Article
Materials Science, Multidisciplinary
Qihua Zhang, Xue Yin, Songrui Zhao
Summary: The AlGaN alloy system has potential for the development of semiconductor DUV lasers due to its unique properties, but faces challenges including dislocations, defects, and difficulty in obtaining p-type high-Al-content AlGaN layers. Recent advancements in AlGaN alloys grown by MBE have shown highly conductive p-type high-Al-content AlGaN epilayers and DUV lasers with nanowire structures.
PHYSICA STATUS SOLIDI-RAPID RESEARCH LETTERS
(2021)
Article
Chemistry, Multidisciplinary
Yimeng Song, Yingfeng He, Yangfeng Li, Huiyun Wei, Peng Qiu, Qianming Huang, Zhiquan He, Junhui Die, Mingzeng Peng, Xinhe Zheng
Summary: In this study, GaN thin films were grown directly on monolayer MoS2 for the first time using plasma-enhanced atomic layer deposition. Various characterization methods revealed the crystalline structure of GaN and the interface properties with mono-MoS2. The growth of GaN on MoS2 was found to follow the Stranski-Krastanov mode, with different growth phases observed depending on the ALD cycles.
CRYSTAL GROWTH & DESIGN
(2021)
Article
Physics, Applied
Rie Togashi, Ken Goto, Masataka Higashiwaki, Yoshinao Kumagai
Summary: Thermodynamic analyses were performed to study the growth of group-III sesquioxides by ozone and plasma-assisted MBE. The driving force for III2O3 growth increased with increasing input partial pressure of the group-III metal under O-rich conditions, but decreased under group-III-metal-rich conditions. This decrease was caused by the formation of Ga2O or In2O during growth. Ga and In droplets formed at low temperatures, while Al droplets were formed at high temperatures, with the growth order being c-In2O3 < ss-Ga2O3 << alpha-Al2O3.
JAPANESE JOURNAL OF APPLIED PHYSICS
(2023)
Article
Chemistry, Multidisciplinary
Iwan Susanto, Chi-Yu Tsai, Yen-Teng Ho, Ping-Yu Tsai, Ing-Song Yu
Summary: Van der Waals epitaxial GaN thin films were successfully grown on c-sapphire substrates with a sp(2)-bonded two-dimensional MoS2 buffer layer. Higher substrate temperatures during molecular beam epitaxy (MBE) growth led to improved crystallinity and optical properties of the GaN films, as well as smoother surface morphology and stable chemical composition. Exfoliation of the GaN/MoS2 heterostructure was also examined, revealing the largest granular structures with good crystallinity in films grown at 700 degrees C.
Article
Engineering, Electrical & Electronic
Arun Malla Chowdhury, Deependra Kumar Singh, Basanta Roul, K. K. Nanda, S. B. Krupanidhi
Summary: This study demonstrates a self-powered, broad band, and ultrafast photodetector based on nanorods/epilayer heterojunction, showing outstanding photodetection performance in UV, visible, and IR ranges. The maximum responsivity observed, along with response and recovery times, provides important insights for further research on the properties of such heterojunction devices.
ACS APPLIED ELECTRONIC MATERIALS
(2021)
Article
Chemistry, Multidisciplinary
Mustaqeem Shiffa, Benjamin T. Dewes, Jonathan Bradford, Nathan D. Cottam, Tin S. Cheng, Christopher J. Mellor, Oleg Makarovskiy, Kazi Rahman, James N. O'Shea, Peter H. Beton, Sergei V. Novikov, Teresa Ben, David Gonzalez, Jiahao Xie, Lijun Zhang, Amalia Patane
Summary: 2D semiconductors show great potential in various fields, but current fabrication methods have limitations. This study demonstrates a bottom-up approach for high-quality, wafer-scale 2SEM based on the wide band gap gallium selenide compound. The optical properties of the layers are utilized for photon sensing in the UV spectrum, offering a scalable route to deep-UV optoelectronics.
Article
Chemistry, Physical
Danhao Wang, Shubham Mondal, Pat Kezer, Mingtao Hu, Jiangnan Liu, Yuanpeng Wu, Peng Zhou, Tao Ma, Ping Wang, Ding Wang, John T. Heron, Zetian Mi
Summary: Incorporating scandium (Sc) into III-nitride lattice offers remarkable ferroelectric and optical properties. Yttrium (Y), a substitute for Sc, shows potential in alloyed III-nitride materials. In this study, we investigated the energy band gap alignment and transport properties of a YAlN-based HEMT structure. Experimental results showed promising electrical characteristics and compatibility with semiconductor technology, making it a significant development in next-generation HEMTs.
APPLIED SURFACE SCIENCE
(2023)
Article
Chemistry, Physical
Danhao Wang, Ding Wang, Peng Zhou, Mingtao Hu, Jiangnan Liu, Shubham Mondal, Tao Ma, Ping Wang, Zetian Mi
Summary: Through high-resolution X-ray photoelectron spectroscopy measurements, we discovered a thick oxide layer on ScAlN when exposed to air, which significantly affects its characterization and electronic structure evaluation. By excluding the possible impact from the surface oxide layer, the band alignment of Sc0.18Al0.82N/GaN can be accurately determined. Simulation results further demonstrate that the Sc0.18Al0.82N barrier layer offers excellent charge carrier confinement and a high density of two-dimensional electron gas (2DEG) at the heterostructure interface, crucial for high-performance GaN-based high electron mobility transistors (HEMTs).
APPLIED SURFACE SCIENCE
(2023)
Article
Materials Science, Multidisciplinary
Xia-Xi Zheng, Chun Wang, Jian-Hao Huang, Jen-Yao Huang, Daisuke Ueda, Krishna Pande, Chang Fu Dee, Ching Ting Lee, Edward-Yi Chang
Summary: This paper investigates the influence of group-III precursor injection rate on the material and electrical properties of InAlGaN/GaN heterostructures grown by Metalorganic Chemical Vapor Phase Deposition. It is demonstrated that high-quality GaN layers can be achieved by using the sputtered AlN/sapphire templates and optimized group-III injection rate, while maintaining high crystallinity and smooth surface of InAlGaN barrier layer.
Article
Nanoscience & Nanotechnology
Kenny Huynh, Michael E. Liao, Akhil Mauze, Takeki Itoh, Xingxu Yan, James S. Speck, Xiaoqing Pan, Mark S. Goorsky
Summary: The orientational dependence of interfacial reaction between aluminum and different β-Ga2O3 substrates (010, (001), and ((2) over bar 01)) was investigated. It was found that the orientation of β-Ga2O3 substrates influences the formation of aluminum oxide layers and diffusional pathways.
Article
Crystallography
Stephanie Tomasulo, Margaret A. Stevens, Jill A. Nolde, Nicole A. Kotulak, Michael K. Yakes
Summary: We investigated droplet epitaxy of Ga(As) on In0.53Ga0.47As and found an unexpected morphology of etched pits, tracks, and mounds instead of the dot and halo structure. Varying growth conditions revealed that the irregular morphology arose from competing diffusion lengths of In and Ga adatoms in Ga-rich conditions. Additionally, co-deposition experiments showed that In and Ga cannot form an alloyed droplet under the explored growth conditions, suggesting the possibility of self-segregation and phase separation.
JOURNAL OF CRYSTAL GROWTH
(2022)
Article
Chemistry, Multidisciplinary
Ara Ghukasyan, Nebile Isik Goktas, Vladimir G. Dubrovskii, Ray R. LaPierre
Summary: Transmission electron microscopy was used to investigate the formation of TSLs in Te-doped GaAs nanowires grown by selective-area molecular beam epitaxy, revealing periodic TSLs only at low V/III flux ratio and intermediate growth temperatures. These results were explained by a kinetic growth model based on diffusion flux feeding the Ga droplet.
Article
Physics, Condensed Matter
Mario Littmann, Dirk Reuter, Donat Josef As
Summary: Remote epitaxy, a new area of research, has the potential to reduce lattice mismatch and simplify film exfoliation. This study focuses on applying this growth method to cubic gallium nitride (c-GaN), a metastable phase. However, nucleating the metastable cubic phase is challenging due to weaker interactions between the substrate and the epitaxial layer. Initially, only polycrystalline wurtzite gallium nitride could be grown, but by optimizing conditions and adding a cubic aluminum nitride buffer layer, predominantly cubic gallium nitride layers can be grown. High-resolution X-ray diffraction measurements confirm a reduction in hexagonal inclusions from 80% to 23%.
PHYSICA STATUS SOLIDI B-BASIC SOLID STATE PHYSICS
(2023)
Article
Physics, Condensed Matter
Xue Yin, Songrui Zhao
Summary: By growing the AlGaN active layer at a higher temperature, the lasing threshold of the AlGaN/AlN laser has been significantly reduced, with successful control of Al vacancy related point defects demonstrated by the absence of defect emission in the visible band.
PHYSICA STATUS SOLIDI B-BASIC SOLID STATE PHYSICS
(2021)
Article
Materials Science, Multidisciplinary
J. J. Cabrera-Montealvo, L. I. Espinosa-Vega, L. M. Hernandez-Gaytan, C. A. Mercado-Ornelas, F. E. Perea-Parrales, A. Belio-Manzano, C. M. Yee-Rendon, A. G. Rodriguez, V. H. Mendez-Garcia, I. E. Cortes-Mestizo
Summary: By characterizing the GaNAs/GaAs system grown by Molecular Beam Epitaxy with different GaNAs layer thicknesses and similar nitrogen concentration (%N), we show that in the optimization of nitrogen inclusion through rapid thermal annealing, factors such as thickness and strain need to be considered in addition to nitrogen concentration (%N).
Article
Physics, Condensed Matter
Mylene Sauty, Natalia Alyabyeva, Cheyenne Lynsky, Yi Chao Chow, Shuji Nakamura, James S. Speck, Yves Lassailly, Alistair C. H. Rowe, Claude Weisbuch, Jacques Peretti
Summary: In this study, scanning tunneling electroluminescence microscopy was used to investigate the unique radiative recombination properties near a defect in an InGaN/GaN quantum well. The results revealed intense emission peaks at higher energies close to the defect edges, which were not visible in the macrophotoluminescence spectrum. The quantitative information obtained from fitting the local tunneling electroluminescence spectra provided important insights into carrier localization in the quantum well.
PHYSICA STATUS SOLIDI B-BASIC SOLID STATE PHYSICS
(2023)
Article
Engineering, Electrical & Electronic
R. M. Cadena, D. R. Ball, E. X. Zhang, S. Islam, A. Senarath, M. W. McCurdy, E. Farzana, J. S. Speck, N. Karom, A. O'Hara, B. R. Tuttle, S. T. Pantelides, A. F. Witulski, K. F. Galloway, M. L. Alles, R. A. Reed, D. M. Fleetwood, R. D. Schrimpf
Summary: Low-energy ion-induced breakdown and single event burnout (SEB) were observed in beta-gallium oxide (beta-Ga2O3) Schottky diodes at voltages lower than expected. Different responses were observed for alpha particles, Cf-252, and heavy-ion irradiation. TCAD simulations explained the breakdown as a result of ion strikes and defect-driven breakdown due to displacement-damage-induced defects in beta-Ga2O3. First-principles calculations showed the formation of less resistive defect clusters that can lead to destruction at reduced voltages.
IEEE TRANSACTIONS ON NUCLEAR SCIENCE
(2023)
Article
Physics, Applied
Feng Wu, Jacob Ewing, Cheyenne Lynsky, Michael Iza, Shuji Nakamura, Steven P. DenBaars, James S. Speck
Summary: In this article, the authors used advanced characterization techniques to study the active region compositions, V-defect formation, and V-defect structure in green and red LEDs. They identified two types of V-defects, one that promotes hole injection and one that is believed to be deleterious to high-efficiency LEDs.
JOURNAL OF APPLIED PHYSICS
(2023)
Article
Optics
Panpan Li, Hongjian Li, Yifan Yao, Kai Shek Qwah, Mike Iza, James S. Speck, Shuji Nakamura, Steven P. Denbaars
Summary: In this work, we demonstrate the vertical integration of nitride-based blue/green micro-light-emitting diode (mu LED) stacks with independent junction control using a hybrid tunnel junction (TJ). The hybrid TJ was grown by metal-organic chemical vapor deposition (p + GaN) and molecular-beam epitaxy (n + GaN). Different junction diodes were able to generate uniform blue, green, and blue/green emissions. The peak external quantum efficiency (EQE) of the TJ blue mu LEDs and green mu LEDs with indium tin oxide contact were 30% and 12%, respectively. Carrier transportation between different junction diodes was discussed. This work suggests a promising approach for vertical mu LED integration to enhance the output power of single LED chips and monolithic mu LEDs with different emission colors and independent junction control.
Article
Engineering, Electrical & Electronic
M. Ikram Md Taib, M. A. Ahmad, E. A. Alias, A. Alhassan, I. A. Ajia, M. M. Muhammed, I. S. Roqan, S. P. DenBaars, J. S. Speck, S. Nakamura, N. Zainal
Summary: In-surfactant was introduced during the growth of high temperature GaN quantum barriers and GaN interlayer in InGaN/GaN green LEDs. Results showed that the introduction of In-surfactant improved LED growth, particularly in the GaN interlayer. It improved the morphology of the interlayer, allowed it to serve as a good surface growth, and effectively improved the multi-quantum wells. Moreover, the introduction of In-surfactant shifted the emission wavelength towards red, reduced the forward voltage of the LEDs, and allowed faster carrier decay lifetime.
SEMICONDUCTOR SCIENCE AND TECHNOLOGY
(2023)
Article
Nanoscience & Nanotechnology
Matthew S. Wong, Aditya Raj, Hsun-Ming Chang, Vincent Rienzi, Feng Wu, Jacob J. Ewing, Emily S. Trageser, Stephen Gee, Nathan C. Palmquist, Philip Chan, Ji Hun Kang, James S. Speck, Umesh K. Mishra, Shuji Nakamura, Steven P. DenBaars
Summary: The electrical performance of III-nitride blue micro-light-emitting diodes (mu LEDs) with different tunnel junction (TJ) architectures grown by metalorganic chemical vapor deposition is investigated. The introduction of AlGaN layer above the n-side of the TJ layer improves the current density-voltage characteristic and the effects of AlGaN/GaN superlattices are examined. The band diagram simulation shows that a net positive polarization charge is formed at the AlGaN/GaN interface, leading to a reduction in tunneling distance and an increase in tunneling probability. Additionally, the proposed AlGaN-enhanced TJ design significantly enhances the wall-plug efficiency of mu LEDs.
Article
Physics, Applied
Panpan Li, Hongjian Li, Yunxuan Yang, Matthew S. Wong, Mike Iza, Michael J. Gordon, James S. Speck, Shuji Nakamura, Steven P. DenBaars
Summary: This article presents high-performance 10 x 10 μm InGaN amber micro-size LEDs. At 15 A cm(-2), the InGaN micro LEDs exhibit a single emission peak at 601 nm. The peak external quantum efficiency (EQE) and wall-plug efficiency are 5.5% and 3.2%, respectively. Compared to the 100 x 100 μm InGaN red micro LEDs, the 10 x 10 μm InGaN red micro LEDs maintain a similar EQE value with the same efficiency droop. These results highlight the higher efficiency potential of InGaN materials compared to common AlInGaP materials for the ultra-small size red micro LEDs required by augmented reality and virtual reality displays.
APPLIED PHYSICS EXPRESS
(2023)
Article
Physics, Applied
Wan Ying Ho, Yi Chao Chow, Shuji Nakamura, Jacques Peretti, Claude Weisbuch, James S. Speck
Summary: Electron emission spectroscopy was performed on metalorganic chemical vapor deposition grown p-n(-)-n(+) junctions with p-thicknesses ranging from 50 to 300 nm, doped with [Mg] = 3.5 x 10(19) cm(-3). By measuring the decreasing emitted electron intensity from a cesiated p-GaN surface with increasing p-thickness, we were able to extract the minority carrier diffusion length of electron in p-type GaN, L-e = 2663 nm. The measured value is in good agreement with literature reported values. The extrapolated electron current at the n(-) region p-GaN interface is in reasonable agreement with the simulated electron current at the interface.
APPLIED PHYSICS LETTERS
(2023)
Article
Physics, Applied
Fikadu Alema, Takeki Itoh, William Brand, Andrei Osinsky, James S. Speck
Summary: We investigated the controllable nitrogen doping of beta-Ga2O3 using ammonia diluted in nitrogen as a source of active nitrogen. The study looked at the effects of flow rate and substrate temperature on the doping efficiency and reproducibility. By increasing the flow rate of NH3/N-2, the nitrogen impurities incorporated into beta-Ga2O3 increased linearly. The presence of hydrogen in the film accompanied the nitrogen doping at low substrate temperatures.
APPLIED PHYSICS LETTERS
(2023)
Article
Physics, Applied
Y. C. Chow, C. Lynsky, S. Nakamura, S. P. DenBaars, C. Weisbuch, J. S. Speck
Summary: Efficiency droop at high current densities is a common problem for InGaN-based LEDs, especially for conventional c-plane devices. This study introduces a method to reduce the internal electric fields in c-plane quantum wells by using doped barriers, which allows for a thick active region design and leads to improved LED performance.
JOURNAL OF APPLIED PHYSICS
(2023)
Article
Optics
J. Mickevic, E. Valkiunaite, Z. Podlipskas, K. Nomeika, S. Nargelas, G. Tamulaitis, Y. C. Chow, S. Nakamura, J. S. Speck, C. Weisbuch, R. Aleksieju
Summary: The dynamics of two distinct bands in non-polar m-plane InGaN/GaN multiple quantum wells (MQWs) were investigated using PL, CL, and DT spectroscopy. The shift in peak emission wavelength with increasing excitation was caused by competition between these bands. DT measurements attributed the high-energy PL band to optical transitions between ground QW states, while the low-energy PL band was associated with recombination of localized carriers. CL measurements confirmed the dispersion of deep localized states and suggested small-scale disorder. PL measurements showed that localized states are highly sensitive to indium content and structural parameters. Temperature-dependent PL studies revealed strong carrier-phonon interaction.
JOURNAL OF LUMINESCENCE
(2023)
Article
Nanoscience & Nanotechnology
Panpan Li, Hongjian Li, Yifan Yao, Norleakvisoth Lim, Matthew Wong, Mike Iza, Michael J. Gordon, James S. Speck, Shuji Nakamura, Steven P. DenBaars
Summary: We have shown a significant improvement in the quantum efficiency of InGaN red micro-light-emitting diodes (mu LEDs). The peak external quantum efficiency (EQE) of the packaged 80 x 80 mu m(2) InGaN red mu LEDs increased to 6.0% at 12A/cm(2), indicating a significant advancement in the efficiency exploration of InGaN red mu LEDs. The enhancement in EQE is attributed to improved quantum efficiency, confirmed by electron-hole wavefunction overlap and photoluminescence intensity ratio analysis. Additionally, ultrasmall 5x 5 mu m(2) InGaN red mu LEDs were obtained with a high peak EQE of 4.5%.
Article
Nanoscience & Nanotechnology
Takeki Itoh, Akhil Mauze, Yuewei Zhang, James S. Speck
Summary: Continuous Si doping in beta-Ga2O3 epitaxial films was achieved using plasma-assisted molecular beam epitaxy with a valved effusion cell for the Si source. Secondary ion mass spectroscopy results indicated flat and sharply turned Si doping profiles in beta-Ga2O3. The Si doping concentration could be controlled by adjusting the cell temperature or the valve aperture of the Si effusion cell. High crystal quality and smooth surface morphologies were observed in Si-doped beta-Ga2O3 films grown on (010) and (001) substrates. The Si-doped (001) beta-Ga2O3 epitaxial film exhibited an electron mobility of 67 cm(2)/Vs at a Hall concentration of 3 x 10(18) cm(-3).
Article
Physics, Applied
Wan Ying Ho, Cameron W. Johnson, Tanay Tak, Mylene Sauty, Yi Chao Chow, Shuji Nakamura, Andreas Schmid, Jacques Peretti, Claude Weisbuch, James S. Speck
Summary: In this study, the lateral distribution of the junction current in an electrical biased p-n GaN diode was measured using electron emission microscopy with a low-energy electron microscope. The vacuum level on the diode surface was reduced by cesium deposition to achieve negative electron affinity, allowing emitted overflow electrons on the biased diode surface to be imaged for their spatial distribution. The obtained results were compared with Joyce and Wemple's analytical solutions [J. Appl. Phys. 41, 3818 (1970)] and showed a good match.
APPLIED PHYSICS LETTERS
(2023)
Article
Materials Science, Multidisciplinary
Wan Ying Ho, Abdullah I. Alhassan, Cheyenne Lynsky, Yi Chao Chow, Daniel J. Myers, Steven P. DenBaars, Shuji Nakamura, Jacques Peretti, Claude Weisbuch, James S. Speck
Summary: Using electron emission spectroscopy, researchers measured and analyzed the energy distribution of vacuum emitted electrons from electrically driven InGaN/GaN green light emitting diodes (LEDs) with and without a prewell superlattice (SL). They discovered a high-energy upper valley peak at approximately 1.7 eV above the I' valley in samples without a prewell SL, which is attributed to trap-assisted Auger recombination (TAAR). The absence of this peak in the sample with a prewell SL suggests the gettering of unidentified impurities that act as TAAR centers.