4.6 Article

Preparation of titania/hydroxyapatite (TiO2/HAp) composite photocatalyst with mosaic structure for degradation of pentachlorophenol

期刊

MATERIALS LETTERS
卷 110, 期 -, 页码 57-60

出版社

ELSEVIER SCIENCE BV
DOI: 10.1016/j.matlet.2013.07.108

关键词

Titania; Hydroxyapatite; Composite materials; Microstructure; Photocatalysis; Pentachlorophenol

资金

  1. National Natural Science Foundation of China [21206026]
  2. Natural Science Foundation of Hebei Province [B2012402011, B2012402006]
  3. Science and Technology Research Foundation of Hebei Education Department for Outstanding Young Teachers in University [Y2012028]
  4. Science and Technology Research and Development Projects of Handan City [1128130092, 1223120094]

向作者/读者索取更多资源

Titania/hydroxyapatite (TiO2/HAp) composite with mosaic structure was successfully synthesized via a facile route without any structure-directing agent. XRD, EDS and FESEM were used to characterize the product. It is found that lots of spherical TiO2 particles with average diameter of about 24 nm are formed, like pearls densely inlaid in the ravines of HAp carrier surface. Meanwhile, a possible surface adsorption layer hydrolysis mechanism for the formation of such novel structure has been proposed. Experimental results show that the obtained TiO2/HAp composite, which combines the excellent adsorption capacity of HAp and the high photocatalytic activity of TiO2, can effectively degrade persistent organic pollutant pentachlorophenol under UV irradiation. (C) 2013 Elsevier B.V. All rights reserved.

作者

我是这篇论文的作者
点击您的名字以认领此论文并将其添加到您的个人资料中。

评论

主要评分

4.6
评分不足

次要评分

新颖性
-
重要性
-
科学严谨性
-
评价这篇论文

推荐

Article Nanoscience & Nanotechnology

Construction of 3D CrN@nitrogen-doped carbon nanosheet arrays by reactive magnetron sputtering for the free-standing electrode of supercapacitor

Xun Xu, Songyang Chang, Zhuozheng Hong, Ye Zeng, Hao Zhang, Ping Li, Shizheng Zheng, Zhoucheng Wang, Shuwang Duo

Summary: 3D CrN@nitrogen-doped carbon nanosheet arrays (NCs) were successfully deposited on carbon paper (CP) using reactive magnetron sputtering method, showing satisfactory electrochemical properties. The electrode exhibited high specific capacitance and capacitance retention, making it suitable for energy storage applications.

NANOTECHNOLOGY (2022)

Article Nanoscience & Nanotechnology

In situ self-assembly fabrication of ultrathin sheet-like CuS modified g-C3N4 heterojunction and its enhanced visible-light photocatalytic performance

Zheyuan Liu, Lingfang Qiu, Ke Wen, Banpeng Cao, Ping Li, Yi Tang, Xiangshu Chen, Hidetoshi Kita, Shuwang Duo

Summary: In this study, CuS/g-C3N4 heterojunction was successfully synthesized via a simple hydrothermal method, exhibiting excellent photocatalytic performance and stability. The results provide important implications for similar research on g-C3N4-based heterojunctions for photocatalytic applications.

NANOTECHNOLOGY (2023)

Article Chemistry, Physical

Construction of core-shell Co-NC@W2N Schottky heterojunctions for high-efficiency hydrogen evolution reaction

Zhuozheng Hong, Zili Xu, Zhengtao Wu, Hao Zhang, Ping Li, Xun Xu, Shuwang Duo

Summary: In this study, W2N was directly synthesized on Co-NC microarrays derived from metal-organic frameworks (MOFs) using magnetron sputtering. The Co-NC microarray support increased the number of surface activity sites exposed to W2N. Moreover, the formation of Co-NC@W2N Schottky heterojunctions significantly facilitated charge transfer between Co-NC and W2N. The Co-NC@W2N heterojunctions exhibited outstanding hydrogen evolution reaction (HER) activity, surpassing Pt/C catalyst at high current densities. This research provides a simple and environmentally friendly approach for fabricating high-performance metal-nitride catalysts for water splitting.

APPLIED SURFACE SCIENCE (2023)

Article Nanoscience & Nanotechnology

Fabrication and enhanced visible-light photocatalytic H2 production of B-doped N-deficient g-C3N4/CdS Hybrids with robust 2D/2D hetero-interface interaction

Guoliang Chu, Lingfang Qiu, Ke Wen, Ping Li, Banpeng Cao, Yi Tang, Xiangshu Chen, Hidetoshi Kita, Shuwang Duo

Summary: By calcining the mixture of ultrathin g-C3N4 and NaBH4, heteroatom B and N defect were introduced into the g-C3N4 structure. The modified g-C3N4 was then coupled with 2D flower-like CdS nanosheet to form a heterojunction. The optimized 2D/2D BDCNN/CdS-15% heterojunction showed excellent photocatalytic activity for H-2 production with a revolution rate of 1013.8 mu mol g(-1) h(-1), significantly higher than pristine CNN, BDCNN, and CdS. The band structure of 2D/2D BDCNN/CdS-15% was well tuned for improved visible-light absorption and higher separation efficiency of photo-induced carriers, leading to enhanced H-2 production performance. This study provides valuable insights for exploring g-C3N4 based heterojunctions with better H-2 production performance.

NANOTECHNOLOGY (2023)

Article Chemistry, Physical

Ni-Pd-Incorporated Fe3O4 Yolk-Shelled Nanospheres as Efficient Magnetically Recyclable Catalysts for Reduction of N-Containing Unsaturated Compounds

Dong Wang, Yi Li, Liangsong Wen, Jiangbo Xi, Pei Liu, Thomas Willum Hansen, Ping Li

Summary: This study reports the synthesis of Ni-Pd/Fe3O4 composite nanospheres by incorporating heterometals into Fe3O4 shell and yolk, which exhibit excellent treatment efficiency and capability for the degradation of N-containing organic dyes. The as-prepared composite shows enhanced catalytic activity and recyclability compared to its mono metal counterparts. In addition, it demonstrates superior catalytic activity in the reduction of 4-nitrophenol. This work provides a new strategy to enhance the activity of iron oxide-based catalytic materials and contributes to environmental catalysis research.

CATALYSTS (2023)

Article Chemistry, Physical

Highly efficient visible-light photocatalytic performance of MOFs-derived TiO2 via heterojunction construction and oxygen vacancy engineering

Yue Chen, Huan Liu, Liang Hu, Youliang Shen, Lingfang Qiu, Liezhen Zhu, Qianxiang Shi, Xun Xu, Ping Li, Shuwang Duo

Summary: A novel Z-scheme ZnIn2S4/TiO2-x photocatalyst was successfully synthesized for the first time through self-sacrificing template-chemical bath deposition combined with a NaBH4 reduction method. The ZnIn2S4/TiO2-x showed high-efficient visible-light photocatalytic degradation of RhB with a rate of 91% within 40 minutes, which was significantly better than TiO2, ZnIn2S4/TiO2, and TiO2-x. The excellent photocatalytic performance was attributed to the synergistic effect of Ov, ZnIn2S4, and MOF-derived TiO2, which enhanced the visible-light photoresponse range and improved the separation of charge carriers.

CHEMICAL PHYSICS LETTERS (2023)

Article Chemistry, Inorganic & Nuclear

Coupling ZnIn2S4 Nanosheets with MoS2 Hollow Nanospheres as Visible-Light-Active Bifunctional Photocatalysts for Enhancing H2 Evolution and RhB Degradation

Yue Chen, Liezhen Zhu, Jingzhe Li, Lingfang Qiu, Chenhui Zhou, Xun Xu, Youliang Shen, Jiangbo Xi, Dandan Men, Ping Li, Shuwang Duo

Summary: In this study, MoS2 hollow nanospheres (HNS) were synthesized using Mo-glycerate as a precursor and applied to modify ZnIn2S4 nanosheets to create MoS2 HNS/ZnIn2S4 photocatalysts. The MoS2 HNS/ZnIn2S4 heterojunctions exhibited significantly enhanced photocatalytic properties and excellent reusability without the need for Pt as a co-catalyst. Among the heterojunctions, the optimized MoS2 HNS/ZnIn2S4-3 wt% composite showed nearly 5-fold and 34-fold higher efficiency in RhB degradation and H2 evolution than ZnIn2S4, respectively. The improved performance of MoS2 HNS/ZnIn2S4-3 wt% can be attributed to the expansion of visible-light response range and accelerated separation efficiency of photo-induced carriers, as revealed by optical property tests. Based on the established band gap position and characterization results, a potential mechanism for the enhanced photocatalytic activity of MoS2 HNS/ZnIn2S4 heterojunctions was proposed.

INORGANIC CHEMISTRY (2023)

Article Materials Science, Multidisciplinary

Fe3O4 nanoparticles anchoring onto graphitic carbon nitrogen nanosheets for enhanced magneto-stimuli responses and sedimentation stability

Guangshuo Wang, Fangfang Si, Yingying Ma, Yanming Wang, Zhixiao Zhang, Ruitao Yu, Xiaoliang Zhang, Guoqing Chang, Jingbo Mu, Hongwei Che, Ping Li, Dong Li

Summary: A novel two-dimensional magnetic nanocomposites were successfully synthesized by immobilizing Fe3O4 nanoparticles onto g-C3N4 nanosheets via a liquid exfoliated method and solvothermal reaction. The structural, morphological, compositional, thermal, and magnetic properties of the composites were characterized. The Fe3O4/g-C3N4 composites were used to fabricate a stable magnetorheological (MR) suspension, and its rheological performance and sedimentation stability were investigated. The MR fluid exhibited enhanced sedimentation stability compared to another suspension containing carbonyl iron particles, which can be attributed to the dispersed Fe3O4/g-C3N4 composite particles with ultrathin sheet-like nanostructure and reduced density mismatch.

JOURNAL OF MATERIALS RESEARCH AND TECHNOLOGY-JMR&T (2023)

Article Chemistry, Physical

Fabrication of Ni/NiFe-LDH Core-Shell Schottky Heterojunction as Ultrastable Bifunctional Electrocatalyst for Ampere-Level Current Density Water Splitting

Junzhi Liao, Mengyao Xue, Yuankang Bao, Zhengtao Wu, Hao Zhang, Ping Li, Xun Xu, Shuwang Duo

Summary: A three-dimensional core-shell Ni/NiFe-LDH/IF electrode was reported in this study. The assembly enhanced the interfacial strength, promoted electron transfer, and increased the adsorption energy of OH-. The electrode exhibited ultralow overpotentials and excellent water splitting characteristics at different current densities. It also demonstrated extremely high stability in alkaline solutions.

ACS APPLIED ENERGY MATERIALS (2023)

Article Chemistry, Physical

g-C3N4/PDI@ZnIn2S4 2D/2D organic-inorganic hybrid heterojunction with enhanced visible light photocatalytic property

Liezhen Zhu, Yue Chen, Youliang Shen, Yuhang Zhang, Dandan Men, Lingfang Qiu, Xun Xu, Jiangbo Xi, Ping Li, Shuwang Duo

Summary: This study presents the design and fabrication of novel g-C3N4/PDI@ZnIn2S4 2D/2D organic/inorganic hybrid heterojunctions, which are used as photocatalysts for the visible-light photodegradation of Rhodamine B. The composite photocatalysts displayed enhanced photocatalytic performance, with the optimal photocatalyst exhibiting significantly higher activity compared to other materials. The enhanced activity can be attributed to the close interface contact and matched band structure between g-C3N4/PDI and ZnIn2S4, which facilitate the separation and transfer of photo-induced charges, as well as the utilization of visible light. This work highlights the promising application prospects of g-C3N4/PDI@ZnIn2S4 photocatalysts in environmental remediation fields.

CHEMICAL PHYSICS LETTERS (2023)

Article Materials Science, Multidisciplinary

Boosting the photocatalytic activity for H2 production of Bi2O2Se/ CdS heterojunction

Jiajia Liu, Lingfang Qiu, Zheyuan Liu, Yi Tang, Lihong Cheng, Zhiqin Chen, Ping Li, Banpeng Cao, Xiangshu Chen, Hidetoshi Kita, Shuwang Duo

Summary: In order to overcome the drawbacks of CdS in photocatalytic processes, Bi2O2Se was prepared with a narrow band gap and unique optical and electrochemical properties, and used to fabricate Bi2O2Se/CdS heterojunctions through a facile in-situ self-assembly hydrothermal method. The synthesized Bi2O2Se/CdS heterojunctions demonstrated significantly stronger visible-light adsorption compared to CdS. Bi2O2Se/CdS with a mass ratio of 2% exhibited the best H2 production performance (lambda >= 420 nm), with a H2 evolution rate of 424 μ mol g(-1) h(-1), which was 24 times higher than that of CdS. This work provided new insights into designing heterojunction interfaces based on CdS to synthesize novel photocatalysts with high efficiency.

MATERIALS LETTERS (2023)

Article Chemistry, Analytical

Multi-mode detection of iodine based on Au@Ag nanoparticle array with highly sensibility and stability using plasmonic surface lattice resonances

Dandan Men, Wenjuan Li, Ting Wu, Guihua Jiang, Honghua Zhang, Lifeng Hang, Ping Li, Hong Wang, Junhuai Xiang

Summary: The present study focuses on designing a sensor with excellent sensitivity, high stability, and low cost at room temperature for rapid and simple detection of iodine (I2) in liquid and gaseous phase. A two-dimensional Au@Ag nanoparticle ordered array was prepared using a template method combined with chemical reduction. The array exhibited plasmonic surface lattice resonances (PSLR) peak in the extinction spectrum, which changed with the reaction of the Ag shell with I2, enabling multi-mode detection of liquid and gaseous I2 without sophisticated instruments. The ordered array showed good uniformity and stability, making it suitable for detecting I2 in a large concentration region. The Au@Ag nanoparticle array also demonstrated high sensitivity to gaseous I2 at room temperature, with a detection limit reaching trace level (1 ppb), indicating great potential for real-world application.

SENSORS AND ACTUATORS B-CHEMICAL (2024)

Article Chemistry, Multidisciplinary

In situ fabrication of a novel CdS/ZnIn2S4/g-C3N4 ternary heterojunction with enhanced visible-light photocatalytic performance

Jingzhe Li, Yue Chen, Liezhen Zhu, Linfa Liao, Xinmao Wang, Xun Xu, Lingfang Qiu, Jiangbo Xi, Ping Li, Shuwang Duo

Summary: A novel g-C3N4-based ternary heterojunction CdS/ZnIn2S4/g-C3N4 was successfully designed and constructed. The optimized CdS/ZnIn2S4/g-C3N4 photocatalyst exhibited higher photocatalytic activity due to the synergistic effects of CdS nanoparticles, ZnIn2S4 nanosheets and g-C3N4 nanosheets.

RSC ADVANCES (2022)

Article Chemistry, Multidisciplinary

Ternary photocatalysts based on MOF-derived TiO2 co-decorated with ZnIn2S4 nanosheets and CdS nanoparticles for effective visible light degradation of organic pollutants

Huan Liu, Jingzhe Li, Yue Chen, Xuting Sun, Xun Xu, Lingfang Qiu, Shuwang Duo, Ping Li

Summary: One feasible strategy to enhance the photocatalytic properties of TiO2 is to design and synthesize heterostructures using narrow-band-gap semiconductors. In this study, a ternary heterostructure based on MOF-derived TiO2 was fabricated and showed improved visible-light photocatalytic properties for the degradation of organic pollutants.

NEW JOURNAL OF CHEMISTRY (2022)

Article Chemistry, Physical

Oxygen-vacancy-containing Nb2O5 nanorods with modified semiconductor character for boosting selective nitrate-to-ammonia electroreduction

Bo Cao, Xun Xu, Zhuozheng Hong, Junzhi Liao, Ping Li, Hao Zhang, Shuwang Duo

Summary: This research demonstrates that introducing oxygen vacancies into Nb2O5 nanorods significantly enhances the electrocatalytic reduction of NO3- to ammonia, improving both the activity and selectivity of the catalyst. The findings pave the way for the development of defect-engineered metal oxide catalysts for selective ENRA process.

SUSTAINABLE ENERGY & FUELS (2022)

Article Materials Science, Multidisciplinary

F-doped Co3O4 with Pt-like activity and excellent stability for hydrogen evolution reaction in alkaline media

Deyong Zheng, Huihui Jin, Yucong Liao, Pengxia Ji

Summary: In this study, a highly stable and efficient catalyst, fluorine-doped Co3O4 (F-Co3O4), was developed for hydrogen production by water electrolysis. The F-Co3O4 catalyst exhibited a remarkable reduction in overpotential and demonstrated excellent stability for over 100 hours.

MATERIALS LETTERS (2024)

Article Materials Science, Multidisciplinary

Effect of the addition of Cu6Sn5 nanoparticles on the growth of intermetallic compounds at the interfaces of Sn3.0Ag0.5Cu solder joints

Ziwen Lv, Jintao Wang, Fengyi Wang, Jianqiang Wang, Fuquan Li, Hongtao Chen

Summary: Adding Cu6Sn5 nano particles can effectively inhibit the overgrowth of intermetallic compounds at the interfaces of solder joints in electronic devices, providing a solution to this issue. A new growth mechanism of intermetallic compounds at the interfaces was identified.

MATERIALS LETTERS (2024)

Article Materials Science, Multidisciplinary

BiOI/AgI/Ag plasmonic heterostructure for efficient photoelectrochemical water splitting

Jun Wang, Jiawei Chen, Wanru Liao, Fangyang Liu, Min Liu, Liangxing Jiang

Summary: A BiOI/AgI/Ag plasmonic heterostructure photocathode was successfully designed through electrodeposition, ion-exchange, and illumination methods. This photocathode exhibits superior performance in photoelectrochemical water splitting.

MATERIALS LETTERS (2024)

Article Materials Science, Multidisciplinary

Ni@O-doped carbon Mott-Schottky heterojunctions to enhance sulfur conversion kinetics

Xiaoxiao Liu, Xianxian Zhou, Xiaotao Ma, Qinbo Yuan, Shibin Liu

Summary: In this study, the authors propose a method to accelerate the reaction of polysulfides in lithium-sulfur batteries using a Ni@OC Mott-Schottky heterojunction as a catalyst. The experimental results demonstrate that the charge redistribution at the Ni@OC interface accelerates electron transfer and enhances catalytic activity, leading to improved reaction kinetics and battery performance.

MATERIALS LETTERS (2024)

Article Materials Science, Multidisciplinary

Effect of fixture boundary conditions for low-velocity impact: A focus on composites with different matrix and fibers

Dayou Ma, Mohammad Rezasefat, Joziel Aparecido da Cruz, Sandro Campos Amico, Marco Giglio, Andrea Manes

Summary: The matrix has a significant effect on the impact resistance of composite materials. Replacing a brittle polymer with a more flexible one can improve impact resistance, but it poses challenges to standard testing methods. This study designs a new fixture for testing the low-velocity impact of soft composites and investigates the effect of the fixture on the mechanical performance.

MATERIALS LETTERS (2024)

Article Materials Science, Multidisciplinary

Synergistic effect of defects and heterostructures endowing bronze titanium dioxide with superior lithium storage performances

Lingchang Wang, Qihang Yang, Huzhen Li, Ming Wei, Qian Wang, Zhenzhong Hu, Mengmeng Zhen

Summary: Bronze titanium dioxide (TiO2(B)) is a promising anode material for lithium-ion batteries due to its high specific capacity. However, its practical applications are hindered by poor conductivity and limited electrochemical kinetics. In this study, TiO2(B)-carbon nanosheets heterostructures are synthesized to enhance the cycling performance and rate capability of TiO2(B).

MATERIALS LETTERS (2024)

Article Materials Science, Multidisciplinary

Sustained electromagnetic parameters of barium ferrite and epoxy nanocomposites for patch antenna miniaturization over GHz frequency range

Atul Thakur, Ritesh Verma, Ankush Chauhan, Fayu Wan, Preeti Thakur

Summary: In this study, BaFe12O19 and BaFe12O19: Epoxy (50:50) nanocomposites were synthesized using the co-precipitation method. The structural information and material properties, such as crystallite size and electrical conductivity, were characterized by XRD, FESEM, EDX, and TEM techniques.

MATERIALS LETTERS (2024)

Article Materials Science, Multidisciplinary

In-situ construction of CoS2@NC hierarchical binder-free cathode for advanced Li-CO2 batteries

Jingyu Wu, Xinyan Ma, Yong Yang

Summary: A well-defined CoS2@NC(CS-500) hierarchical binder-free catalyst cathode is constructed through in-situ grown of ZIF-67 on carbon cloth and high-temperature carbonization. The cathode shows excellent reaction kinetics and electrochemical performance, providing inspiration for developing advanced Li-CO2 battery catalysts.

MATERIALS LETTERS (2024)

Article Materials Science, Multidisciplinary

K5Eu1-xHox(MoO4)4: Structures and luminescence properties

Svetlana M. Posokhova, Vladimir A. Morozov, Kirill N. Boldyrev, Dina Deyneko, Erzhena T. Pavlova, Bogdan I. Lazoryak

Summary: This study explores the impact of synthesis method and composition on the structure and luminescence properties of K5Eu1-xHox(MoO4)4 with the palmierite-type matrix. The co-doping of Eu3+ and Ho3+ ions plays a critical role in manipulating charge transfer and luminescence efficiency in the visible and infrared regions.

MATERIALS LETTERS (2024)

Article Materials Science, Multidisciplinary

Benzonitrile/pyridylbenzoimidazole hybrid electron-transport material for efficient phosphorescence and TADF OLEDs

Jian Wang, Yeting Tao, Jingsheng Wang, Youtian Tao

Summary: A new electron-transport material iTPyBI-CN is developed through non-catalytic C-N coupling reaction. It exhibits better electroluminescence efficiency in organic light-emitting diodes compared to the commercial material TPBI, due to its twisted geometry and higher energy levels.

MATERIALS LETTERS (2024)

Article Materials Science, Multidisciplinary

Microscopic characteristics and thermodynamic property changes in limestone under high-temperature treatment

Tao Zhu, Feng Huang, Shuo Li, Yang Zhou

Summary: This article combines XRD analysis and microscopic structural observation to investigate the changes in limestone after high-temperature treatment. It finds that 500 degrees C is the critical temperature for crystalline and spatial arrangement changes in limestone, and the thermal conductivity, specific heat capacity, and heat storage coefficient gradually decrease after thermal treatment.

MATERIALS LETTERS (2024)

Article Materials Science, Multidisciplinary

Novel synthesis of ZnO nanostructure from galvanization waste for antibacterial application

Muhammad Haekal Habibie, Fransiska Sri Herwahyu Krismastuti, Abdi Wira Septama, Faiza Maryani, Vivi Fauzia

Summary: This study focuses on the synthesis of zinc oxide nanostructure from zinc recovered from galvanization ash and highlights its potential as a sustainable source of zinc and as an antibacterial agent.

MATERIALS LETTERS (2024)

Article Materials Science, Multidisciplinary

Biomimetic mineralization engineered phycocyanin with improved stability and antioxidantive activity under environmental stress

Jingyi Li, Yixin Xing, Wei Gu, Shousi Lu

Summary: In this study, PC@CaP microparticles were fabricated using biomimetic mineralization. The results showed that under environmental stress, PC@CaP exhibited improved stability and antioxidative activity, indicating its potential use in high-added value fields.

MATERIALS LETTERS (2024)

Article Materials Science, Multidisciplinary

ZIF-8 nanoparticles combined with fibroin protein co-modified TiO2 nanotube arrays to construct a drug sustained-release platform

Yan Liu, Shunyou Chen

Summary: In this study, TNTs were used as a drug carrier and modified with ZIF-8 and silk fibroin to obtain a new drug loading platform. The results showed that this drug-loaded platform had a good drug release effect in vitro and could promote cell proliferation and osteogenic differentiation.

MATERIALS LETTERS (2024)

Article Materials Science, Multidisciplinary

Observation of stacking faults in ε-phase InSe crystal

Chunhui Zhu, Wentao Wang, Qing Zhen, Xinning Huang, Shixin Li, Shaochang Wang, Xiaoping Ma, Xiaoxia Liu, Yalong Jiao, Kai Sun, Zhuangzhi Li, Huaixin Yang, Jianqi Li

Summary: A type of stacking fault is revealed in e-InSe crystal, which is associated with a small stacking-fault energy and shows exceptional plasticity.

MATERIALS LETTERS (2024)