Article
Materials Science, Ceramics
Alireza Ramezani, Hossein Abdizadeh, Mohammad Reza Golobostanfard
Summary: BaTiO3 and SrTiO3 thin films and BaTiO3/SrTiO3 lamellar composites were successfully synthesized using the sol-gel spin-coating method in this study. The morphology and band gap of the composite samples could be altered by changing the periodicity of the samples. The optical properties of the multi-stacked composites, including dielectric constant, dielectric loss, impedance, Urbach tail, extinction coefficient, and electric modulus, were also investigated.
CERAMICS INTERNATIONAL
(2021)
Article
Chemistry, Physical
Jing Shi, Rizhuang Dong, Jiayi He, Daowei Wu, Wenchao Tian, Xiao Liu
Summary: This study investigated the structural, dielectric, and ferroelectric properties of lead-free ceramics based on the ternary system of BaTiO3 (BT). It was observed that the dopant concentration influenced the structural evolution from tetragonal to pseudocubic phase. The dielectric response showed diffusive peaks and relaxor behavior, indicating a transition from ferroelectric to relaxor state. The ceramics exhibited slim polarization hysteresis loops and electrical inhomogeneities caused by excessive dopant addition, leading to degraded electric breakdown strength. The oxygen vacancy hopping mechanism was proposed to explain the diffuse dielectric response at high dopant concentrations.
JOURNAL OF ALLOYS AND COMPOUNDS
(2023)
Article
Materials Science, Multidisciplinary
Lang Chen, Ping Wang, Li Yang, Jiacheng Ling, Chao Liu, Yi Wang, Shousheng Zhang, Shaojie Feng, Xiusheng Wu, Pei Xu, Yunsheng Ding
Summary: Polydicyclopentadiene (PDCPD)/hydroxylated barium titanate (BTOH) and PDCPD/norbornene functionalized barium titanate (BTNA) composites were prepared using ROMP. The higher glass transition temperature (Tg) of PDCPD/BTNA was attributed to enhanced interfacial affinity. PDCPD/BTNA composites showed high dielectric constant due to interfacial polarization and low loss tangent due to nonconductive norbornene groups.
Article
Materials Science, Ceramics
Shuangqian Ma, Zhongyang Wang, Lan Yang, Danning He, Ming Yang, Liping Tong, Xiao Zhou, Tongxiang Fan
Summary: This work systematically studied the solar-reflective and infrared-radiative properties of Sr-doped BaTiO3 ceramics. It was found that increasing Sr content led to higher infrared emissivity and solar absorptivity, with Ba0.8Sr0.2TiO3 achieving the lowest absorptivity-emissivity ratio. The optical properties of these ceramics remained stable even during heat-induced phase transition, indicating potential for improved radiative cooling performance.
CERAMICS INTERNATIONAL
(2023)
Article
Materials Science, Ceramics
Gyung Hyun Ryu, Preston C. Bowes, John R. McGarrahan, Douglas L. Irving, Elizabeth C. Dickey
Summary: This study investigates the synergistic effects of co-doping BaTiO3 with acceptors and donors to control point defect chemistry and electrical properties, aiming to limit electronic and ionic conductivities. Results show that co-doping with Mn and Y can increase electrical resistivity, maintain independent electrical conductivity under oxidizing conditions, and improve time-dependent dielectric degradation resistance. These effects are attributed to a Fermi level pinning mechanism and reduced oxygen vacancy concentration.
JOURNAL OF THE AMERICAN CERAMIC SOCIETY
(2022)
Article
Materials Science, Multidisciplinary
Reda E. El-Shater, Ahmed S. Atlam, M. K. Elnimr, S. T. Assar, D. I. Tishkevich, T. I. Zubar, S. V. Trukhanov, A. V. Trukhanov, Di Zhou, Moustafa A. Darwish
Summary: Multiferroic composite materials have been widely used in various applications. In this study, multiferroic composite materials of Ni0.5Zn0.5Fe2O4 and BaTiO3 were prepared using co-precipitation synthesis route. The samples were characterized and their electrical and magnetic properties were studied. It was found that the prepared samples showed good electrical properties and magnetic properties when an appropriate amount of Ni0.5Zn0.5Fe2O4 was added.
MATERIALS SCIENCE AND ENGINEERING B-ADVANCED FUNCTIONAL SOLID-STATE MATERIALS
(2022)
Article
Chemistry, Multidisciplinary
Megha Acharya, Ella Banyas, Maya Ramesh, Yizhe Jiang, Abel Fernandez, Arvind Dasgupta, Handong Ling, Brendan Hanrahan, Kristin Persson, Jeffrey B. Neaton, Lane W. Martin
Summary: The study focused on epitaxial thin films of hafnate perovskites PbHfO3 and SrHfO3 on SrTiO3 (001) substrates, observing morphotropic phase boundary in the Pb1-xSrxHfO3 system. While the PbHfO3 films showed antiferroelectric properties, the SrHfO3 films did not exhibit ferroelectric behavior or transition to a polar phase. Alloying with strontium improved electric-breakdown strength and reduced hysteresis loss, leading to enhanced capacitive energy storage density and efficiency in the system.
ADVANCED MATERIALS
(2022)
Article
Nanoscience & Nanotechnology
Farnaz Safi Samghabadi, Long Chang, Mohammad Khodadadi, Karen S. Martirosyan, Dmitri Litvinov
Summary: In this study, cobalt ferrite/barium titanate particulate composites with high magnetoelectric coefficients were synthesized using mechanical ball milling and high-temperature annealing. The use of 50 nm cubic BaTiO3 powder as a precursor resulted in a composite with a magnetoelectric coupling coefficient value as high as 4.3 mV/Oe cm. The Microstructure of these composites differs significantly from those synthesized using 200 nm tetragonal BaTiO3 powder, showing larger CoFe2O4 grains and better electrical insulation due to the surrounding BaTiO3 matrix.
Article
Physics, Condensed Matter
Haolei Shen, Kui Xia, Peng Wang, Rongri Tan
Summary: Based on first-principles calculations, the electronic, structural, ferroelectric, and optical properties of (Ba0.875Sr0.125)(Zr0.125Ti0.875)O-3(BSZT) were investigated. The analysis showed that the crystal structure of BaTiO3 was distorted after doping with Sr and Zr, with different displacement magnitudes for Zr and Ti atoms. The ferroelectric properties could be attributed to the strong hybridization between Ti 3d, Zr 4d, and O 2p orbitals. The optical properties of BSZT exhibited a blue-shift and showed good optical response in the UV region, indicating potential applications in ceramic capacitors, resistors with high dielectric insulation, and optoelectronic devices.
SOLID STATE COMMUNICATIONS
(2022)
Article
Materials Science, Ceramics
S. A. N. Franca Junior, W. Acchar, S. L. A. Dantas, P. H. Chiberio, H. P. A. Alves, M. R. D. Bomio, F. V. Motta, F. Bohn, A. Ferreira, F. Vaz, M. A. Correa
Summary: We conducted a comprehensive investigation on the high-frequency dielectric properties of (ZrO2)100-x(BaTiO3)x heterostructures. By adjusting the content of BaTiO3, we could modify the dielectric constant of the resulting ceramic sheets. Our results demonstrated successful fabrication of heterostructured ceramic sheets and the ability to tailor the electric, structural, and dielectric properties of both ZrO2 and BaTiO3 materials. Furthermore, the evolution of the dielectric constant could be manipulated according to specific technological applications.
CERAMICS INTERNATIONAL
(2023)
Article
Materials Science, Ceramics
Ye Zhao, Qian Wang, Jun-Hu Lv, Xian Zhao, Chun-Ming Wang
Summary: In this study, Y-modified BaTiO3 ceramics with different yttrium doping levels were prepared, and BT-2.5Y showed the highest electrocaloric effect performance. This indicates that BT-100xY ceramics have great potential for applications.
CERAMICS INTERNATIONAL
(2021)
Article
Chemistry, Multidisciplinary
Jing-Wei Chen, Arnab Pal, Bo-Hao Chen, Gautam Kumar, Subhodeep Chatterjee, Kiran Peringeth, Zong-Hong Lin, Michael H. H. Huang
Summary: This study successfully synthesizes various forms of BaTiO3, including octahedra, edge- and corner-truncated cubes, and cubes with four tunable sizes. Acetic acid treatment removes BaCO3 impurities, and Rietveld refinement confirms the crystal structure is tetragonal. The crystals' physical properties vary with their size and facet. BaTiO3 octahedra exhibit better performance than truncated cubes and cubes, especially in piezoelectric nanogenerators.
Article
Physics, Multidisciplinary
Kouddad Elhachemi, D. Vigneswaran, Naoum Rafah, Deepika Koundal, Dekkiche Leila
Summary: In this paper, a new hybrid platform for optical logic gates based on the Pockels effect is proposed. The platform, which utilizes two-dimensional photonic crystal structure, enables the realization of multifunctional and high-performance photonic logic gates. Numerical analysis and optimization show that the platform exhibits high contrast ratio and ultrafast response time.
Article
Physics, Applied
Toshiki Okazaki, Takao Sada, Kosuke Tsuji, Yoshihiro Fujioka, Clive A. Randall
Summary: This paper reviews the synthesis of BaTiO3-based ceramic and composites through the cold sintering process. It provides several opportunities to fabricate BaTiO3 into new composite structures, while considering the challenges of surface chemistry, transient flux selection, core-shell designs, and co-sintering with polymers.
JAPANESE JOURNAL OF APPLIED PHYSICS
(2023)
Article
Materials Science, Ceramics
Zhihui Yi, Zhuo Wang, Yanxin Li, Dan Wu, Ying Xue
Summary: This paper focuses on addressing the low energy density issue of dielectric capacitors by designing layered polymer matrix composites. Various Ba0.7Sr0.3TiO3, Ba0.8Sr0.2TiO3, and Ba0.9Sr0.1TiO3 nanoparticles were successfully prepared and used in the composites. The three-layer asymmetric composites showed improved breakdown field strength and energy storage properties, indicating the potential for enhancing electrical energy storage.
CERAMICS INTERNATIONAL
(2022)
Article
Materials Science, Multidisciplinary
T. Bhowmick, S. Nag, S. B. Majumder
Summary: The response of p-type CuO thin films to ethanol and acetone vapours was investigated using a gas diffusion equation, Langmuir-Hinshelwood mechanism, and nonlinear sensor conductance variations with gas concentration. The maximum response rates were achieved at 300 degrees C for 240 nm CuO thin films, with a bell-shaped dependence of response on temperature for different film thicknesses. Additionally, irreversible gas responses were observed for both ethanol and acetone vapours within a certain concentration range.
MATERIALS CHEMISTRY AND PHYSICS
(2021)
Article
Engineering, Electrical & Electronic
Anisha Bandyopadhyay, Kamalika Mandal, Vibhav Ambardekar, Debasish Das, S. B. Majumder
Summary: The study focused on the ethanol-sensing performance of CuO thick film fabricated by electrophoretic deposition (EPD) technique, which showed high response %, quick response and recovery time, and stable baseline resistance in static ambient. The EPD-grown thick film CuO sensor exhibited characteristics constant response time for different test gas concentrations, and activation energies of transduction and first-order kinetics were estimated through theoretical analysis.
JOURNAL OF MATERIALS SCIENCE-MATERIALS IN ELECTRONICS
(2021)
Article
Materials Science, Multidisciplinary
Moumita Dewan, Tania Majumder, S. B. Majumder
Summary: The implementation of new energy storage technologies is crucial for addressing the ever-growing energy demand, and identifying suitable dual role anode materials while inspecting their reaction mechanism is significant for battery storage technology advancement. The EPD grown BFO anode shows impressive performance in both lithium and sodium storage, demonstrating the concept of dual role operation. The uniform BFO structure contributes to favorable Li and Na ion uptake by conversion reaction, offering potential for new dual role anode material development.
MATERIALS TODAY COMMUNICATIONS
(2021)
Article
Chemistry, Multidisciplinary
Solomon Amsalu Chekol, Stephan Menzel, Rana Walied Ahmad, Rainer Waser, Susanne Hoffmann-Eifert
Summary: The study investigates the switching dynamics of diffusive memristors based on volatile electrochemical metallization (v-ECM) devices, identifying the importance of filament formation and growth process on its relaxation time through analysis of threshold kinetics and filament relaxation.
ADVANCED FUNCTIONAL MATERIALS
(2022)
Article
Materials Science, Multidisciplinary
Anwesa Mukherjee, Subhadip Mondal, Debasish Das, Susanta Banerjee, S. B. Majumder
Summary: Surface modification by a thin layer of inert carbon or zirconia obtained by a simple impregnation method can improve the cycleability and rate capability of Na2Ti3O7, a promising low voltage anode for sodium ion battery. X-ray diffraction analysis confirms that the structure of Na2Ti3O7 remains unaltered after the surface modification. After 100 cycles, the modified materials are able to retain a higher percentage of their initial capacity compared to the bare material.
Article
Nanoscience & Nanotechnology
S. Tappertzhofen, L. Nielen, I Valov, R. Waser
Summary: The memristively programmable transistor design overcomes the tradeoff between long state retention and fast programming speed by using ions for programming, allowing for higher leakage current levels in gate-dielectrics. Experimental validation demonstrates the potential for high programming endurance and retention times, fast programming speeds, and high scalability.
Article
Chemistry, Multidisciplinary
Mainul Akhtar, Tania Majumder, Jeng-Kuei Chang, Subhasish Basu Majumder
Summary: In this study, a novel carbon-coated lithium titanate nanocomposite was reported as a superior anode material for lithium-ion batteries. A hybrid lithium-ion battery composed of this anode material and a specific cathode material was successfully fabricated. The battery exhibited excellent cycling stability, rate performance, and overall safety.
ACS SUSTAINABLE CHEMISTRY & ENGINEERING
(2022)
Article
Chemistry, Physical
Mainul Akhtar, Subhasish B. Majumder
Summary: Nickel-doped Na3V2(PO4)(3)@C compounds synthesized via sol-gel method were studied for the first time as cathodes for hybrid Li-ion batteries, showing improved stability, cycling performance, and ion intercalation pathway broadening. Among the tested cathodes, optimized Ni-doped and in situ carbon-coated NVP (NVPNi0.05@C) demonstrated the best electrochemical performance, with higher discharge capacity, capacity retention, and impressive rate performance. The preliminary results suggest great potential for developing low-cost, high-performance advanced energy devices with HLIBs incorporating Ni-doped NVP structures.
ACS APPLIED ENERGY MATERIALS
(2021)
Article
Chemistry, Physical
Mainul Akhtar, Arijit Mitra, Jeng-Kuei Chang, Subhasish Basu Majumder
Summary: In this work, sol-gel synthesized carbon-coated materials were reported as excellent cathode materials for hybrid Li-ion batteries. The structure of the synthesized material enhances electrochemical performances by reducing diffusion distance, improving electrical conductivity, and structural stability. Additionally, double hybridization was introduced to further improve rate performance and cycleability. The excellent performances of the bimaterial electrodes are attributed to the synergistic interaction between the materials.
ACS APPLIED ENERGY MATERIALS
(2022)
Article
Engineering, Electrical & Electronic
T. Bhowmick, A. Ghosh, V Ambardekar, S. Nag, S. B. Majumder
Summary: An economical and portable gas-sensing prototype for monitoring CO2 gas in flue gas has been developed. The prototype demonstrated high sensitivity to the tested gas and could operate within a temperature range of room temperature to 350 degrees C. The dominant mechanism for gas sensing was found to be the formation of carbonates on the CuO surface.
JOURNAL OF MATERIALS SCIENCE-MATERIALS IN ELECTRONICS
(2022)
Article
Chemistry, Physical
Arijit Mitra, Jagabandhu Patra, Jeng-Kuei Chang, Subhasish B. Majumder, Siddhartha Das
Summary: This article investigates the electrochemical performance of amorphous sodium iron carbonophosphate in both organic and ionic-liquid based electrolytes. The results show that using ionic-liquids instead of organic electrolytes leads to superior cycling performance at room temperature and high temperature, with nearly fade-free electrochemical cells. The dense and ionically conductive protective film composed of anion-reduced moieties is responsible for the excellent high-temperature performance of amorphous sodium iron carbonophosphate with ionic-liquids.
JOURNAL OF POWER SOURCES
(2023)
Article
Materials Science, Multidisciplinary
Anwesa Mukherjee, Mainul Akhtar, Jeng-Kuei Chang, Susanta Banerjee, Subhasish Basu Majumder
Summary: A novel NTP/GO/CNT nanocomposite anode material was reported, in which NTP particles were engineered with rGO and CNT. The NTP-rGO10-CNT10 electrode exhibited excellent electrochemical performance, including high specific capacity (124 mA h g-1 at 100 mA g-1), remarkable high-rate cycleability (62.5% capacity retention after 400 cycles at 10 C), and excellent rate capability (87 mA h g-1 at 25C). The capacitive and faradaic contributions to total capacities of the composite electrode were estimated by cyclic voltammetry investigation.
MATERIALS CHEMISTRY AND PHYSICS
(2023)
Article
Nanoscience & Nanotechnology
Stephan Aussen, Felix Cueppers, Carsten Funck, Janghyun Jo, Stephan Werner, Christoph Pratsch, Stephan Menzel, Regina Dittmann, Rafal Dunin-Borkowski, Rainer Waser, Susanne Hoffmann-Eifert
Summary: In this study, two different switching modes of memristive devices with valence change mechanism were identified: filamentary mode and interfacial mode. The filamentary mode involves Joule heating, while the interfacial mode operates by modulating the accumulation and depletion of oxygen vacancies.
ADVANCED ELECTRONIC MATERIALS
(2023)
Article
Computer Science, Information Systems
Nils Kopperberg, Stefan Wiefels, Karl Hofmann, Jan Otterstedt, Dirk J. Wouters, Rainer Waser, Stephan Menzel
Summary: In this work, the endurance of 2 Mbit resistive switching random access memories (ReRAMs) from a 16 MBit test-chip is experimentally characterized. Rare failure events where the memory cells become stuck in the low-resistive state (LRS) are observed. Investigations, both experimental and simulation-based, are conducted to understand the underlying mechanisms causing the failure and provide suggestions for improving switching algorithms.
Article
Engineering, Electrical & Electronic
Christopher Bengel, Johannes Mohr, Stefan Wiefels, Abhairaj Singh, Anteneh Gebregiorgis, Rajendra Bishnoi, Said Hamdioui, Rainer Waser, Dirk Wouters, Stephan Menzel
Summary: This study investigates the impact of device and circuit-level effects on VMM in VCM crossbars, highlighting the importance of variability in the low resistive state and the preference for reading in the RESET direction.
NEUROMORPHIC COMPUTING AND ENGINEERING
(2022)