4.6 Article

Fabrication of WO3 nanostructures by anodization method for visible-light driven water splitting and photodegradation of methyl orange

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ELSEVIER SCI LTD
DOI: 10.1016/j.mssp.2012.10.007

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WO3 nanostructures; Anodic oxidation; Photoelectrochemical water splitting; Photodegradation of methyl orange; Visible-light

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  1. Universiti Sains Malaysia [8044058, 6071195]

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Visible light-responsive WO3 nanostructures were synthesized by anodization in a NH4F/Na2SO4 electrolyte solution. Applied potential and anodization time play an important role in the formation of self-organized WO3 nanostructures, further developed upon anodization. The average pore diameter of similar to 80 nm with thickness of similar to 300 nm of WO3 nanoporous layer was successfully synthesized at 50 V for 15 min. The uniform and regular WO3 nanoporous layer exhibited better photocurrent density of similar to 0.18 mA/cm(2) at 0.7 V vs. SCE and better photodegradation of MO solution of similar to 50% after 5 h of visible-light illumination. The larger active surface area of WO3 nanoporous layer played a significant role to generate more electron-hole pairs, which triggered the PEC water splitting reaction and photodegradation reaction much more effectively. (C) 2012 Elsevier Ltd. All rights reserved.

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