Review
Physics, Applied
Aleksander M. Wrobel, Pawel Uznanski
Summary: Our study reviews the production of amorphous hydrogenated silicon carbonitride thin films through remote plasma chemical vapor deposition (RP-CVD) using 1,1,3,3-tetramethyldisilazane as a single-source compound with H2 + N2 upstream-gas mixture. The effects of nitrogen content in the mixture on the RP-CVD process, chemical structure, surface morphology, and properties of the deposited films are described. The a-SiCN films show great potential as coatings for improving the surface mechanics of engineering materials in advanced technologies.
PLASMA PROCESSES AND POLYMERS
(2023)
Article
Chemistry, Physical
W. Ke, K. Yang, X. D. Zhu
Summary: Amorphous Si-B-N alloy films prepared on SS304 stainless steel substrates by RF-PCVD technique exhibited improved hardness and wear resistance, with a surface morphology of hilly clusters composed of small particles.
APPLIED SURFACE SCIENCE
(2021)
Article
Materials Science, Multidisciplinary
Youngsuk Kim, Nina Baule, Maheshwar Shrestha, Qi Hua Fan
Summary: A single-beam plasma source was used to deposit transparent and durable hydrogenated amorphous carbon coatings at room temperature, with high transmittance and high durability, suitable for many applications.
Article
Materials Science, Multidisciplinary
Antoine Raison, Nathalie Prud'homme, Wu Wang, Diana Dragoe, Nita Dragoe
Summary: We have successfully synthesized a multi-cationic oxide (MgCoNiCuZn)O through pulsed liquid injection chemical vapor deposition. The synthesis was carried out at temperatures ranging from 400 degrees C to 550 degrees C, using five metal-organic precursors solubilized in dimethoxyethane (DME). The microstructure of the material was analyzed using HRTEM with HAADF, SEM, EDS, XPS, and XRD techniques before and after annealing.
Article
Physics, Applied
Aleksander M. Wrobel, Pawel Uznanski
Summary: The study examines the amorphous hydrogenated silicon carbonitride (a-SiCN) thin film coatings produced by remote plasma chemical vapor deposition using 1,1,3,3-tetramethyldisilazane as a single-source compound. Different gas mixtures and substrate temperatures were used to explore the relationship between structure and properties of the deposited films. The results show that the a-SiCN films produced using hydrogen as plasma feeding gas exhibit excellent mechanical properties, making them suitable for improving surface properties of engineering materials and other advanced technological applications.
PLASMA PROCESSES AND POLYMERS
(2023)
Article
Crystallography
Feifei Lan, Rui Zhou, Ziyue Qian, Yuansha Chen, Liming Xie
Summary: In this study, Fe3O4 thin films with room-temperature ferrimagnetism were successfully grown using a simple chemical vapor deposition method. The films maintained good magnetic properties even at thicknesses as low as 4 nm. Various analysis techniques were used to study the structure and quality of the films, and it was found that the saturation magnetization was higher than that of bulk materials and the Verwey transition was observed. This work provides a new method for synthesizing ultrathin films with ferrimagnetic properties for applications in electronics, spintronics, and memory devices.
Article
Materials Science, Ceramics
Han-Yin Liu, Yu-Jie Liao, Hung-Yi Wu
Summary: This study investigates the deposition of InSnZnO thin films using mist chemical vapor deposition with different nitrogen/oxygen ratios of carrier gases. The results show that using nitrogen as the carrier gas leads to the highest field-effect mobility, and using a mixed nitrogen/oxygen carrier gas improves the electrical characteristics of the films.
CERAMICS INTERNATIONAL
(2022)
Article
Chemistry, Physical
Lianping Chen, Yuanhong Gao, Yibin Chen, Jun Cao
Summary: The influence of europium on the structure and luminescent properties of CaWO4 thin films was investigated, and the sputtering yields of different compounds were studied. The results showed that the compositions of the deposits matched those of the targets, and the lattice constants increased under certain conditions. The preferential growth along a specific crystal plane also increased due to the substitution of Ca2+ with Eu2+. Doping of Eu led to improved photoluminescence performance of the films.
JOURNAL OF ALLOYS AND COMPOUNDS
(2022)
Article
Engineering, Chemical
David Redka, Milan Buttberg, Gerhard Franz
Summary: This article discusses the issue of longitudinal decreasing film thickness and its solution, providing a theoretical model and experimental verification. By predicting the sticking coefficient curve, the actual homogeneous film thickness can be obtained and shown to be in good agreement with the prediction. Additionally, it is found that there is a maximum achievable homogeneous film thickness in the tube, which can be understood as the coating efficiency.
Article
Materials Science, Multidisciplinary
Maxime Puyo, Konstantina Christina Topka, Babacar Diallo, Raphael Laloo, Cecile Genevois, Pierre Florian, Thierry Sauvage, Diane Samelor, Francois Senocq, Hugues Vergnes, Brigitte Caussat, Marie-Joelle Menu, Nadia Pellerin, Constantin Vahlas, Viviane Turq
Summary: Nanoindentation is a well-known technique for evaluating the mechanical properties of materials. This study focused on assessing the intrinsic properties of chemical vapor deposited silicon oxide and silicon oxycarbide thin films through dynamic indentation experiments. Results showed that the Young modulus of the films was more affected by substrate properties than hardness, with correlations established between properties, chemical composition, and structural organization.
Article
Materials Science, Coatings & Films
Jorge Sanchez Espinoza, Fatma Trabelsi, Christophe Escape, Ludovic Charpentier, Marc Fivel, Elisabeth Blanquet, Frederic Mercier
Summary: Ti3SiC2-SiC multilayer film coatings were synthesized using the high temperature reactive chemical vapor deposition technique. The coatings exhibited good mechanical integrity and high temperature stability.
SURFACE & COATINGS TECHNOLOGY
(2022)
Article
Chemistry, Physical
Kang-Bin Bae, Hae-Seong Jang, Yoon-Suk Oh, In-Hwan Lee, Sung-Min Lee
Summary: This study investigates the effects of HfO2 addition to Y2O3 thin films on plasma resistance, and finds that this strategy can improve the etch resistance during fluorine-based plasma etching.
APPLIED SURFACE SCIENCE
(2023)
Article
Engineering, Electrical & Electronic
Kunihiro Kamataki, Yusuke Sasaki, Iori Nagao, Daisuke Yamashita, Takamasa Okumura, Naoto Yamashita, Naho Itagaki, Kazunori Koga, Masaharu Shiratani
Summary: High-quality amorphous silicon nitride (SiNx) thin films were fabricated by controlled growth of nanoparticles in SiH4+N2 multi-hollow remote plasma chemical vapor deposition (CVD) at low substrate temperature. The incorporation of nanoparticles in the film corresponded to a higher N/Si ratio, indicating nitridation of the nanoparticles in the plasma. The size of the nanoparticles was controlled by adjusting the N2/SiH4 gas flow ratio and total gas flow rate, resulting in higher N/Si ratio and lower hydrogen content in the film.
MATERIALS SCIENCE IN SEMICONDUCTOR PROCESSING
(2023)
Article
Chemistry, Inorganic & Nuclear
Aida Raauf, Jennifer Leduc, Michael Frank, Daniel Stadler, David Graf, Michael Wilhelm, Matthias Grosch, Sanjay Mathur
Summary: In this study, UO2 thin films were synthesized by CVD using a U(VI) precursor, and it was found that the application of magnetic fields can alter the morphology and crystallographic orientation of grains, reduce grain size, promote polycrystalline growth, and decrease surface oxidation of U(IV) centers. The presence of a magnetic field as an extrinsic parameter in the CVD process has a positive effect on controlling the texture and chemical homogeneity of the grown films.
INORGANIC CHEMISTRY
(2021)
Article
Materials Science, Ceramics
T. V. Perevalov, V. A. Volodin, G. N. Kamaev, A. A. Gismatulin, S. G. Cherkova, I. P. Prosvirin, K. N. Astankova, V. A. Gritsenko
Summary: The electronic structure and optical properties of SiOxNy:H films enriched with silicon obtained by plasma-enhanced chemical deposition are studied. It is found that the film composition can be effectively varied by changing the gas flow ratio and plasma generator power. Additionally, the p+-Si/SiOxNy:H/Ni structures exhibit properties of memristor bipolar type.
JOURNAL OF NON-CRYSTALLINE SOLIDS
(2022)