Stereocontrolled 1,2-cis glycosylation as the driving force of progress in synthetic carbohydrate chemistry

New Strategies for the Synthesis of Bio-medically Relevant Oligosaccharides: Recent Updates on 1,2-cis-O-Glycosylation and α-O-Sialylation

(2016) Stefano Crotti et al.   CURRENT ORGANIC SYNTHESIS

C6 picoloyl protection: a remote stereodirecting group for 2-deoxy-β-glycoside formation

(2015) Jyh-Herng Ruei et al.   CHEMICAL COMMUNICATIONS

Hydrogen-Bond-Mediated Aglycone Delivery (HAD): A Highly Stereoselective Synthesis of 1,2-cisα-D-Glucosides from Common Glycosyl Donors in the Presence of Bromine

(2015) Jagodige P. Yasomanee et al.   CHEMISTRY-A EUROPEAN JOURNAL

Synthesis of the Highly Glycosylated Hydrophilic Motif of Extensins

(2014) Akihiro Ishiwata et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Hydrogen Bond Mediated Aglycone Delivery: Synthesis of Linear and Branched α-Glucans

(2014) Jagodige P. Yasomanee et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

A New Chemical Approach to Human ABO Histo-Blood Group Type 2 Antigens

(2014) Atsushi Hara et al.   MOLECULES

1,2-cis Alkyl glycosides: straightforward glycosylation from unprotected 1-thioglycosyl donors

(2014) Bo Meng et al.   ORGANIC & BIOMOLECULAR CHEMISTRY

Hydrogen-Bond-Mediated Aglycone Delivery: Focus on β-Mannosylation

(2014) Salvatore G. Pistorio et al.   ORGANIC LETTERS

Cooperative Catalysis in Glycosidation Reactions withO-Glycosyl Trichloroacetimidates as Glycosyl Donors

(2013) Yiqun Geng et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Chiral Brønsted Acid Mediated Glycosylation with Recognition of Alcohol Chirality

(2013) Tomoya Kimura et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Is an acyl group at O-3 in glucosyl donors able to control α-stereoselectivity of glycosylation? The role of conformational mobility and the protecting group at O-6

(2013) Bozhena S. Komarova et al.   CARBOHYDRATE RESEARCH

Total Synthesis of theEscherichia coliO111O-Specific Polysaccharide Repeating Unit

(2013) Oliviana Calin et al.   CHEMISTRY-A EUROPEAN JOURNAL

Study of the stereoselectivity of 2-azido-2-deoxyglucosyl donors: protecting group effects

(2013) George Ngoje et al.   ORGANIC & BIOMOLECULAR CHEMISTRY

β-Arabinofuranosylation Using 5-O-(2-Quinolinecarbonyl) Substituted Ethyl Thioglycoside Donors

(2013) Qiang-Wei Liu et al.   ORGANIC LETTERS

Selective Synthesis of 1,2-cis-α-Glycosides without Directing Groups. Application to Iterative Oligosaccharide Synthesis

(2013) An-Hsiang Adam Chu et al.   ORGANIC LETTERS

A General Strategy for the Chemoenzymatic Synthesis of Asymmetrically Branched N-Glycans

(2013) Z. Wang et al.   SCIENCE

Iterative One-Pot α-Glycosylation Strategy: Application to Oligosaccharide Synthesis

(2012) Chih-Yueh Ivan Liu et al.   ADVANCED SYNTHESIS & CATALYSIS

α-Selective Organocatalytic Synthesis of 2-Deoxygalactosides

(2012) Edward I. Balmond et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Halide Effects on Cyclopropenium Cation Promoted Glycosylation with Deoxy Sugars: Highly α-Selective Glycosylations Using a 3,3-Dibromo-1,2-diphenylcyclopropene Promoter

(2012) Jason M. Nogueira et al.   EUROPEAN JOURNAL OF ORGANIC CHEMISTRY

Recent Development in Carbohydrate Based Anticancer Vaccines

(2012) Zhaojun Yin et al.   JOURNAL OF CARBOHYDRATE CHEMISTRY

Lewis Acids as α-Directing Additives in Glycosylations by Using 2,3-O-Carbonate-Protected Glucose and Galactose Thioglycoside Donors Based on Preactivation Protocol

(2012) Yiqun Geng et al.   JOURNAL OF ORGANIC CHEMISTRY

Effect of Remote Picolinyl and Picoloyl Substituents on the Stereoselectivity of Chemical Glycosylation

(2012) Jagodige P. Yasomanee et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Stereoselective Assembly of Complex Oligosaccharides Using Anomeric Sulfonium Ions as Glycosyl Donors

(2012) Tao Fang et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

α-Glycosylation by d-Glucosamine-Derived Donors: Synthesis of Heparosan and Heparin Analogues That Interact with Mycobacterial Heparin-Binding Hemagglutinin

(2012) Medel Manuel L. Zulueta et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Dissecting the mechanisms of a class of chemical glycosylation using primary 13C kinetic isotope effects

(2012) Min Huang et al.   Nature Chemistry

pTSA/[bmim][BF4] Ionic Liquid: A Powerful Recyclable Catalytic System for the Synthesis of α-2-Deoxyglycosides

(2012) Gisela Díaz et al.   TOPICS IN CATALYSIS

Gold-Catalyzed Synthesis of 2-Deoxy Glycosides Using S-But-3-ynyl Thioglycoside Donors

(2012) Surya Adhikari et al.   ACS Catalysis

Recent Advances in Transition Metal-Catalyzed Glycosylation

(2012) Matthew J. McKay et al.   ACS Catalysis

Stereoselective glycosylations using oxathiane spiroketal glycosyl donors

(2011) Martin A. Fascione et al.   CARBOHYDRATE RESEARCH

Reducing the conformational flexibility of carbohydrates: locking the 6-hydroxyl group by cyclopropanes

(2011) Christian Brand et al.   CHEMICAL COMMUNICATIONS

Neighboring-Group Participation by C-2 Ether Functions in Glycosylations Directed by Nitrile Solvents

(2011) Chin-Sheng Chao et al.   CHEMISTRY-A EUROPEAN JOURNAL

Study of the Stereoselectivity of 2-Azido-2-deoxygalactosyl Donors: Remote Protecting Group Effects and Temperature Dependency

(2011) Jane Kalikanda et al.   JOURNAL OF ORGANIC CHEMISTRY

Assembly of Digitoxin by Gold(I)-Catalyzed Glycosidation of Glycosylo-Alkynylbenzoates

(2011) Yuyong Ma et al.   JOURNAL OF ORGANIC CHEMISTRY

Glycosidation of Thioglycosides in the Presence of Bromine: Mechanism, Reactivity, and Stereoselectivity

(2011) Sophon Kaeothip et al.   JOURNAL OF ORGANIC CHEMISTRY

Methodology Development and Physical Organic Chemistry: A Powerful Combination for the Advancement of Glycochemistry

(2011) David Crich   JOURNAL OF ORGANIC CHEMISTRY

Endocyclic Cleavage in Glycosides with 2,3-transCyclic Protecting Groups

(2011) Hiroko Satoh et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Glycoconjugates and polysaccharides from the Scedosporium/Pseudallescheria boydii complex: structural characterisation, involvement in cell differentiation, cell recognition and virulence

(2011) Livia Cristina L. Lopes et al.   MYCOSES

A Fluorous Phosphate Protecting Group with Applications to Carbohydrate Synthesis

(2011) Lin Liu et al.   ORGANIC LETTERS

Pre-activation based stereoselective glycosylations: Stereochemical control by additives and solvent

(2011) Gilbert Wasonga et al.   Science China-Chemistry

Mechanism of a Chemical Glycosylation Reaction

(2010) David Crich   ACCOUNTS OF CHEMICAL RESEARCH

Ionic liquids in oligosaccharide synthesis: towards mucin-type glycan probes

(2010) M. Carmen Galan et al.   BIOCHEMICAL SOCIETY TRANSACTIONS

Improved catalytic and stereoselective glycosylation with glycosyl N-trichloroacetylcarbamate: application to various 1-hydroxy sugars

(2010) Tatsuya Shirahata et al.   CARBOHYDRATE RESEARCH

On the stereoselectivity of glycosidation of thiocyanates, thioimidates, and thioglycosides

(2010) Sophon Kaeothip et al.   CARBOHYDRATE RESEARCH

A highly α-selective glycosylation for the convenient synthesis of repeating α-(1→4)-linked N-acetyl-galactosamine units

(2010) Lin Yang et al.   CARBOHYDRATE RESEARCH

A novel liquid-phase strategy for organic synthesis using organic ions as soluble supports

(2010) Congde Huo et al.   CHEMICAL SOCIETY REVIEWS

First Examples of α-(1→4)-Glycosylation Reactions on Ionic Liquid Supports

(2010) Matthieu Pépin et al.   EUROPEAN JOURNAL OF ORGANIC CHEMISTRY

N-Benzyl-2,3-trans-Carbamate-Bearing Glycosyl Donors for 1,2-cis-Selective Glycosylation Reactions

(2010) Shino Manabe et al.   EUROPEAN JOURNAL OF ORGANIC CHEMISTRY

Theoretical Investigation of Solvent Effects on Glycosylation Reactions: Stereoselectivity Controlled by Preferential Conformations of the Intermediate Oxacarbenium-Counterion Complex

(2010) Hiroko Satoh et al.   Journal of Chemical Theory and Computation

Mannosazide Methyl Uronate Donors. Glycosylating Properties and Use in the Construction of β-ManNAcA-Containing Oligosaccharides

(2010) Marthe T. C. Walvoort et al.   JOURNAL OF ORGANIC CHEMISTRY

Nickel-Catalyzed Stereoselective Glycosylation with C(2)-N-Substituted Benzylidened-Glucosamine and Galactosamine Trichloroacetimidates for the Formation of 1,2-cis-2-Amino Glycosides. Applications to the Synthesis of Heparin Disaccharides, GPI Anchor Pseudodisaccharides, and α-GalNAc

(2010) Enoch A. Mensah et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Chiral-auxiliary-mediated 1,2-cis-glycosylations for the solid-supported synthesis of a biologically important branched α-glucan

(2010) Thomas J. Boltje et al.   Nature Chemistry

Recent advances in stereoselective glycosylation through intramolecular aglycon delivery

(2010) Akihiro Ishiwata et al.   ORGANIC & BIOMOLECULAR CHEMISTRY

Stereoelectronic Effects Determine Oxacarbenium vs β-Sulfonium Ion Mediated Glycosylations

(2010) Thomas J. Boltje et al.   ORGANIC LETTERS

New Principles for Glycoside-Bond Formation

(2009) Xiangming Zhu et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Scope and limitations of imidazolium-based ionic liquids as room temperature glycosylation promoters

(2009) M. Carmen Galan et al.   CARBOHYDRATE RESEARCH

Coordination chemistry approach to the long-standing challenge of stereocontrolled chemical glycosylation

(2009) Papapida Pornsuriyasak et al.   CHEMICAL COMMUNICATIONS

Stereoselective glycosylation using oxathiane glycosyl donors

(2009) Martin A. Fascione et al.   CHEMICAL COMMUNICATIONS

Gold(I)-Catalyzed Glycosylation with Glycosylortho-Alkynylbenzoates as Donors: General Scope and Application in the Synthesis of a Cyclic Triterpene Saponin

(2009) Yao Li et al.   CHEMISTRY-A EUROPEAN JOURNAL

Recent progress in chemical and chemoenzymatic synthesis of carbohydrates

(2009) Saddam Muthana et al.   CURRENT OPINION IN CHEMICAL BIOLOGY

DTBS Effect: The Unique Sterically Driven Director for a-Galactosylation

(2009) Makoto Kiso et al.   HETEROCYCLES

Glycosylation Using Unprotected Alkynyl Donors

(2009) Sreeman K. Mamidyala et al.   JOURNAL OF ORGANIC CHEMISTRY

Palladium-Controlled β-Selective Glycosylation in the Absence of the C(2)-Ester Participatory Group

(2009) Enoch A. Mensah et al.   JOURNAL OF ORGANIC CHEMISTRY

Nickel-Catalyzed Stereoselective Formation of α-2-Deoxy-2-Amino Glycosides

(2009) Enoch A. Mensah et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Equatorial Anomeric Triflates from Mannuronic Acid Esters

(2009) Marthe T. C. Walvoort et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

β-Directing Effect of Electron-Withdrawing Groups atO-3,O-4, andO-6 Positions and α-Directing Effect by Remote Participation of 3-O-Acyl and 6-O-Acetyl Groups of Donors in Mannopyranosylations

(2009) Ju Yuel Baek et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

The De Novo Synthesis of Oligosaccharides: Application to the Medicinal Chemistry SAR-Study of Digitoxin

(2008) George O'Doherty et al.   CURRENT TOPICS IN MEDICINAL CHEMISTRY

NAP Ether Mediated Intramolecular Aglycon Delivery: A Unified Strategy for 1,2-cis-Glycosylation

(2008) Akihiro Ishiwata et al.   EUROPEAN JOURNAL OF ORGANIC CHEMISTRY

Investigations of Glycosylation Reactions with 2-N-Acetyl-2N,3O-oxazolidinone-Protected Glucosamine Donors

(2008) Johan D. M. Olsson et al.   JOURNAL OF ORGANIC CHEMISTRY

How the Arming Participating Moieties can Broaden the Scope of Chemoselective Oligosaccharide Synthesis by Allowing the Inverse Armed−Disarmed Approach

(2008) James T. Smoot et al.   JOURNAL OF ORGANIC CHEMISTRY

Cationic Palladium(II)-Catalyzed Stereoselective Glycosylation with Glycosyl Trichloroacetimidates

(2008) Jaemoon Yang et al.   JOURNAL OF ORGANIC CHEMISTRY

De Novo Asymmetric Synthesis of Anthrax Tetrasaccharide and Related Tetrasaccharide

(2008) Haibing Guo et al.   JOURNAL OF ORGANIC CHEMISTRY

Stereoselective Direct Glycosylation with Anomeric Hydroxy Sugars by Activation with Phthalic Anhydride and Trifluoromethanesulfonic Anhydride Involving Glycosyl Phthalate Intermediates

(2008) Kwan Soo Kim et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Enantioselective Thiourea-Catalyzed Additions to Oxocarbenium Ions

(2008) Sarah E. Reisman et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Toward solution-phase automated iterative synthesis: fluorous-tag assisted solution-phase synthesis of linear and branched mannose oligomers

(2008) Firoz A. Jaipuri et al.   ORGANIC & BIOMOLECULAR CHEMISTRY

Highly Direct α-Selective Glycosylations of 3,4-O-Carbonate-Protected 2-Deoxy- and 2,6-Dideoxythioglycosides by Preactivation Protocol

(2008) Yin-Suo Lu et al.   ORGANIC LETTERS

Stereoselective Synthesis of 2-Deoxy-β-glycosides Using Anomeric O-Alkylation/Arylation

(2008) William J. Morris et al.   ORGANIC LETTERS

Stereoselectivity investigation on glycosylation of oxazolidinone protected 2-amino-2-deoxy-d-glucose donors based on pre-activation protocol

(2008) Yiqun Geng et al.   TETRAHEDRON

Pre-activation protocol leading to highly stereoselectivity-controllable glycosylations of oxazolidinone protected glucosamines

(2007) Yiqun Geng et al.   CHEMICAL COMMUNICATIONS

Automated oligosaccharide synthesis

(2007) Peter H. Seeberger   CHEMICAL SOCIETY REVIEWS

Oligomannan Synthesis Using Ionic Liquid Supported Glycosylation§

(2007) Ashish K. Pathak et al.   ORGANIC LETTERS

Synergistic solvent effect in 1,2-cis-glycoside formation

(2007) Akihiro Ishiwata et al.   TETRAHEDRON