Article
Materials Science, Multidisciplinary
C. Yuan, M. Park, Y. Zheng, J. Shi, R. Dargis, S. Graham, A. Ansari
Summary: This study investigates phonon scattering processes and thermal conductivity in Al1-xScxN alloys grown by molecular beam epitaxy. The results show a decreasing trend in thermal conductivity with increasing scandium content, with an increase in thermal conductivity with temperature below 200 K and a plateau at higher temperatures. Application of an analytical model helps estimate the effects of scattering mechanisms on thermal conductivity behavior.
MATERIALS TODAY PHYSICS
(2021)
Article
Materials Science, Multidisciplinary
Yangyu Guo, Xiao-Ping Luo, Zhongwei Zhang, Samy Merabia, Masahiro Nomura, Sebastian Volz
Summary: The phonon hydrodynamic regime in graphite films has been experimentally studied, but understanding and modeling of heat transport along the basal plane is still unclear. We predict that surface roughness significantly affects basal-plane thermal conductivity due to collective phonon drift. The occurrence of the phonon Knudsen minimum also depends strongly on surface roughness. We summarize basal-plane heat transport into coherent and incoherent regimes and speculate on the observed thickness-dependent thermal conductivity. Our work provides guidance for future experimental explorations of phonon hydrodynamics in graphitic micro- and nanostructures.
Article
Chemistry, Multidisciplinary
Xinglin Xiao, Yali Mao, Biwei Meng, Guoliang Ma, Kristina Husekova, Fridrich Egyenes, Alica Rosova, Edmund Dobrocka, Peter Elias, Milan Tapajna, Filip Gucmann, Chao Yuan
Summary: Different phases of Ga2O3 have distinct thermal transport properties. The thermal conductivity (TC) of alpha-Ga2O3 is larger than that of beta and kappa-Ga2O3, while the TC of bulk alpha and beta-Ga2O3 are similar. The thermal boundary conductance (TBC) at the Ga2O3/sapphire interface shows phase-dependence. This study provides insight into the phonon transport mechanism and contributes to the thermal management of Ga2O3-based devices.
Article
Chemistry, Multidisciplinary
Fengju Yao, Shunji Xia, Haoxiang Wei, Jiongzhi Zheng, Ziyuan Yuan, Yusheng Wang, Baoling Huang, Deyu Li, Hong Lu, Dongyan Xu
Summary: This study provides direct experimental evidence that superdiffusive thermal transport exists in SiGe alloys, as the thermal conductivity follows a power law relationship with film thickness. This research is significant for understanding the unique phenomenon of heat conduction.
Article
Physics, Applied
T. J. Spence, Arden L. Moore
Summary: This study uses Monte Carlo methods to simulate phonon transport in silicon thin films and finds that thin film source-drain reservoirs do not behave as semi-infinite reservoirs for specific sizes. Existing analytical models cannot be applied to such systems directly. Additionally, the study supports the idea that ballistic phonon effects are small in silicon nanowires at room temperature.
JOURNAL OF APPLIED PHYSICS
(2022)
Article
Chemistry, Physical
Katir Ziouche, Ibrahim Bel-Hadj, Zahia Bougrioua
Summary: This paper discusses the optimization of electrical and thermoelectrical properties of nanostructured polysilicon material for use in thermoelectric devices. The nanostructured porous polysilicon (POpSi) thin film is shown to significantly reduce thermal conductivity while maintaining Seebeck coefficient, resulting in a substantial improvement in ZT compared to standard polySi layers. The integration of POpSi into planar TE microgenerators leads to a 28% increase in simulated conversion efficiency compared to those using standard polySi layers.
Article
Acoustics
K. Herrmann, N. W. Pech-May, M. Retsch
Summary: The photoacoustic measurement technique is a powerful method for characterizing thermal transport properties of thin films, particularly in isotropic low thermal diffusivity samples. Significant influence of thermal effusivity, thermal diffusivity, and sample layer thickness on the measurement accuracy is discussed. The method allows for direct extraction of thermal conductivity without separate determination of heat capacity when appropriate boundary conditions are met.
Article
Nanoscience & Nanotechnology
Yiwen Song, Praneeth Ranga, Yingying Zhang, Zixuan Feng, Hsien-Lien Huang, Marco D. Santia, Stefan C. Badescu, C. Ulises Gonzalez-Valle, Carlos Perez, Kevin Fern, Robert M. Lavelle, David W. Snyder, Brianna A. Klein, Julia Deitz, Albert G. Baca, Jon-Paul Maria, Bladimir Ramos-Alvarado, Jinwoo Hwang, Hongping Zhao, Xiaojia Wang, Sriram Krishnamoorthy, Brian M. Foley, Sukwon Choi
Summary: This study investigates the thermal conductivity of heteroepitaxial beta-Ga2O3 films, and finds that the thermal conductivity is strongly influenced by film thickness, crystallinity, and substrate offcut angles. Additionally, the thermal conductivity of ((2) over bar 01)-oriented beta-(AlxGal)(2)O-3 thin films grown via MOVPE was characterized, with results showing lower conductivity due to phonon-alloy disorder scattering. These findings provide fundamental insights for the development of beta-Ga2O3 electronic and optoelectronic devices.
ACS APPLIED MATERIALS & INTERFACES
(2021)
Article
Nanoscience & Nanotechnology
Ashutosh Giri, Ramez Cheaito, John T. Gaskins, Takanori Mimura, Harlan J. Brown-Shaklee, Douglas L. Medlin, Jon F. Ihlefeld, Patrick E. Hopkins
Summary: Experimental results show that thermal resistance may not increase with the addition of confined solid-solution films of varying thicknesses between parent materials. This contradicts the conventional understanding that adding more material leads to larger thermal resistances. The results potentially support the concept of vibrational matching across interfaces, suggesting that adding a thin vibrational bridge layer between two solids could enhance thermal boundary conductance.
ACS APPLIED MATERIALS & INTERFACES
(2021)
Article
Energy & Fuels
Heegyeom Jeon, Jeong Ho Na, Yong Seok Kim, Seung-Keun Park, Youngjae Yoo
Summary: In this study, wave-selective emitter coolers were fabricated using glass bubbles and barium sulfate, and polyacrylonitrile nanofibers were electrospun on these coolers. The optical properties and cooling power were analyzed based on the ratio of glass bubbles and barium sulfate, as well as the electrospinning conditions. The cooler with the added electrospinning layer showed higher reflectivity and cooling power compared to the cooler containing only polydimethylsiloxane/glass bubbles and barium sulfate. This study improves the performance of previously studied passive radiative cooling.
SOLAR ENERGY MATERIALS AND SOLAR CELLS
(2023)
Article
Physics, Applied
Sien Wang, Qiyu Chen, Qing Hao
Summary: This study investigates the heat exchange between a solid material and the gas environment in miniature electronic devices. A two-layer model is proposed to evaluate the heat transfer coefficient of nanoporous Si thin films. The results confirm the dominance of air conduction in the heat transfer process and suggest the potential of increasing the heat transfer coefficient by introducing ultra-fine nanoporous patterns.
APPLIED PHYSICS LETTERS
(2022)
Article
Engineering, Electrical & Electronic
Thiet Van Duong, Nguyen Xuan Chung, Hong Ngoc Phan, Hong Tuan Nguyen, Dung Dinh Nguyen, Lu Trong Le, Nhat Van Pham
Summary: SnSe nanosheets and nanostructured thin films were successfully synthesized using sonication-assisted exfoliation and coating process. The nanosheets had a uniform lateral size, with an average thickness of 2.82 nm and an average area of 280 nm(2), consisting of two to three single layers. The characterization using scanning electron microscope, transmission electron microscope, and atomic force microscope confirmed the results. The SnSe nanostructured thin films had various thicknesses ranging from 350 to 650 nm, with the highest power factor value achieved at 450 nm in the temperature range of 375-600 K. The study also introduced a simple method of fabrication and controllable thermoelectric properties of SnSe nanostructured thin films as well as other two-dimensional (2D) materials.
JOURNAL OF MATERIALS SCIENCE-MATERIALS IN ELECTRONICS
(2022)
Article
Nanoscience & Nanotechnology
Gabriel Velarde, Shishir Pandya, J. Karthik, David Pesquera, Lane W. Martin
Summary: This review discusses recent advances in thin-film pyroelectrics, highlighting the complex physical phenomena and history in this field, and emphasizing the importance of controlling thin-film materials. The review also explores recent advancements in thin-film pyroelectric devices and potential future research directions.
Article
Chemistry, Multidisciplinary
Christopher Perez, Aaron J. Mcleod, Michelle E. Chen, Su-In Yi, Sam Vaziri, Ryan Hood, Scott T. Ueda, Xinyu Bao, Mehdi Asheghi, Woosung Park, A. Alec Talin, Suhas Kumar, Eric Pop, Andrew C. Kummel, Kenneth E. Goodson
Summary: Aluminum nitride (AlN) is an electrically insulating material with excellent thermal conductivity. This study demonstrates the deposition of AlN films at low temperatures using sputtering, and analyzes their thermal properties based on grain size and interfacial quality. The results show that varying the partial pressure of reactive N2 can significantly alter the thermal conductivity of the films, and the defect densities can be estimated from the measurements, providing insights for optimizing the thermal engineering of AlN.
Article
Chemistry, Physical
Cristina Manzano, Cristina Llorente del Olmo, Olga Caballero-Calero, Marisol Martin-Gonzalez
Summary: The research focuses on developing a new sustainable, easily scalable, and cost-effective electrochemical deposition method to fabricate stable silver selenide films, and analyzing their thermoelectric properties. Films with similar properties were successfully deposited on a flexible Kapton substrate using electrodeposition techniques.
SUSTAINABLE ENERGY & FUELS
(2021)
Article
Materials Science, Multidisciplinary
Maksim Naumochkin, Gyu-Hyeon Park, Kornelius Nielsch, Heiko Reith
Summary: This study presents the full TE characterization of sputtered Bi2Te3 thin films for micro-TE device fabrication, revealing the influence of thickness and annealing conditions on their ZT values.
PHYSICA STATUS SOLIDI-RAPID RESEARCH LETTERS
(2022)
Article
Physics, Applied
Sami Alajlouni, David Alberto Lara Ramos, Kerry Maize, Nicolas Perez, Kornelius Nielsch, Gabi Schierning, Ali Shakouri
Summary: We introduce a noncontact experimental method for estimating the thermal conductivity of nanoscale thin films by fitting high spatial resolution thermoreflectance images of surface spot heating. The method offers advantages of easy sample preparation, rapid in situ measurement, and applicability to a broad range of thin-film materials.
JOURNAL OF APPLIED PHYSICS
(2022)
Article
Chemistry, Multidisciplinary
Jun Yang, Amin Bahrami, Xingwei Ding, Sebastian Lehmann, Nadine Kruse, Shiyang He, Bowen Wang, Martin Hantusch, Kornelius Nielsch
Summary: This study investigates the deposition of ZnO thin films using atomic layer deposition (ALD) with diethylzinc as the zinc source and H2O and H2O2 as oxygen sources. The results show that H2O2 provides an oxygen-rich environment, suppressing the oxygen vacancies and resulting in lower carrier concentration and higher resistivity. Additionally, the lower growth rate leads to ZnO thin films growing along the lower surface energy direction, leading to lower Hall mobility. Furthermore, ZnO thin films are integrated into thin film transistor (TFT) devices and their electrical properties are analyzed, demonstrating promising results for potential application in metal-oxide electronics optimization.
ADVANCED MATERIALS INTERFACES
(2022)
Review
Engineering, Electrical & Electronic
Qihao Zhang, Kangfa Deng, Lennart Wilkens, Heiko Reith, Kornelius Nielsch
Summary: This review examines the development of micro-thermoelectric devices, exploring progress in device design, integration, and performance, as well as the potential applications of the technology in cooling, power generation, and sensing. These devices offer faster response time, higher resolution, and greater power density compared to their commercial counterparts, making them crucial for highly integrated electronic devices, the Internet of Things, and flexible and wearable technology.
NATURE ELECTRONICS
(2022)
Article
Physics, Applied
Jun Yang, Amin Bahrami, Xingwei Ding, Sebastian Lehmann, Kornelius Nielsch
Summary: The study demonstrated a novel strategy for improving the mechanical and electrical properties of flexible silver nanowire thin films, utilizing ethanol mist welding at room temperature and aluminum-doped zinc oxide coating to achieve high transmittance and low sheet resistance. The addition of ultrathin antimony oxide film provided protection against water or oxygen degradation, maintaining conductivity after bending and chemical exposure. The integrated W-Ag NW/AZO/SbOx layer showed superior electrical stability on low-power operating flexible Ti-ZnO thin film transistors, with high field-effect mobility and I-on/I-off ratio.
APPLIED PHYSICS LETTERS
(2022)
Article
Materials Science, Multidisciplinary
Stefan Schwabe, Klara Luenser, Daniel Schmidt, Kornelius Nielsch, Peter Gaal, Sebastian Faehler
Summary: This study demonstrates that a thermoelastic martensite to austenite transformation can be completed within 10 ns, and the temperature has an influence on the transformation rate.
SCIENCE AND TECHNOLOGY OF ADVANCED MATERIALS
(2022)
Article
Chemistry, Multidisciplinary
Niloofar Soltani, Syed Muhammad Abbas, Martin Hantusch, Sebastian Lehmann, Kornelius Nielsch, Amin Bahrami, Daria Mikhailova
Summary: The electrochemical performance of CoSn2 and Ni3Sn4 as anode materials in lithium-ion batteries can be improved by depositing an alumina layer using the atomic layer deposition (ALD) technique. Coated electrodes showed higher capacity at high current densities, but exhibited faster decay in cycling performance at low current densities. The composition of the solid-electrolyte interface strongly influenced the electrochemical performance.
ADVANCED MATERIALS INTERFACES
(2022)
Article
Physics, Applied
Mickey Martini, Helena Reichlova, Yejin Lee, Dominika Dusikova, Jan Zemen, Kornelius Nielsch, Andy Thomas
Summary: In this study, we analyze magneto-thermal transport data in IrMn/FeCo bilayers based on the Mott relation and observe an enhancement of the Nernst response near the blocking temperature. We measure all four transport coefficients and find a discrepancy between the measured Nernst coefficient and the one calculated using the Mott rule around the blocking temperature, which we attribute to spin fluctuations at the antiferromagnet/ferromagnet interface.
APPLIED PHYSICS LETTERS
(2022)
Article
Materials Science, Multidisciplinary
Kangfa Deng, Qihao Zhang, Yangxi Fu, Andres Fabian Lasagni, Heiko Reith, Kornelius Nielsch
Summary: This article presents a novel fabrication technique named PowderMEMS for high-performance, low-cost TE films and micro-patterns. The TE film is composed of agglomerated micro-sized N-type Bi2Te2.5Se0.5 powders with a molten binder of bismuth (Bi). The influence of key process parameters on TE performance is investigated, and the TE film exhibits a maximum power factor of 1.7 mW m-1K-2 at room temperature, the highest value reported so far.
ADVANCED ENGINEERING MATERIALS
(2023)
Article
Chemistry, Physical
Ruben Bueno Villoro, Duncan Zavanelli, Chanwon Jung, Dominique Alexander Mattlat, Raana Hatami Naderloo, Nicolas Perez, Kornelius Nielsch, Gerald Jeffrey Snyder, Christina Scheu, Ran He, Siyuan Zhang
Summary: By using scanning transmission electron microscopy and atom probe tomography, this study revealed the structural differences of hexagonal close-packed lattice phases at grain boundaries in Ti-doped NbFeSb half-Heusler compounds. It was found that the enrichment of Fe leads to high electrical resistivity in Nb0.95Ti0.05FeSb, while the accumulation of Ti dopants results in good electrical conductivity in Nb0.80Ti0.20FeSb. This resistive to conductive grain boundary phase transition provides a new design space for decoupling the intertwined electronic and phononic transport in thermoelectric materials.
ADVANCED ENERGY MATERIALS
(2023)
Article
Materials Science, Multidisciplinary
Klara Luenser, Andreas Undisz, Kornelius Nielsch, Sebastian Faehler
Summary: Understanding and optimizing the martensitic microstructure of nickel-titanium (NiTi) thin films is important for their applications in microsystems. Epitaxial films grown on single-crystalline substrates provide a model system to study the microstructure and exploit the anisotropic mechanical properties of NiTi. By analyzing the growth of NiTi on MgO(100) and Al2O3(0001), we achieve epitaxial films with desired orientations and demonstrate the effect of buffer layers on crystal quality and transformation behavior. Transmission electron microscopy confirms the presence of a martensitic microstructure with Guinier Preston-zone precipitates. This study provides valuable insights into the development of NiTi thin films with optimized properties.
JOURNAL OF PHYSICS-MATERIALS
(2023)
Article
Materials Science, Multidisciplinary
Satyakam Kar, Kornelius Nielsch, Sebastian Faehler, Heiko Reith
Summary: This article investigates different etching techniques for the microfabrication of magnetic shape memory alloys, compares their advantages and disadvantages, and proposes methods to overcome challenges. The results show that wet chemical etching is suitable for large structures, while ion beam etching is suitable for small structures. Finally, a microfabrication process using Si microtechnology to fabricate partially freestanding structures is demonstrated.
ADVANCED ENGINEERING MATERIALS
(2023)
Article
Chemistry, Multidisciplinary
Lukas Fink, Satyakam Kar, Klara Luenser, Kornelius Nielsch, Heiko Reith, Sebastian Faehler
Summary: Magnetic shape memory alloys have multifunctional properties and can be used for high stroke actuation, magnetocaloric refrigeration, and thermomagnetic energy harvesting. This study demonstrates the epitaxial growth of Ni-Mn-based Heusler alloys with single crystal-like properties on silicon substrates using a SrTiO3 buffer. It shows that standard microfabrication technologies can be used to prepare partly freestanding patterns. The approach is versatile and can be applied to NiTi shape memory alloys as well as spintronic and thermoelectric Heusler alloys, paving the way for integrating additional multifunctional effects into state-of-the-art microelectronic and micromechanical technology based on silicon.
ADVANCED FUNCTIONAL MATERIALS
(2023)
Article
Multidisciplinary Sciences
Wuyang Ren, Wenhua Xue, Shuping Guo, Ran He, Liangzi Deng, Shaowei Song, Andrei Sotnikov, Kornelius Nielsch, Jeroen van den Brink, Guanhui Gao, Shuo Chen, Yimo Han, Jiang Wu, Ching-Wu Chu, Zhiming Wang, Yumei Wang, Zhifeng Ren
Summary: Studies have shown that vacancy-mediated anomalous transport properties are flourishing in various fields due to their fascinating effects on photoelectric, ferroelectric, and spin-electric behaviors in solid materials. In this study, the authors reveal the multifunctionality of vacancy in tailoring the transport properties of a defective half-Heusler ZrNiBi material, providing insights into the phononic and electronic transport processes. These findings not only demonstrate the potential of this thermoelectric material but also promote further exploration of vacancy-mediated transport properties.
NATURE COMMUNICATIONS
(2023)
Article
Chemistry, Physical
Jonas Wawra, Kornelius Nielsch, Ruben Huehne
Summary: Substrate-induced strains can significantly affect the structural and functional properties of epitaxial thin films. By growing epitaxial Ba0.7Sr0.3TiO3 films on REScO3 substrates with smaller lattice mismatch, the quality of the films was improved compared to SrTiO3. The strain state of the functional layer depended on the substrate and thickness, leading to differences in permittivity and polarization behavior at different temperatures.