Article
Chemistry, Organic
Yulin Sun, Zhuoyuan Liu, Donghan Liu, Mingshuai Zhang, Longkun Chen, Zhangmengjie Chai, Xue-Bing Chen, Fuchao Yu
Summary: Highly functionalized 4-alkylated 1,4-dihydropyridines (1,4-DHPs) are synthesized for the first time from cyclic ethers and enaminones via iron(II)-mediated oxidative free radical cascade C(sp(3))-H bond functionalization/C(sp(3))-O bond cleavage/cyclization reaction. This novel synthetic strategy provides an alternative method for the construction of 1,4-DHPs using esters as the C4 sources, and expands the application of ethers in heterocycle synthesis.
JOURNAL OF ORGANIC CHEMISTRY
(2023)
Review
Chemistry, Inorganic & Nuclear
Ekaterina S. Gulyaeva, Elena S. Osipova, Ruqaya Buhaibeh, Yves Canac, Jean-Baptiste Sortais, Dmitry A. Valyaev
Summary: This paper provides a comprehensive review of the rapidly emerging application of organometallic manganese complexes in catalytic reactions. It focuses on the influence of different donor ligands on catalytic activity and selectivity, the comparison with polydentate systems, and the study of mechanistic aspects.
COORDINATION CHEMISTRY REVIEWS
(2022)
Article
Chemistry, Multidisciplinary
Holger Elsen, Jens Langer, Gerd Ballmann, Michael Wiesinger, Sjoerd Harder
Summary: Commercial LiAlH4 can be used as a catalyst in the hydrogenation of imines, with cooperation between Li and Al being crucial for activity. Different intermediates have been isolated, with varying imine insertion observed depending on the structure of the imine. Experimental and theoretical investigations provide insights into the mechanism and barriers for the hydrogenation reaction, showing the effects of substituents on the imine structure.
CHEMISTRY-A EUROPEAN JOURNAL
(2021)
Article
Chemistry, Organic
Rongrong Xie, Cungang Liu, Renwei Lin, Runchen Zhang, Haizhou Huang, Mingxin Chang
Summary: The strong coordination between 1,2-diamines and transition metals can hinder or disrupt regular catalytic cycles. In this study, we employed sets of additives to ensure a smooth transformation catalyzed by rhodium complexes and versatile phosphoramidite-phosphine ligands. The tunability of the ligands was fully utilized to accommodate various diamines and alpha-ketoesters for the efficient synthesis of chiral 3,4-dihydroquinox-alinones.
Article
Chemistry, Multidisciplinary
Wei Sun, Ming-Peng Li, Lu-Jie Li, Qiang Huang, Meng-Yang Hu, Shou-Fei Zhu
Summary: Iron-catalyzed organic reactions have limitations compared to precious metal catalysts. This research develops novel iron complexes that can catalyze specific hydrosilylation reactions and provides insight into the mechanism. The crowded environment around the iron center plays a crucial role in the selectivity.
Article
Chemistry, Physical
Jennifer Poelker, Dieter Schaarschmidt, Josef Bernauer, Matteo Villa, Axel Jacobi von Wangelin
Summary: This article introduces a catalytic hydrogenation of amines using a bimetallic Li/Al dihydride catalyst. The research demonstrates that the preparation of this catalyst is relatively simple.
Article
Chemistry, Multidisciplinary
Alexander Friedrich, Jonathan Eyselein, Holger Elsen, Jens Langer, Jurgen Pahl, Michael Wiesinger, Sjoerd Harder
Summary: Cationic aluminum complexes stabilized by BDI ligands were investigated for catalytic activity in imine hydrogenation, with the steric and electronic factors needing to be balanced for optimal performance. The bulkiest cation ((BDI)-B-tBu,DIPP)AlMe+ showed the best catalytic activity, while DFT calculations revealed two interconnected catalytic cycles in the mechanism of imine hydrogenation.
CHEMISTRY-A EUROPEAN JOURNAL
(2021)
Article
Chemistry, Physical
Robert T. Kumah, Paranthaman Vijayan, Stephen O. Ojwach
Summary: Chiral (pyridyl)imine Fe(II) complexes were synthesized and evaluated as catalysts in asymmetric transfer hydrogenation of ketones reactions. The catalytic activities were regulated by the nature of the metal complexes and reaction conditions, with moderate catalytic activities and low enantioselectivity observed. Poisoning experiments suggested possible formation of both active Fe(0) nanoparticles and Fe(II) homogeneous intermediates.
Review
Chemistry, Multidisciplinary
Patrick D. Parker, Xintong Hou, Vy M. Dong
Summary: Tandem catalysis allows for constructing complex structures quickly from simple building blocks to address diverse challenges. This article focuses on using tandem hydrogenation to prepare complex natural products and presents tandem catalysis involving transfer hydrogenation. Lastly, recent breakthroughs and opportunities for asymmetric hydrogenation are highlighted.
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
(2021)
Article
Chemistry, Organic
Shunki Jinno, Takahiro Senoo, Keiji Mori
Summary: A facile method for the synthesis of N-(2-halophenyl)-2-hydroxyphenylimine derivatives via imine anion-mediated Smiles rearrangement has been developed.
Article
Chemistry, Multidisciplinary
Sangmin Kim, Junho Kim, Hongyu Zhong, Grace B. Panetti, Paul J. Chirik
Summary: The synthesis of a piano-stool ruthenium hydride with dual catalytic functions is described. The addition of a neutral supporting ligand successfully prevents a deleterious reaction pathway. The ruthenium hydride is an effective catalyst for various reactions.
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
(2022)
Article
Chemistry, Multidisciplinary
Lin Huang, Alessandro Bismuto, Simon A. Rath, Nils Trapp, Bill Morandi
Summary: The study introduces a novel strategy for the catalytic, intermolecular dehydrogenation of alkanes using a ruthenium catalyst, which involves a combination of a redox-active ligand and a sterically hindered aryl radical intermediate to unleash the new strategy. Mechanistic investigations have been conducted to provide a conceptual framework for the further development of this new catalytic dehydrogenation system.
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION
(2021)
Article
Multidisciplinary Sciences
Zitong Wu, Wenji Wang, Haodong Guo, Guorui Gao, Haizhou Huang, Mingxin Chang
Summary: Direct asymmetric reductive amination is an efficient method for obtaining chiral amines. In this study, the authors demonstrate how primary alkyl amines can undergo this transformation in the presence of an iridium catalyst with sterically tuneable chiral phosphoramidite ligands, leading to the synthesis of pharmaceutical compounds.
NATURE COMMUNICATIONS
(2022)
Article
Chemistry, Inorganic & Nuclear
Nokwanda Tsaulwayo, Robert T. Kumah, Stephen O. Ojwach
Summary: The reactions of (pyridyl)imine ligands with FeCl2 salt produced various Fe(II) complexes with different coordination modes, some of which showed excellent catalytic activities in the transfer hydrogenation of ketones. The existence of both Fe(0) nanoparticles and homogeneous Fe(II) species as the active intermediates was confirmed through mercury and sub-stoichiometric poisoning tests.
Article
Chemistry, Organic
Tingjie You, Maosheng Zhang, Jianhui Chen, Hongmei Liu, Yuanzhi Xia
Summary: A convenient method for the reductive cleavage of N-O bonds was described using a commercially available ruthenium(II) catalyst and a mixture of HCOOH/NEt3 as the hydride source under an air atmosphere. This catalytic system was applicable for a variety of N-oxygen-substituted amides, efficiently delivering the corresponding products with good functional group tolerance in moderate to good yields.
ORGANIC CHEMISTRY FRONTIERS
(2021)
Article
Chemistry, Applied
Serkan Dayan, Cevahir Altinkaynak, Nilgun Kayaci, Sengul Dilem Dogan, Nalan Ozdemir, Nilgun Kalaycioglu Ozpozan
APPLIED ORGANOMETALLIC CHEMISTRY
(2020)
Article
Chemistry, Inorganic & Nuclear
Noor Ibrahim Alhayali, Nilgun Kalaycioglu Ozpozan, Serkan Dayan, Nalan Ozdemir, Burcu Somturk Yilmaz
Summary: In this study, catalase/Fe3O4@Cu2+ hNFs were prepared as catalysts and characterized using various techniques. The reduction of nitrobenzenes and organic dye at different pH levels showed promising results, with the best conversion rates observed at pH 9.0 for both substrates. The study also examined the impact of pH and substrate change on the catalytic reaction conversion.
Article
Biochemistry & Molecular Biology
M. Ihsan Han, Pinar Atalay, Cansu Umran Tunc, Gokhan Unal, Serkan Dayan, Omer Aydin, S. Guniz Kucukguzel
Summary: Novel (S)-Naproxen derivatives were synthesized and compound 3a exhibited potent anticancer activity against two human breast cancer cell lines. The compound also showed anticancer effects in a mouse breast cancer model, reducing tumor volume in both low and high doses.
BIOORGANIC & MEDICINAL CHEMISTRY
(2021)
Article
Chemistry, Inorganic & Nuclear
Serkan Dayan, Melek Tercan, Fethi Ahmet Ozdemir, Gurkan Aykutoglu, Namik Ozdemir, Zafer Serbetci, Muharrem Dincer, Osman Dayan
Summary: PdL1-3 complexes with bi-dentate Schiff base ligands were synthesized and characterized, with PdL3 showing the best catalytic activity in the reduction of organic pollutants. The complexes also exhibited cytotoxic effects, especially against SH-SY5Y cells, and moderate antimicrobial and antifungal properties were observed for all compounds.
Article
Chemistry, Physical
Serkan DAYAN
Summary: The eco-friendly hybrid nanomaterial Co3O4@nHAP was successfully prepared and exhibited promising catalytic performance, which can be widely applied in environmentally friendly reaction systems. It was also tested as a counter electrode in dye-sensitized solar cells for the first time, showing good catalytic activity and reusability.
JOURNAL OF MOLECULAR STRUCTURE
(2021)
Article
Chemistry, Multidisciplinary
Nilgun Kayaci, Resul Ozdemir, Mustafa Kalay, N. Burak Kiremitler, Hakan Usta, M. Serdar Onses
Summary: The development of novel physically unclonable functions based on fluorescent organic semiconductors offers unique advantages for versatile and easily processable materials. The demonstrated OLE-PUFs show excellent surface features and optical properties, making them suitable for various substrates and environments. This study highlights the great potential of engineered f-OSCs in the development of new-generation PUFs.
ADVANCED FUNCTIONAL MATERIALS
(2022)
Article
Chemistry, Multidisciplinary
Burcu Somturk Yilmaz, Serkan Dayan, Nalan Ozdemir, Nilgun Kalaycioglu Ozpozan
Summary: In this study, flower-like enzyme-inorganic hybrid nanoflowers were synthesized for the first time. These nanoflowers were used as catalysts in the reduction of organic pollutants, showing promising catalytic properties for water-based reduction reactions.
Review
Nanoscience & Nanotechnology
Nuri Burak Kiremitler, Munteha Zeynep Kemerli, Nilgun Kayaci, Sultan Karagoz, Sami Pekdemir, Gokhan Sarp, Senem Sanduvac, Mustafa Serdar Onses, Erkan Yilmaz
Summary: This article provides an overview of how nanoscience and nanotechnology approaches can be used to combat the spread of the coronavirus SARS-CoV-2, focusing on protective equipment, diagnostic and treatment methods, medicine, and vaccine applications. It highlights the importance of controlled use of disinfection systems, rapid virus diagnosis, and the development of nanotechnology-based test and diagnostic kits.
ACS APPLIED NANO MATERIALS
(2022)
Article
Engineering, Electrical & Electronic
Serkan Dayan, Nalan Ozdemir, Mustafa Akbulut, Nilgun Kalaycioglu Ozpozan
Summary: In this study, modified flower-like hybrid nanomaterials were fabricated and tested as Pt-free counter electrodes in dye-sensitized solar cells. The addition of multi-walled carbon nanotubes to the structure significantly improved the photovoltaic parameters, leading to a fivefold increase in power conversion efficiency.
JOURNAL OF ELECTRONIC MATERIALS
(2022)
Article
Anatomy & Morphology
Sezer Demirbuga, Serkan Dayan, Hacer Balkaya
Summary: The aim of this study was to evaluate the drug release, degree of conversion (DC), and surface properties of resin composites containing chlorhexidine (CHX)-loaded mesoporous (mHAP) and nonporous hydroxyapatite (HAP) nanocarriers. Controlled CHX release was achieved by mHAP and HAP nanocarriers for 120 days. The addition of 5% nanocarrier increased the surface roughness but did not negatively affect the DC and the surface hardness of the resin composites.
MICROSCOPY RESEARCH AND TECHNIQUE
(2023)
Article
Chemistry, Multidisciplinary
M. Sakir, N. Torun, N. Kayaci, I. Torun, M. Kalay, M. S. Onses
Summary: This manuscript presents a method for the fabrication of silver nanoflowers with high surface-enhanced Raman scattering (SERS) activity and unique morphology. The nanoflowers are formed through seed-mediated growth of silver nanostructures over gold nanoparticles on hemispherical polymer features. The silver nanoflowers exhibit high SERS activity, allowing for detection of rhodamine 6G at a concentration of 100 pM. This fabrication method has great potential for anti-counterfeiting applications.
MATERIALS TODAY CHEMISTRY
(2023)
Article
Nanoscience & Nanotechnology
Abidin Esidir, Nilgun Kayaci, N. Burak Kiremitler, Mustafa Kalay, Furkan Sahin, Gulay Sezer, Murat Kaya, M. Serdar Onses
Summary: Counterfeit products in the pharmaceutical and food industries pose increasing threats to health. A study has developed security labels using food-grade materials, such as corn starch, to prevent counterfeiting. These labels, composed of fluorescent microparticles, offer a low-cost and sustainable solution in the fight against counterfeiting, with promising performance in terms of uniqueness and randomness.
ACS APPLIED MATERIALS & INTERFACES
(2023)
Article
Nanoscience & Nanotechnology
Abidin Esidir, Nilgun Kayaci, N. Burak Kiremitler, Mustafa Kalay, Furkan Sahin, Gulay Sezer, Murat Kaya, M. Serdar Onses
Summary: Counterfeit products in the pharmaceutical and food industries are a growing threat to health. This study presents the development of security labels using food-grade materials, specifically food-grade corn starch and a food colorant. The labels are created through spin-coating and transfer onto an edible gelatin film, with randomly positioned particles used to construct a physically unclonable function (PUF)-based security label. The performance of the PUFs demonstrates their potential in preventing counterfeiting, and their biocompatibility is confirmed through cell assays.
ACS APPLIED MATERIALS & INTERFACES
(2023)
Article
Chemistry, Multidisciplinary
Serkan Dayan, Namik Ozdemir, Digdem Erdener, Osman Dayan, Bekir cetinkaya
Summary: A new cationic ruthenium(II) complex (2) was synthesized and fully characterized. The immobilized Ru(II)-RGO-TiO2@FTO electrode showed moderately good sensitivity for glucose sensing. Modifications of the electrode can be made to improve the performance of future biosensor devices.
NEW JOURNAL OF CHEMISTRY
(2023)
Article
Chemistry, Multidisciplinary
Serkan Dayan, Mert Olgun Karatas, Bulent Alici, Nilgun Kalaycioglu Ozpozan
Summary: The new benzimidazolium derivative salt was fabricated and characterized for application in DSSC, with a focus on the influence of ion exchange on DSSC performance efficiency. The study showed that potential improvements in DSSC devices could be achieved through molecular modifications of benzimidazole derivatives or mixtures with conventional redox couples in the future.
TURKISH JOURNAL OF CHEMISTRY
(2021)
Article
Spectroscopy
Zh. E. Ozbekova, A. A. Abdyldaev, A. A. Kulmyrzaev
Summary: This study compared two drying methods for cow and yak muscles, finding that freeze drying caused less discoloration. Additionally, analysis of fluorescence spectra allowed for accurate prediction of chemical composition and color characteristics of the muscles.
SPECTROCHIMICA ACTA PART A-MOLECULAR AND BIOMOLECULAR SPECTROSCOPY
(2024)
Article
Spectroscopy
Leo Mandic, Ivan Ljubic, Iva Dzeba
Summary: In this study, a combined experimental and computational approach was used to investigate the photoexcitation and photodegradation mechanisms of Doxazosin (DOX). The results provide valuable insights into the primary events following the photoexcitation of DOX and its potential applications.
SPECTROCHIMICA ACTA PART A-MOLECULAR AND BIOMOLECULAR SPECTROSCOPY
(2024)
Article
Spectroscopy
Xiufeng Wang, Yao Jin, Wenhui Ai, Siqi Wang, Zhiqing Zhang, Ting Zhou, Fang Wang, Guodong Zhang
Summary: This study successfully synthesized near infrared fluorescence Ag2S quantum dots (QDs) and developed a dual-mode sensor for sulfide anion using the excellent oxidase-like characteristics of manganese dioxide (MnO2) nanosheets. The sensor showed a wider detection range, higher sensitivity, and shorter reaction time, making it suitable for highly selective detection of sulfide in different concentration ranges.
SPECTROCHIMICA ACTA PART A-MOLECULAR AND BIOMOLECULAR SPECTROSCOPY
(2024)
Article
Spectroscopy
Yafei Li, Yanming Ma, Chuantao Zheng, Di Yu, Lien Hu, Shuo Yang, Fang Song, Yadan Li, Shuanghai Liu, Zhanrui Zhang, Yu Zhang, Yiding Wang, Frank K. Tittel
Summary: To effectively monitor gas explosion and coal spontaneous combustion in coal mine, an intrinsically safe and explosion-proof dual-gas sensor system was developed for methane (CH4) and carbon monoxide (CO) measurement. The system achieved different measurement ranges using laser scanning and gas cells, and improved stability and accuracy through gas pre-treatment and temperature compensation algorithm.
SPECTROCHIMICA ACTA PART A-MOLECULAR AND BIOMOLECULAR SPECTROSCOPY
(2024)
Article
Spectroscopy
Pei-Rong Chen, Li-Kang Chu
Summary: In this study, the hydrates of glyoxal were investigated using infrared absorption spectrometry. The results showed that at low concentrations, glyoxal mainly exists as monomeric dihydrate. These findings provide suitable detection windows for further research on the roles of glyoxal and its hydrates in atmospheric and aerosol chemistry, as well as the relevant reaction kinetics.
SPECTROCHIMICA ACTA PART A-MOLECULAR AND BIOMOLECULAR SPECTROSCOPY
(2024)
Article
Spectroscopy
Nichole O'Neill, Thamires A. Lima, Fabio Furlan Ferreira, Nicolas J. Alvarez, Reinhard Schweitzer-Stenner
Summary: This study determines the main fibril axis of GHG gel-forming fibrils using various techniques and compares the results with simulated data. The analysis suggests that the hydrophobic xz-surfaces of GHG fibrils could be a good target for the adsorption of hydrophobic drugs.
SPECTROCHIMICA ACTA PART A-MOLECULAR AND BIOMOLECULAR SPECTROSCOPY
(2024)
Article
Spectroscopy
Mengyuan Liu, Hanchuang Zhu, Yikun Fang, Caiyun Liu, Xinke Li, Xiaohui Zhang, Lixue Ma, Kun Wang, Miaohui Yu, Wenlong Sheng, Baocun Zhu
Summary: ABHS is an efficient fluorescent probe that can accurately and sensitively detect Al3+ with strong resistance to interference. It also demonstrates excellent detection and imaging capabilities in complex real samples.
SPECTROCHIMICA ACTA PART A-MOLECULAR AND BIOMOLECULAR SPECTROSCOPY
(2024)
Article
Spectroscopy
Ahmed S. El-Shafie, Evana Rahman, Yasser Gadelhak, Rehab Mahmoud, Marwa El-Azary
Summary: The recycling of waste mandarin peels into biochar (MRBC) has been used as a high performance and cost-effective adsorbent for treating polluted wastewater effluents. Batch adsorption studies were conducted to analyze the adsorption competency of MRBC on two dyes, methylene blue (MB) and basic fuchsin (BF), either in individual solutions or binary combinations. The results showed that MRBC was capable of effectively removing a high percentage of both dyes. However, the adsorption capacity decreased when the dyes were combined. The cost estimation of MRBC production and wastewater treatment indicated that both were relatively low.
SPECTROCHIMICA ACTA PART A-MOLECULAR AND BIOMOLECULAR SPECTROSCOPY
(2024)
Article
Spectroscopy
Anindita Bhatta, Jahnabi Upadhyaya, Dipak Chamlagai, Lincoln Dkhar, Pynskhemborlang T. Phanrang, Mohan Rao Kollipara, Sivaprasad Mitra
Summary: Derivatives of thiazole-pyrazole fused benzo-coumarin compounds were synthesized and their photophysical properties were investigated. The synthesized coumarin compounds showed potential as therapeutic agents for Alzheimer's disease, inhibiting acetylcholinesterase activity. The presence of human serum albumin was found to affect the inhibition activity.
SPECTROCHIMICA ACTA PART A-MOLECULAR AND BIOMOLECULAR SPECTROSCOPY
(2024)
Article
Spectroscopy
Yongwei Duan, Quancheng Liu, Yiju Zhu, Qi Zhang, Xiaohui Duan, Hu Deng, Liping Shang
Summary: In this study, the phase transition of CL-20 was observed using terahertz spectroscopy, and quantum chemical calculations were employed to analyze the vibrations. The results indicated changes in the vibrations of CL-20 before and after phase transition.
SPECTROCHIMICA ACTA PART A-MOLECULAR AND BIOMOLECULAR SPECTROSCOPY
(2024)
Article
Spectroscopy
Yuefeng Gao, Sai Xu, Baojiu Chen
Summary: This study synthesized Cs2NaInCl6 nanocrystals co-doped with Sb3+ and Tb3+ ions as probes for copper ions detection in lubricating oil. The introduction of Sb3+ effectively reduced the band gap of the host material and enabled energy transfer pathway for Tb3+ emission. The doped Tb3+ ions resulted in the suppression of emission due to electron transfer. The Cs2NaInCl6: 2.5 %Sb3+, 40 %Tb3+ NCs exhibited superior sensitivity and selectivity for copper ions detection.
SPECTROCHIMICA ACTA PART A-MOLECULAR AND BIOMOLECULAR SPECTROSCOPY
(2024)
Article
Spectroscopy
Yu Liu, Yue Zhang, Changyao Liu, Ce Wang, Baocai Xu, Li Zhao
Summary: A highly sensitive detection platform for heparin was developed using a cationic fluorescent dye (cresyl violet acetate) as a fluorescence probe. The platform demonstrated high selectivity towards heparin and achieved detection in both HEPES solution and serum.
SPECTROCHIMICA ACTA PART A-MOLECULAR AND BIOMOLECULAR SPECTROSCOPY
(2024)
Article
Spectroscopy
Lopamudra Roy, Nivedita Pan, Susmita Mondal, Ria Ghosh, Md. Nur Hasan, Neha Bhattacharyya, Soumendra Singh, Kallol Bhattacharyya, Arpita Chattopadhyay, Samir Kumar Pal
Summary: The study focuses on the interaction between reactive oxygen species (ROS) and a spectroscopic probe called Rose Bengal (RB), encapsulated in nanoscopic sodium dodecyl sulphate (SDS) micelles and entrapped in microscopic nylon 66 solid matrix. The research demonstrates efficient interaction between ROS and RB-SDS, and investigates the mechanism of hydroxyl radicals generation. Based on these findings, a prototype device utilizing RB embedded in a nylon thin film for quantification of ROS in extracellular fluids and food materials was developed.
SPECTROCHIMICA ACTA PART A-MOLECULAR AND BIOMOLECULAR SPECTROSCOPY
(2024)
Article
Spectroscopy
Xiaosong Sun, Qihao Cui, Wenyue Dong, Qian Duan, Teng Fei
Summary: Conjugated porous polymers (CPPs) are promising sensing materials and their application in aqueous media is limited. In this study, we synthesized CPPs with porous structure and prepared nanoparticles, enabling efficient photoluminescence sensing of nitroaromatic explosives in aqueous phase.
SPECTROCHIMICA ACTA PART A-MOLECULAR AND BIOMOLECULAR SPECTROSCOPY
(2024)
Article
Spectroscopy
Maria Cristina Caggiani, Germana Barone, Paolo Mazzoleni
Summary: Raman spectroscopy is commonly used for studying glassy materials in cultural heritage, but it is more difficult to interpret the spectra and apply the technique with portable instruments. In contrast, diffuse reflectance infrared Fourier transform spectroscopy (DRIFTS) can be used in archaeometric investigations as it is portable and non-invasive. However, there is limited application of this technique to historical glasses. This exploratory work demonstrates the potential of DRIFTS, in combination with portable X-ray Fluorescence (pXRF) and EDS microanalyses, for studying the composition and alteration of glass samples in cultural heritage.
SPECTROCHIMICA ACTA PART A-MOLECULAR AND BIOMOLECULAR SPECTROSCOPY
(2024)