Article
Polymer Science
Jiawei Li, Chengyu Hong, Hao Zhang, Ye Han, Xin Li, Ruonan Sun, Chao Zhou
Summary: In this study, self-cross-linking silylated polyvinylidene chloride (PVMBV) emulsions with core-shell structure were synthesized using seed emulsion polymerization method. The addition of vinyltrimethoxysilane (VTMO) cross-linker significantly improved the adhesion, thermal stability, toughness, and hydrophobicity of PVMBV films. Additionally, the barrier properties of PVMBV films were effectively enhanced by incorporating a small quantity of VTMO. These findings suggest potential applications of PVMBV coatings in multifunctional barrier coatings for vapor barrier, water barrier, weathering, and corrosion protection.
Article
Materials Science, Multidisciplinary
Juan Yang, Yuanchun Mu, Xiaoyu Li
Summary: We describe a new method for synthesizing phase-separated multilayer core-shell emulsion particles with different morphologies, such as multilayer inverse core-shell (MLICS) particles and multilayer sea-island core-shell (MLSICS) particles. The morphology and size of the particles during the multistage polymerization process were characterized using transmission electron microscopy (TEM) and dynamic laser scattering (DLS) methods. The effect of the crosslinking agent, divinylbenzene (DVB), on particle morphology was also discussed.
Article
Polymer Science
Junpeng Cao, Yingxin Tan, Xiaocong Dai, Ying Chen, Li Zhang, Jianbo Tan
Summary: In this study, the intrinsic monomer-feeding mechanism of RAFT-mediated emulsion polymerization was utilized to delay in situ crosslinking during PISA, enabling the preparation of cross-linked block copolymer nano-objects with high crosslinker contents. The use of various cross-linkers with different properties was demonstrated to promote the formation of higher-order morphologies.
Article
Polymer Science
Zhengliang Bian, Lin Zhang, Shuai Wu, Feng He, Fan Zhang, Jinshan Pan, Guoxin Xie
Summary: In this study, core-shell nanoparticles composed of PTFE as the core and PMMA as the shell were synthesized to improve the uniformity, tensile strength, and wear resistance of the resulting core-shell nanocomposites. The experiments demonstrated enhanced mechanical properties and reduced wear rate of the core-shell nanocomposites compared to mechanically mixed composites with the same composition. The study also investigated the effects of temperature on the friction coefficient and interfacial mechanical properties of the core-shell nanocomposites.
JOURNAL OF APPLIED POLYMER SCIENCE
(2021)
Article
Materials Science, Multidisciplinary
Elvis Lopes Brito, Nicholas Ballard
Summary: Controlling the colloidal structure of multiphase latex particles can improve the mechanical properties of dried films in coatings. However, there is often conflict between optimal mechanical properties and good film formation at reduced temperatures. This study focuses on two-stage latex particles with a high glass transition temperature (Tg). The results show that film formation behavior in multiphase latex systems is influenced by the interplay between various colloidal and polymeric features, and a balance between low Tg film formation properties and high Tg polymer mechanical properties can be achieved by targeting a core-shell structure.
MACROMOLECULAR MATERIALS AND ENGINEERING
(2023)
Article
Polymer Science
Elvis Lopes Brito, Nicholas Ballard
Summary: This study focuses on the synthesis and film formation behavior of hard-core/soft-shell latexes with varying compositions. It is found that the MFFT is significantly affected by the hard-core content, and film formation is restricted when the hard-core content is above 60%. Additionally, blending different core-shell particles can decrease the MFFT.
JOURNAL OF POLYMER SCIENCE
(2023)
Article
Polymer Science
Giselle Rosetta, Line Macaire, Mike Butters, Chris E. Finlayson
Summary: The emulsion polymerization process allows for control over the size and monodispersity of core-interlayer-shell polymer nanoparticles. By optimizing key experimental parameters, such as temperature, reactant purity, and agitation rate, composite particles with shear-orderable properties can be created. These findings have implications for the industrial-scale fabrication of polymeric photonic materials.
Article
Polymer Science
Ke Xu, Bo Fan, Kevin Putera, Michaela Wawryk, Jing Wan, Bo Peng, Mark M. Banaszak Holl, Antonio F. Patti, San H. Thang
Summary: This study demonstrates a new surfactant-free emulsion polymerization method, using surface cross-linking technology to achieve high cross-linking efficiency and prevent surfactant migration. This approach produces films with improved physical properties.
Article
Chemistry, Multidisciplinary
Lukas Siegwardt, Markus Gallei
Summary: A scalable protocol for designing and 3D-printing polymeric core-shell particles is presented. The particles are synthesized via emulsion polymerization and their architecture and composition can be tailored. The size, mechanical properties, and chemical functionalities of the particles can be controlled to meet specific requirements for additive manufacturing. The self-assembly of the monodisperse particles into an ordered lattice structure during 3D-printing results in visible reflection colors according to Bragg's law of diffraction. The resulting colors can be easily tuned by adjusting synthesis parameters, making the particles promising for various applications such as decorative ornaments and smart optical coatings.
ADVANCED FUNCTIONAL MATERIALS
(2023)
Article
Polymer Science
Lu Han, Lingxiao Li, Rongsheng Gao, Xueyan Liu, Chengyou Kan
Summary: Researchers have prepared stable and uniform core/shell polymer particles using a simple method, and investigated their adsorption behavior towards heavy metal ions. The core/shell particles showed high selectivity and adsorption capacity, indicating promising applications in water treatment.
JOURNAL OF APPLIED POLYMER SCIENCE
(2022)
Article
Chemistry, Physical
Cheng Yao, Yiheng Song, Yao Lu, Zhaodongfang Gao, Quanling Yang, Chuanxi Xiong
Summary: The liquid-like poly(6-chloroindole) doped with NPES exhibited good dispersion as core-shell nanoparticles, high electric conductivity, and blue-light emitting properties, making it a promising precursor for applications such as lightweight batteries, super capacitors, and anti-corrosion of metals and organic lasers.
Article
Chemistry, Multidisciplinary
Katsuhiro Onita, Miku Onishi, Taro Omura, Takeshi Wakiya, Toyoko Suzuki, Hideto Minami
Summary: Monodisperse bio-based polymer particles were prepared through dispersion polymerization. The particle size can be controlled by changing the composition of the reaction medium or PVP concentration. 100% bio-based PMBL particles were also prepared using hydrolyzed PMBL as a colloidal stabilizer.
Article
Biochemistry & Molecular Biology
Malgorzata Latos-Brozio, Anna Masek, Malgorzata Piotrowska
Summary: The study successfully obtained the polymeric form of catechin through a cross-linking reaction, enhancing its antioxidant and antibacterial properties, making it suitable for medical dressings and other applications.
Article
Chemistry, Physical
Yifan Chen, Xun Zhan, Sandra L. A. Bueno, Ibrahim H. Shafei, Hannah M. Ashberry, Kaustav Chatterjee, Lin Xu, Yawen Tang, Sara E. Skrabalak
Summary: A new method for converting core@shell NPs into HEA NPs through annealing was reported, showing potential for high-quality HEA NPs synthesis. By seed-mediated co-reduction, PdCu@PtNiCo NPs were prepared, which were then converted into singlecrystalline and single-phase PdCuPtNiCo NPs through annealing.
NANOSCALE HORIZONS
(2021)
Article
Polymer Science
Julia Kredel, Deborah Schmitt, Jan-Lukas Schaefer, Markus Biesalski, Markus Gallei
Summary: The study explores different strategies for a durable resistant cross-linking of a novel fluoropolymer on the surface of fibers. Coating surfaces with fluoropolymers can achieve oil and chemical repellent textiles. The use of degradable fluorinated side-chain monomers in polymer synthesis ensures durability during textile washing processes.
Article
Chemistry, Physical
Yanling Jia, Teng Qiu, Longhai Guo, Jun Ye, Lifan He, Xiaoyu Li
APPLIED SURFACE SCIENCE
(2020)
Article
Polymer Science
Yue Li, Longhai Guo, Jun Ye, Lifan He, Teng Qiu, Xiaoyu Li
Summary: This study synthesized a series of polymer latexes with different crosslinking agents and network distributions by controlling the emulsion polymerization process. It was found that the variation in crosslinking significantly affected the dynamic behavior of the latex and film properties. The sequential monomer feeding method showed good extensional damping performance, while the power monomer feeding method exhibited good constrained layer damping when using specific crosslinking agents.
JOURNAL OF APPLIED POLYMER SCIENCE
(2021)
Article
Polymer Science
Yifei Shi, Teng Qiu, Xinlin Tuo
JOURNAL OF APPLIED POLYMER SCIENCE
(2020)
Article
Polymer Science
Jing Chen, Teng Qiu, Longhai Guo, Lifan He, Xiaoyu Li
Summary: A new type of thermoresponsive hydrogel, amphiphilic ABA triblock copolymers, has been synthesized in this study. By adjusting the degree of polymerization of the hydrophilic A-block and the hydrophobic B-block, the sol-gel transition temperature of the copolymer can be controlled. These copolymers exhibit good anti-fogging properties and ice recrystallization inhibition activity, showing potential applications in various fields.
MACROMOLECULAR RAPID COMMUNICATIONS
(2021)
Article
Chemistry, Multidisciplinary
Chunjie Xie, Siyuan Liu, Qinguan Zhang, Huanxiao Ma, Shixuan Yang, Zhao-Xia Guo, Teng Qu, Xinlin Tuo
Summary: Aerogel is a low-density, highly porous material closely connected to complex processing methods. By using a modified freezing-drying method with polymerization-induced aramid nanofibers as building blocks, all-para-aromatic-amide aerogels with high efficiency can be prepared. The aerogels have high compressive strengths and low thermal conductivities, making them suitable for applications as thermal insulating or shock absorption materials.
Article
Chemistry, Multidisciplinary
Chunjie Xie, Zhao-Xia Guo, Teng Qiu, Xinlin Tuo
Summary: This study introduces a simple hierarchical self-assembly method for producing 3D all-PPTA engineering materials with complex structures and high performance.
ADVANCED MATERIALS
(2021)
Article
Polymer Science
Jing Lv, Longhai Guo, Chunjie Xie, Weitong Xu, Jun Ye, Xiaoyu Li, Teng Qiu, Xinlin Tuo
Summary: Aromatic polyamide nanofibers (ANF) have gained significant attention as a new type of nanomaterials. A study demonstrated that using isopropyl alcohol (IPA) to accelerate the chemical cleavage of chopped poly(p-phenylene terephthalamide) fibers efficiently prepares ANF with minimal dimensions and the highest tensile strength. Additionally, ANF/silicon hybrid films were successfully prepared with adjustable surface properties, showing potential for composite fabrication with various resin matrices.
JOURNAL OF APPLIED POLYMER SCIENCE
(2021)
Article
Polymer Science
Tianyu Gong, Longhai Guo, Jun Ye, Lifan He, Teng Qiu, Xiaoyu Li
Summary: A simple post-curing strategy based on core-shell structured acrylate latex was proposed in this study to improve the overall performance and CANs characteristics in latex films. By introducing a disulfide curing agent and conducting exchange reactions, the latex film exhibited thermal-induced dynamic behavior and achieved enhanced mechanical strength and water resistance.
JOURNAL OF POLYMER SCIENCE
(2021)
Article
Materials Science, Multidisciplinary
Sifan Gao, Ge Ma, Jun Ye, Lifan He, Longhai Guo, Xiaoyu Li, Teng Qiu, Xinlin Tuo
Summary: Recent research on waterborne polyurethane (WPU) focuses on incorporating aramid-urea segments to enhance the film performance in terms of tensile strength and wear resistance.
MATERIALS TODAY COMMUNICATIONS
(2021)
Article
Chemistry, Physical
Teng Qiu, Guangyi Xu, Xiaoyu Li, Longhai Guo
Summary: In this study, macro-porous polymer foams with thermo-responsive shape memory property were synthesized using a W/O high internal phase emulsion polymerization method. The transition temperature of the polyHIPEs can be adjusted by controlling the ratio of macro-monomer, fluorinated monomers, and acrylate monomers. The polyHIPEs exhibited excellent shape recovery ability by changing shape at high temperatures, maintaining the temporary shape at room temperature, and recovering almost completely upon reheating.
COLLOID AND POLYMER SCIENCE
(2022)
Article
Engineering, Environmental
Rihui Liang, Haotian Zhang, Yuhang Wang, Jun Ye, Longhai Guo, Lifan He, Xiaoyu Li, Teng Qiu, Xinlin Tuo
Summary: This research demonstrates the construction of a feasible dual dynamic network for waterborne polyurethane (WPU) using a biobased trifunctional ketose and a water soluble crosslinking agent. The network improves mechanical performances and achieves high recovery efficiency under moderate heating. Additionally, the material exhibits good adhesive strength and re-bonding capabilities. These features indicate the industrialization potential for environmentally friendly WPU materials.
CHEMICAL ENGINEERING JOURNAL
(2022)
Review
Biochemistry & Molecular Biology
Chunjie Xie, Shixuan Yang, Ran He, Jianning Liu, Yuexi Chen, Yongyi Guo, Zhaoxia Guo, Teng Qiu, Xinlin Tuo
Summary: This review provides a brief summary of the self-assembly methods of PPTA-based materials in recent years, with a focus on the polymerization-induced PPTA nanofibers that can be further fabricated into different macroscopic architectures when combined with other self-assembly methods. This monomer-started hierarchical self-assembly strategy enriches the processability and product diversity of PPTA.
Article
Nanoscience & Nanotechnology
Weitong Xu, Yushang Song, Chunjie Xie, Zehan Li, Jiawei Zong, Longhai Guo, Jun Ye, Xiaoyu Li, Teng Qiu, Xinlin Tuo
Summary: Using the polymerization-induced self-assembled (PISA) technique, a step-by-step decoration strategy on surfaces without deprotonation on poly(para-phenylene terephthalamide) (PPTA) is proposed. The strategy allows for modularity in chemical reactions and selective surface chemical choices, giving the nanofibers additional electrical activity and photothermal conversion capability. The unique surfaces built through the PISA process maintain their one-dimensional geometry and have potential for diverse applications.
ACS APPLIED NANO MATERIALS
(2022)
Article
Chemistry, Multidisciplinary
Shixuan Yang, Chunjie Xie, Teng Qiu, Xinlin Tuo
Summary: By using the aramid-coating-on-aramid method, all-aramid aerogel composite films with superior mechanical and thermal properties were successfully fabricated for thermal insulation.
Article
Biochemistry & Molecular Biology
Ge Ma, Qianshu Wang, Jun Ye, Lifan He, Longhai Guo, Xiaoyu Li, Teng Qiu, Xinlin Tuo
Summary: This study developed a high-performance waterborne polyurethane (WPU) as a binder for polymer fiber composites using a multi-step chain extension method. By optimizing the chain extending reaction, the WPU exhibited excellent mechanical properties, suitable interfacial adhesion, and potential application for high-performance fabric composites.
Article
Materials Science, Multidisciplinary
Deyong Zheng, Huihui Jin, Yucong Liao, Pengxia Ji
Summary: In this study, a highly stable and efficient catalyst, fluorine-doped Co3O4 (F-Co3O4), was developed for hydrogen production by water electrolysis. The F-Co3O4 catalyst exhibited a remarkable reduction in overpotential and demonstrated excellent stability for over 100 hours.
Article
Materials Science, Multidisciplinary
Ziwen Lv, Jintao Wang, Fengyi Wang, Jianqiang Wang, Fuquan Li, Hongtao Chen
Summary: Adding Cu6Sn5 nano particles can effectively inhibit the overgrowth of intermetallic compounds at the interfaces of solder joints in electronic devices, providing a solution to this issue. A new growth mechanism of intermetallic compounds at the interfaces was identified.
Article
Materials Science, Multidisciplinary
Jun Wang, Jiawei Chen, Wanru Liao, Fangyang Liu, Min Liu, Liangxing Jiang
Summary: A BiOI/AgI/Ag plasmonic heterostructure photocathode was successfully designed through electrodeposition, ion-exchange, and illumination methods. This photocathode exhibits superior performance in photoelectrochemical water splitting.
Article
Materials Science, Multidisciplinary
Xiaoxiao Liu, Xianxian Zhou, Xiaotao Ma, Qinbo Yuan, Shibin Liu
Summary: In this study, the authors propose a method to accelerate the reaction of polysulfides in lithium-sulfur batteries using a Ni@OC Mott-Schottky heterojunction as a catalyst. The experimental results demonstrate that the charge redistribution at the Ni@OC interface accelerates electron transfer and enhances catalytic activity, leading to improved reaction kinetics and battery performance.
Article
Materials Science, Multidisciplinary
Dayou Ma, Mohammad Rezasefat, Joziel Aparecido da Cruz, Sandro Campos Amico, Marco Giglio, Andrea Manes
Summary: The matrix has a significant effect on the impact resistance of composite materials. Replacing a brittle polymer with a more flexible one can improve impact resistance, but it poses challenges to standard testing methods. This study designs a new fixture for testing the low-velocity impact of soft composites and investigates the effect of the fixture on the mechanical performance.
Article
Materials Science, Multidisciplinary
Lingchang Wang, Qihang Yang, Huzhen Li, Ming Wei, Qian Wang, Zhenzhong Hu, Mengmeng Zhen
Summary: Bronze titanium dioxide (TiO2(B)) is a promising anode material for lithium-ion batteries due to its high specific capacity. However, its practical applications are hindered by poor conductivity and limited electrochemical kinetics. In this study, TiO2(B)-carbon nanosheets heterostructures are synthesized to enhance the cycling performance and rate capability of TiO2(B).
Article
Materials Science, Multidisciplinary
Atul Thakur, Ritesh Verma, Ankush Chauhan, Fayu Wan, Preeti Thakur
Summary: In this study, BaFe12O19 and BaFe12O19: Epoxy (50:50) nanocomposites were synthesized using the co-precipitation method. The structural information and material properties, such as crystallite size and electrical conductivity, were characterized by XRD, FESEM, EDX, and TEM techniques.
Article
Materials Science, Multidisciplinary
Jingyu Wu, Xinyan Ma, Yong Yang
Summary: A well-defined CoS2@NC(CS-500) hierarchical binder-free catalyst cathode is constructed through in-situ grown of ZIF-67 on carbon cloth and high-temperature carbonization. The cathode shows excellent reaction kinetics and electrochemical performance, providing inspiration for developing advanced Li-CO2 battery catalysts.
Article
Materials Science, Multidisciplinary
Svetlana M. Posokhova, Vladimir A. Morozov, Kirill N. Boldyrev, Dina Deyneko, Erzhena T. Pavlova, Bogdan I. Lazoryak
Summary: This study explores the impact of synthesis method and composition on the structure and luminescence properties of K5Eu1-xHox(MoO4)4 with the palmierite-type matrix. The co-doping of Eu3+ and Ho3+ ions plays a critical role in manipulating charge transfer and luminescence efficiency in the visible and infrared regions.
Article
Materials Science, Multidisciplinary
Jian Wang, Yeting Tao, Jingsheng Wang, Youtian Tao
Summary: A new electron-transport material iTPyBI-CN is developed through non-catalytic C-N coupling reaction. It exhibits better electroluminescence efficiency in organic light-emitting diodes compared to the commercial material TPBI, due to its twisted geometry and higher energy levels.
Article
Materials Science, Multidisciplinary
Tao Zhu, Feng Huang, Shuo Li, Yang Zhou
Summary: This article combines XRD analysis and microscopic structural observation to investigate the changes in limestone after high-temperature treatment. It finds that 500 degrees C is the critical temperature for crystalline and spatial arrangement changes in limestone, and the thermal conductivity, specific heat capacity, and heat storage coefficient gradually decrease after thermal treatment.
Article
Materials Science, Multidisciplinary
Muhammad Haekal Habibie, Fransiska Sri Herwahyu Krismastuti, Abdi Wira Septama, Faiza Maryani, Vivi Fauzia
Summary: This study focuses on the synthesis of zinc oxide nanostructure from zinc recovered from galvanization ash and highlights its potential as a sustainable source of zinc and as an antibacterial agent.
Article
Materials Science, Multidisciplinary
Jingyi Li, Yixin Xing, Wei Gu, Shousi Lu
Summary: In this study, PC@CaP microparticles were fabricated using biomimetic mineralization. The results showed that under environmental stress, PC@CaP exhibited improved stability and antioxidative activity, indicating its potential use in high-added value fields.
Article
Materials Science, Multidisciplinary
Yan Liu, Shunyou Chen
Summary: In this study, TNTs were used as a drug carrier and modified with ZIF-8 and silk fibroin to obtain a new drug loading platform. The results showed that this drug-loaded platform had a good drug release effect in vitro and could promote cell proliferation and osteogenic differentiation.
Article
Materials Science, Multidisciplinary
Chunhui Zhu, Wentao Wang, Qing Zhen, Xinning Huang, Shixin Li, Shaochang Wang, Xiaoping Ma, Xiaoxia Liu, Yalong Jiao, Kai Sun, Zhuangzhi Li, Huaixin Yang, Jianqi Li
Summary: A type of stacking fault is revealed in e-InSe crystal, which is associated with a small stacking-fault energy and shows exceptional plasticity.
