4.7 Article

Catalytic ozonation of p-nitrophenol over mesoporous Mn-Co-Fe oxide

期刊

SEPARATION AND PURIFICATION TECHNOLOGY
卷 133, 期 -, 页码 357-364

出版社

ELSEVIER SCIENCE BV
DOI: 10.1016/j.seppur.2014.07.011

关键词

p-Nitrophenol; Composite oxide; Catalytic ozonation; Surface property

资金

  1. National Natural Science Foundation of China [21207032]
  2. Natural Science Foundation of Hebei Province of China [B2012205012, B2013205028]

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Mesoporous composite metal oxides were prepared by an oxidation-precipitation method. The characterization studies indicated that the structure and surface property of the products could be controlled through simple manipulation of precursor composition. The activity of the synthesized catalysts for ozonation of p-nitrophenol (PNP) in aqueous solution was investigated. It was found that the negatively charged surface enhanced the adsorption and decomposition of ozone, but inhibited the adsorption of organic intermediates. This heterogeneous catalytic ozonation process should mainly follow a mechanism of surface reactions involving adsorbed ozone and organic molecules. Mn-Co-Fe exhibited the highest catalytic activity and stability for the mineralization of PNP due to its proper adsorption capacities for ozone and organic intermediates, which facilitated the surface reactions. (C) 2014 Elsevier B.V. All rights reserved.

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