4.6 Article

Room temperature synthesis of Mn3O4 nanoparticles: characterization, electrochemical properties and hydrothermal transformation to γ-MnO2 nanorods

期刊

MATERIALS LETTERS
卷 92, 期 -, 页码 401-404

出版社

ELSEVIER SCIENCE BV
DOI: 10.1016/j.matlet.2012.11.022

关键词

Manganese oxide; Supercapacitor; Nanoparticles; Crystal growth; Energy storage and conversion

资金

  1. Knowledge Innovation Program of the Chinese Academy of Sciences [KJCX2-YW-W26]
  2. Beijing Municipal Science and Technology Commission [Z111100056011007]
  3. National Natural Science Foundation of China [21001103, 51025726]

向作者/读者索取更多资源

A mild and room temperature route has been developed for the synthesis of Mn3O4 nanoparticles by mixing the aqueous solution of MnSO4 and Na2CO3. The Mn3O4 products were investigated by X-ray diffraction (XRD), field emission scanning electron microscopy (FESEM), transmission electron microscopy (TEM) and electrochemical tests. A specific capacitance of 205 F g(-1) was obtained for Mn3O4 nanoparticles at a current density of 0.5 A g(-1) in 1 M Na2SO4 electrolyte solution. The Mn3O4 nanoparticles exhibited a good rate capability and electrochemical stability. In addition, gamma-MnO2 nanorods were prepared from Mn3O4 nanoparticles by a simple hydrothermal treatment at 120 degrees C under the acidic condition. (C) 2012 Elsevier B.V. All rights reserved.

作者

我是这篇论文的作者
点击您的名字以认领此论文并将其添加到您的个人资料中。

评论

主要评分

4.6
评分不足

次要评分

新颖性
-
重要性
-
科学严谨性
-
评价这篇论文

推荐

Article Chemistry, Applied

Mechanically flexible reduced graphene oxide/carbon composite films for high-performance quasi-solid-state lithium-ion capacitors

Wenjie Liu, Yabin An, Lei Wang, Tao Hu, Chen Li, Yanan Xu, Kai Wang, Xianzhong Sun, Haitao Zhang, Xiong Zhang, Yanwei Ma

Summary: Practical applications of flexible wearable electronics require EES devices with multiple configurations. To fabricate flexible EES devices with high energy density and stability, organic integration from electrode design to device assembly is required. The designed rGO/carbon film exhibits enhanced specific capacities and excellent stability, enabling the development of portable flexible LICs.

JOURNAL OF ENERGY CHEMISTRY (2023)

Article Materials Science, Multidisciplinary

A 10-μm Ultrathin Lithium Metal Composite Anodes with Superior Electrochemical Kinetics and Cycling Stability

Gefei Zhang, Kai Wang, Yanan Xu, Xudong Zhang, Qifan Peng, Yibo Ma, Shani Li, Xiong Zhang, Xianzhong Sun, Yanwei Ma

Summary: In this work, a simple method to fabricate free-standing 10 μm ultrathin Li metal anode is developed using a three-dimensional MnOx-coated CNT framework. The ultrathin Li composite anode exhibits a superior lifespan expanded to 2000 cycles in a symmetric cell and a better capacity and rate capability than that of bare Li anode in a full cell, fulfilling the requirements of high energy density and stable cycling life. Furthermore, a wave-shaped Li metal pouch cell based on the ultrathin Li composite anode demonstrates remarkable mechanical bending toleration and cyclic stability, showing great potential application in the field of flexible wearable devices.

ENERGY & ENVIRONMENTAL MATERIALS (2023)

Article Electrochemistry

Carbon Nano-Onion-Encapsulated Ni Nanoparticles for High-Performance Lithium-Ion Capacitors

Xiaohu Zhang, Keliang Zhang, Weike Zhang, Xiong Zhang, Lei Wang, Yabin An, Xianzhong Sun, Chen Li, Kai Wang, Yanwei Ma

Summary: Lithium-ion capacitors (LICs) have high-power density, long-term cycling stability, and good energy storage performance, making them widely applicable in new energy, new infrastructure, intelligent manufacturing, and other fields. Carbon nano-onions (CNOs) are promising candidates in energy storage due to their excellent electrical conductivity, large surface area, and nanoscopic dimensions. This study characterized the structure, composition, and electrochemical properties of Ni@CNOs and demonstrated their effectiveness in achieving high-performance LICs with compelling electrochemical performance, cycle stability, and high energy density.

BATTERIES-BASEL (2023)

Review Electrochemistry

Battery-Type Lithium-Ion Hybrid Capacitors: Current Status and Future Perspectives

Zhang Guo, Zhien Liu, Wan Chen, Xianzhong Sun, Xiong Zhang, Kai Wang, Yanwei Ma

Summary: The lithium-ion battery (LIB) is widely used as an electrochemical energy storage device due to its high energy density. However, it suffers from poor power performance and cycle performance. These issues can be addressed by incorporating capacitor material into the cathode, resulting in a lithium-ion battery capacitor (LIBC). This review presents the typical structure and working principle of LIBCs and summarizes recent advancements in this field, including non-lithiated and pre-lithiated anode materials, pre-lithiation methods, capacitor materials, suitable separator materials, and electrode engineering for improved electrochemical performance. Future research directions for advanced LIBCs are also discussed based on the existing problems.

BATTERIES-BASEL (2023)

Article Electrochemistry

Surplus charge injection enables high-cell-potential stable 2D polyaniline supercapacitors

Xinglin Jiang, Xiang Chu, Xiong Zhang, Yanting Xie, Tao Yang, Junfeng Huang, Wen Li, Weili Deng, Haitao Zhang, Weiqing Yang

Summary: This study proposes a strategy of surplus electron injection to stabilize the molecular chain of polyaniline (PANI) at high cell potential. The surplus electron injection in 2D PANI is realized by exceeding the stable potential induced by an asymmetric supercapacitor structure design. This strategy enhances the capacitive behavior and cycling lifetime of 2D PANI supercapacitors in sulfuric acid electrolyte.

ELECTROCHIMICA ACTA (2023)

Article Materials Science, Multidisciplinary

Low-Temperature Carbonized Nitrogen-Doped Hard Carbon Nanofiber Toward High-Performance Sodium-Ion Capacitors

Congkai Sun, Xiong Zhang, Yabin An, Chen Li, Lei Wang, Xiaohu Zhang, Xianzhong Sun, Kai Wang, Haitao Zhang, Yanwei Ma

Summary: Nitrogen-doped hard carbon nanofibers were successfully prepared through a low-temperature carbonization treatment and electrospinning technology. The resulting material exhibited a reversible specific capacity of 191.0 mAh g(-1) and no capacity decay after 200 cycles at 1 A g(-1). The constructed sodium-ion capacitor showed high energy and power densities.

ENERGY & ENVIRONMENTAL MATERIALS (2023)

Review Electrochemistry

A Review on Thermal Behaviors and Thermal Management Systems for Supercapacitors

Wei Zhou, Zhien Liu, Wan Chen, Xianzhong Sun, Maji Luo, Xiaohu Zhang, Chen Li, Yabin An, Shuang Song, Kai Wang, Xiong Zhang

Summary: As a representative electrochemical energy storage device, supercapacitors (SCs) have higher energy density than traditional capacitors and better power density and cycle life than lithium-ion batteries, making them extensively used in energy storage. However, there is a lack of understanding of the thermal behaviors and thermal management systems of SCs, which this review aims to address. The review introduces the energy storage mechanisms of SCs and current investigations of thermal behaviors, including heat generation rates, experimental methods, heat generation rate models, and thermal runaway. It also provides an overview of current efforts in different cooling systems and discusses the challenges and future work directions for SCs in thermal behaviors and thermal management systems.

BATTERIES-BASEL (2023)

Article Chemistry, Physical

Hyper-conjugated polyaniline delivering extraordinary electrical and electrochemical properties in supercapacitors

Yihan Wang, Xiang Chu, Hongrui Zhang, Cheng Yan, Guo Tian, Weiqing Yang, Xiangrong Chen, Haitao Zhang

Summary: This study reports a hyper-conjugated effect in copolymerized polyaniline (PANI), which greatly improves electrical conductivity and specific capacitance. The findings pave the way for designing conjugated polymers with remarkable electronic and electrochemical properties.

APPLIED SURFACE SCIENCE (2023)

Article Engineering, Environmental

Cation-deficient T-Nb2O5/graphene Hybrids synthesized via chemical oxidative etching of MXene for advanced lithium-ion capacitors

Lei Wang, Xiong Zhang, Chen Li, Yanan Xu, Yabin An, Wenjie Liu, Tao Hu, Sha Yi, Kai Wang, Xianzhong Sun, Yue Gong, Zhong-Shuai Wu, Yanwei Ma

Summary: By introducing Nb vacancies in T-Nb2O5 nanoparticles via amine-assisted oxidative etching of Nb2CTx MXene, we provide extra storage sites and improve structural flexibility by introducing cationic defects. The resulting T-Nb2O5/rGO hybrid anode exhibits rapid and stable multi-electron transfer lithium storage. The T-Nb2O5/rGO anode shows superior rate capacity and cycling stability, achieving high energy density, power density, and capacity retention.

CHEMICAL ENGINEERING JOURNAL (2023)

Article Engineering, Environmental

Interface engineering of CoSe2/N-doped graphene heterostructure with ultrafast pseudocapacitive kinetics for high-performance lithium-ion capacitors

Wenpin Wei, Lei Wang, Chu Liang, Wenjie Liu, Chen Li, Yabin An, Lixing Zhang, Xianzhong Sun, Kai Wang, Haitao Zhang, Xiong Zhang, Yanwei Ma

Summary: This study investigates the feasibility of using cobalt selenide as an anode material in lithium-ion capacitors and successfully designs a heterostructure with nitrogen-doped graphene to stabilize the electrode structure. The experimental results show that the electrode exhibits excellent cycle performance and rate performance, and the assembled lithium-ion capacitors also have high energy/power density and exceptional long-term stability.

CHEMICAL ENGINEERING JOURNAL (2023)

Review Electrochemistry

Supercapacitive Swing Adsorption of Carbon Dioxide: Current Status and Perspectives

Yuanfei Wang, Keliang Zhang, Jijun Feng, Xianzhong Sun, Chen Li, Kai Wang, Xiong Zhang, Yanwei Ma

Summary: This article briefly introduces the principle and structural design of supercapacitive swing adsorption (SSA), and analyzes the factors influencing SSA performance from multiple aspects, with emphasis on electrode materials. This method can be used for carbon dioxide adsorption, which is of great significance for addressing global climate issues.

BATTERIES & SUPERCAPS (2023)

Article Chemistry, Physical

An interfacial covalent bonding coupled ultrafine CuS-nanocrystals/MXene heterostructure for efficient and durable magnesium storage

Zhi Cheng, Yanan Xu, Xudong Zhang, Qifan Peng, Kai Wang, Xiong Zhang, Xianzhong Sun, Qinyou An, Liqiang Mai, Yanwei Ma

Summary: A confined in situ growth strategy successfully constructs a copper sulfide/delaminated Ti3C2Tx MXene heterostructure with high reversible specific capacity and outstanding rate capability, providing an avenue for designing high-performance cathode materials for rechargeable magnesium batteries.

JOURNAL OF MATERIALS CHEMISTRY A (2023)

Article Materials Science, Multidisciplinary

F-doped Co3O4 with Pt-like activity and excellent stability for hydrogen evolution reaction in alkaline media

Deyong Zheng, Huihui Jin, Yucong Liao, Pengxia Ji

Summary: In this study, a highly stable and efficient catalyst, fluorine-doped Co3O4 (F-Co3O4), was developed for hydrogen production by water electrolysis. The F-Co3O4 catalyst exhibited a remarkable reduction in overpotential and demonstrated excellent stability for over 100 hours.

MATERIALS LETTERS (2024)

Article Materials Science, Multidisciplinary

Effect of the addition of Cu6Sn5 nanoparticles on the growth of intermetallic compounds at the interfaces of Sn3.0Ag0.5Cu solder joints

Ziwen Lv, Jintao Wang, Fengyi Wang, Jianqiang Wang, Fuquan Li, Hongtao Chen

Summary: Adding Cu6Sn5 nano particles can effectively inhibit the overgrowth of intermetallic compounds at the interfaces of solder joints in electronic devices, providing a solution to this issue. A new growth mechanism of intermetallic compounds at the interfaces was identified.

MATERIALS LETTERS (2024)

Article Materials Science, Multidisciplinary

BiOI/AgI/Ag plasmonic heterostructure for efficient photoelectrochemical water splitting

Jun Wang, Jiawei Chen, Wanru Liao, Fangyang Liu, Min Liu, Liangxing Jiang

Summary: A BiOI/AgI/Ag plasmonic heterostructure photocathode was successfully designed through electrodeposition, ion-exchange, and illumination methods. This photocathode exhibits superior performance in photoelectrochemical water splitting.

MATERIALS LETTERS (2024)

Article Materials Science, Multidisciplinary

Ni@O-doped carbon Mott-Schottky heterojunctions to enhance sulfur conversion kinetics

Xiaoxiao Liu, Xianxian Zhou, Xiaotao Ma, Qinbo Yuan, Shibin Liu

Summary: In this study, the authors propose a method to accelerate the reaction of polysulfides in lithium-sulfur batteries using a Ni@OC Mott-Schottky heterojunction as a catalyst. The experimental results demonstrate that the charge redistribution at the Ni@OC interface accelerates electron transfer and enhances catalytic activity, leading to improved reaction kinetics and battery performance.

MATERIALS LETTERS (2024)

Article Materials Science, Multidisciplinary

Effect of fixture boundary conditions for low-velocity impact: A focus on composites with different matrix and fibers

Dayou Ma, Mohammad Rezasefat, Joziel Aparecido da Cruz, Sandro Campos Amico, Marco Giglio, Andrea Manes

Summary: The matrix has a significant effect on the impact resistance of composite materials. Replacing a brittle polymer with a more flexible one can improve impact resistance, but it poses challenges to standard testing methods. This study designs a new fixture for testing the low-velocity impact of soft composites and investigates the effect of the fixture on the mechanical performance.

MATERIALS LETTERS (2024)

Article Materials Science, Multidisciplinary

Synergistic effect of defects and heterostructures endowing bronze titanium dioxide with superior lithium storage performances

Lingchang Wang, Qihang Yang, Huzhen Li, Ming Wei, Qian Wang, Zhenzhong Hu, Mengmeng Zhen

Summary: Bronze titanium dioxide (TiO2(B)) is a promising anode material for lithium-ion batteries due to its high specific capacity. However, its practical applications are hindered by poor conductivity and limited electrochemical kinetics. In this study, TiO2(B)-carbon nanosheets heterostructures are synthesized to enhance the cycling performance and rate capability of TiO2(B).

MATERIALS LETTERS (2024)

Article Materials Science, Multidisciplinary

Sustained electromagnetic parameters of barium ferrite and epoxy nanocomposites for patch antenna miniaturization over GHz frequency range

Atul Thakur, Ritesh Verma, Ankush Chauhan, Fayu Wan, Preeti Thakur

Summary: In this study, BaFe12O19 and BaFe12O19: Epoxy (50:50) nanocomposites were synthesized using the co-precipitation method. The structural information and material properties, such as crystallite size and electrical conductivity, were characterized by XRD, FESEM, EDX, and TEM techniques.

MATERIALS LETTERS (2024)

Article Materials Science, Multidisciplinary

In-situ construction of CoS2@NC hierarchical binder-free cathode for advanced Li-CO2 batteries

Jingyu Wu, Xinyan Ma, Yong Yang

Summary: A well-defined CoS2@NC(CS-500) hierarchical binder-free catalyst cathode is constructed through in-situ grown of ZIF-67 on carbon cloth and high-temperature carbonization. The cathode shows excellent reaction kinetics and electrochemical performance, providing inspiration for developing advanced Li-CO2 battery catalysts.

MATERIALS LETTERS (2024)

Article Materials Science, Multidisciplinary

K5Eu1-xHox(MoO4)4: Structures and luminescence properties

Svetlana M. Posokhova, Vladimir A. Morozov, Kirill N. Boldyrev, Dina Deyneko, Erzhena T. Pavlova, Bogdan I. Lazoryak

Summary: This study explores the impact of synthesis method and composition on the structure and luminescence properties of K5Eu1-xHox(MoO4)4 with the palmierite-type matrix. The co-doping of Eu3+ and Ho3+ ions plays a critical role in manipulating charge transfer and luminescence efficiency in the visible and infrared regions.

MATERIALS LETTERS (2024)

Article Materials Science, Multidisciplinary

Benzonitrile/pyridylbenzoimidazole hybrid electron-transport material for efficient phosphorescence and TADF OLEDs

Jian Wang, Yeting Tao, Jingsheng Wang, Youtian Tao

Summary: A new electron-transport material iTPyBI-CN is developed through non-catalytic C-N coupling reaction. It exhibits better electroluminescence efficiency in organic light-emitting diodes compared to the commercial material TPBI, due to its twisted geometry and higher energy levels.

MATERIALS LETTERS (2024)

Article Materials Science, Multidisciplinary

Microscopic characteristics and thermodynamic property changes in limestone under high-temperature treatment

Tao Zhu, Feng Huang, Shuo Li, Yang Zhou

Summary: This article combines XRD analysis and microscopic structural observation to investigate the changes in limestone after high-temperature treatment. It finds that 500 degrees C is the critical temperature for crystalline and spatial arrangement changes in limestone, and the thermal conductivity, specific heat capacity, and heat storage coefficient gradually decrease after thermal treatment.

MATERIALS LETTERS (2024)

Article Materials Science, Multidisciplinary

Novel synthesis of ZnO nanostructure from galvanization waste for antibacterial application

Muhammad Haekal Habibie, Fransiska Sri Herwahyu Krismastuti, Abdi Wira Septama, Faiza Maryani, Vivi Fauzia

Summary: This study focuses on the synthesis of zinc oxide nanostructure from zinc recovered from galvanization ash and highlights its potential as a sustainable source of zinc and as an antibacterial agent.

MATERIALS LETTERS (2024)

Article Materials Science, Multidisciplinary

Biomimetic mineralization engineered phycocyanin with improved stability and antioxidantive activity under environmental stress

Jingyi Li, Yixin Xing, Wei Gu, Shousi Lu

Summary: In this study, PC@CaP microparticles were fabricated using biomimetic mineralization. The results showed that under environmental stress, PC@CaP exhibited improved stability and antioxidative activity, indicating its potential use in high-added value fields.

MATERIALS LETTERS (2024)

Article Materials Science, Multidisciplinary

ZIF-8 nanoparticles combined with fibroin protein co-modified TiO2 nanotube arrays to construct a drug sustained-release platform

Yan Liu, Shunyou Chen

Summary: In this study, TNTs were used as a drug carrier and modified with ZIF-8 and silk fibroin to obtain a new drug loading platform. The results showed that this drug-loaded platform had a good drug release effect in vitro and could promote cell proliferation and osteogenic differentiation.

MATERIALS LETTERS (2024)

Article Materials Science, Multidisciplinary

Observation of stacking faults in ε-phase InSe crystal

Chunhui Zhu, Wentao Wang, Qing Zhen, Xinning Huang, Shixin Li, Shaochang Wang, Xiaoping Ma, Xiaoxia Liu, Yalong Jiao, Kai Sun, Zhuangzhi Li, Huaixin Yang, Jianqi Li

Summary: A type of stacking fault is revealed in e-InSe crystal, which is associated with a small stacking-fault energy and shows exceptional plasticity.

MATERIALS LETTERS (2024)