribbons on the racetrack of a Zr target during reactive magnetron sputtering. The addition of Ti ribbons prevented the target from being poisoned, especially at lower target currents, leading to a more controlled sputtering process. The color and electrical properties of the films were found to be closely related to the oxygen-to-metal ratio, while the N concentration did not have a significant impact.
SURFACE & COATINGS TECHNOLOGY
(2021)
Article
Materials Science, Multidisciplinary
Changling Tian, Haichao Cai, Yujun Xue
Summary: This study prepared Ce-Ti/MoS2 composite coatings using magnetron sputtering technology and investigated the variations in composition, structure, and tribological properties of the coatings under different working pressures. The results revealed that Ce and Ti doping can improve the performance of the coatings, but excessive working pressure can lead to a coarse coating structure, resulting in poor friction and wear properties.
Article
Materials Science, Multidisciplinary
Andres Gonzalez-Hernandez, William Aperador, Martin Flores, Edgar Onofre-Bustamante, Juan E. Bermea, Roberto Bautista-Garcia, Federico Gamboa-Soto
Summary: Titanium nitride films exhibit excellent mechanical properties and chemical stability, resulting in resistance to wear and corrosion. This study investigates the influence of deposition parameters on the structure, morphology, composition, and electrochemical behavior of Ti/Ti2N films deposited on carbon steel, with a focus on the substrate temperature.
Article
Materials Science, Multidisciplinary
Hichem Benzouid, Said Boudebane, Hana Ferkous, Fouaz Lekoui, Nafarizal Bin Nayan, Amel Delimi, Maha Awjan Alreshidi, Muhammad Arshad, Krishna Kumar Yadav, Barbara Ernst, Noureddine Elboughdiri, Yacine Benguerba
Summary: This study reports the synthesis and characterization of Ti/TiN/TiAlN thin films on 316L stainless steel and silicon wafer substrates using reactive RF/DC magnetron sputtering technique. Experimental and theoretical analyses were performed to investigate the films' microstructure, morphology, thickness, roughness, and wettability. The results demonstrated the effect of different parameters on the properties of the films. The combination of practical and theoretical analyses provided important insights into material properties and design.
MATERIALS TODAY COMMUNICATIONS
(2023)
Article
Chemistry, Physical
Mosab Kaseem, Han-Choel Choe
Summary: The fabrication of bioactive oxide layers on Ti-6Al-4V alloy using a combination of wet and dry plasma methods was reported to optimize chemical stability and biological activity. Incorporating small amounts of zinc and magnesium particles can enhance the biocompatibility of the oxide layer, promote hydroxyapatite formation, and enhance cell proliferation, leading to improved performance of implant materials.
JOURNAL OF ALLOYS AND COMPOUNDS
(2021)
Article
Materials Science, Coatings & Films
Seung-Pyo Kim, Hye-Ri Cho, Han-Cheol Choe
Summary: Bioactive element coatings were successfully applied on a nano-mesh formed Ti-6Al-4V alloy surface using plasma electrolytic oxidation, resulting in improved biological characteristics and enhanced cell adhesion and proliferation.
SURFACE & COATINGS TECHNOLOGY
(2021)
Article
Materials Science, Multidisciplinary
Hye-Ri Cho, Han-Cheol Choe
Summary: This study investigated the morphology of hydroxyapatite and Sr coatings deposited on nanotube formed Ti-6Al-4V alloy using radio frequency-magnetron sputtering method. It was found that the diameter and thickness of the nanotubes increased with applied voltage, and an increased number of anatase phases was observed on the surface with higher voltages. The HA and Sr coating layer was thicker than the HA coating layer, and the surface roughness of the alloy increased with voltage, while the contact angle decreased for non-coating and HA coating, but increased for HA and Sr coating with higher voltages.
Article
Pharmacology & Pharmacy
Manh Tuong Nguyen, Han-Cheol Choe, Byung-Hoon Kim, Sang-Gun Ahn
Summary: This study found that HL156A has a concentration-dependent anti-proliferative effect on oral cancer cells, achieved by inducing cell cycle arrest and apoptosis, while also inducing autophagy to protect cells against apoptosis.
EUROPEAN JOURNAL OF PHARMACOLOGY
(2022)
Article
Materials Science, Multidisciplinary
Seon-Yeong Park, Han-Cheol Choe
Summary: The surface characteristics of a dental implant doped with Si, Mg, Ca, and P ions via plasma electrolytic oxidation (PEO) were investigated. The results show that the Si and Mg ion-doped HA film surface has small and large micro-pores with uniform distributions. The micro-pores formed on the 5 similar to 20Mg/5Si coated samples were smaller than those on the Si and Mg ion-free CaP coated surfaces. Si, Mg, Ca, and P ions were well distributed on the PEO-treated surface, especially on the top, valley and crest of the screw. The adhesion force of the Si and Mg doped HA films increased with increasing Mg and Si ion concentrations.
KOREAN JOURNAL OF METALS AND MATERIALS
(2022)
Article
Materials Science, Multidisciplinary
Ji-Min Yu, Hye-Ri Cho, Han-Cheol Choe
Summary: The purpose of this study is to investigate the electrochemical characteristics of Sr/Si-doped hydroxyapatite coating on the Ti-6Al-4V alloy surface via plasma electrolytic oxidation(PEO). The results showed that the number of pores increased and the average size of the pores decreased as the Sr content increased. The addition of Si and Sr to the electrolyte resulted in a significant increase in the corrosion potential and higher polarization resistances.
Article
Materials Science, Multidisciplinary
Hye-Ri Cho, Han-Cheol Choe
Summary: In this study, the micro-scale morphology of Ti-40Nb-xZr alloys under plasma electrolytic oxidation (PEO) treatment was investigated. The results showed that the microstructure, elastic modulus, hardness, pore size, surface roughness, and contact angle of the alloy changed with the variation of Zr content and applied voltage.
Article
Materials Science, Multidisciplinary
Byeong-Seok Lim, Sang-Gyu Lim, Han-Cheol Choe
Summary: This study investigated the precipitation of bone-like apatite on plasma electrolytic oxidation (PEO)-treated Ti6Al-4V alloys with different electrolyte compositions. Various characterization techniques were used to observe the surface morphology, composition, and microstructure of the samples. It was found that the PEO-treated alloy surface in the electrolyte containing Ca, P, Mn, Sr, Zn, Mg, and Si ions was covered with precipitates in a ring pattern around the pores. The Mn ions were detected in the pores and played a role in the formation of MnO2 and Mn2O3. Apatite nucleation occurred in the pores after treatment in a simulated body fluid (SBF) solution, resulting in the formation of larger precipitates.
Article
Materials Science, Multidisciplinary
Hye-Ri Cho, Han-Cheol Choe
Summary: This study investigated the formation of nanotubes and the corrosion behavior of Ti-6Al-4V alloy with alpha- and beta-phases using various experimental instruments. The results showed that nanotubes were uniformly formed on the surface of the alpha-phase alloy, but irregularly formed on the beta-phase alloy. The nanotube-formed alloy exhibited a wider passivation range and higher corrosion current density. The morphologies of the corroded surfaces and XRD analysis revealed an increase in the anatase phase on the corroded surface of the nanotube-formed alloy.
Article
Nanoscience & Nanotechnology
Hye-Ri Cho, Han-Cheol Choe
Summary: In this study, new Ti-Nb-Ag-Pt alloys were developed to improve the biocompatibility of Ti alloys. The addition of Nb reduced the elastic modulus, while Ag and Pt reduced bacterial activity. Nanotubes were formed on the alloy surfaces using the anodization method. The nanotube-formed Ti-xNb alloys containing Ag and Pt showed antibacterial activity and greatly improved biocompatibility.
APPLIED NANOSCIENCE
(2022)
Article
Materials Science, Multidisciplinary
Byeong-Seok Lim, Hye-Ri Cho, Han-Cheol Choe
Summary: In this study, corrosion behaviors of macro/micro/nano-scale surface modifications of Ti-6Al-4V dental implants for bio-implants were investigated. Different methods were used to create surface roughness on the alloy, and corrosion behavior was studied using potentiodynamic and potentiostatic methods. The results showed that the current density increased with time in nanotube and nanotube-on-sandblasting specimens, indicating unstable film behavior in the sandblasted sample.
Article
Nanoscience & Nanotechnology
Byeong-Seok Lim, Hye-Ri Cho, Han-Cheol Choe
Summary: Surface modification of dental or orthopedic implants is crucial for biocompatibility, with Ti-6Al-4 V alloy being widely used. Research on nanotube formation for drug doping is ongoing to enhance biocompatibility. By varying applied voltage, nanotube shape changes on Ti-6Al-4 V alloy were studied, showing that higher voltage led to larger diameter nanotubes with different shapes.
APPLIED NANOSCIENCE
(2022)
Article
Nanoscience & Nanotechnology
Chang-Su Seo, So-Ra Lee, Han-Cheol Choe
Summary: This study investigated the effect of applied potential on nanoparticle formation during plasma electrolytic oxidation (PEO). The results showed that increasing the applied voltage resulted in larger and more uniform pores, but excessive voltage caused cracks and microcracks to appear on the PEO surface.
APPLIED NANOSCIENCE
(2022)
Article
Chemistry, Physical
Inho Bae, Han-Cheol Choe, Sang -Gun Ahn, Byung-Hoon Kim
Summary: This study compares the cytocompatibility and osteogenic differentiation of polycaprolactone (PCL) surfaces with spiky and hill-and-valley (H-a-V) topologies fabricated by the Plasma reactive ion etching (RIE) technique. It was found that the H-a-V group exhibited better cytocompatibility and osteogenic differentiation compared to the Spiky group.
APPLIED SURFACE SCIENCE
(2023)
Article
Materials Science, Biomaterials
Mosab Kaseem, Han-Choel Choe
Summary: This study investigates the enhancement of the protective and bioactive properties of Ti-6Al-4V alloy by incorporating cellulose microcrystalline (CMC) additive to form titania-based inorganic layers. A novel acetatephosphate-based electrolyte with CMC was formulated to modify the porous structure of the oxide layers made via plasma electrolysis. The presence of CMC changed the characteristics of plasma discharges, leading to different pore sizes and surface roughness of the oxide layers. The coated samples in CMC-containing electrolytes exhibited improved protective and bioactive properties, making them potential implants for dental applications.
ACS BIOMATERIALS SCIENCE & ENGINEERING
(2023)