期刊
MATERIALS LETTERS
卷 63, 期 12, 页码 1037-1040出版社
ELSEVIER SCIENCE BV
DOI: 10.1016/j.matlet.2009.02.001
关键词
Alkaline treatment; Desilication; Hierarchical zeolites; Mesopore formation; Trivalent cation
资金
- The Spanish MEC [CTQ2006-01562/PPQ, PTQ05-01-00980, CSD2006-0003]
- ICIQ Foundation
- ICREA Funding Source: Custom
Desilication in alkaline medium is demonstrated as a general route to synthesize hierarchical metallosilicate zeolite crystals with preserved crystallinity. The lattice trivalent cation (not only Al3+ but also Ga3+, Fe3+, and B3+) regulates the alkaline-assisted hydrolysis of silicon towards controlled mesoporosity development. This finding widens the family of modified zeolite compositions that integrate in a single crystalline material micropores and mesopores and enables better accessibility in catalytic applications compared to the purely microporous counterparts. (C) 2009 Elsevier B.V. All rights reserved.
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