Review
Chemistry, Multidisciplinary
Olga Lebedeva, Dmitry Kultin, Leonid Kustov
Summary: This review explores the characteristics of electrochemical synthesis of nanostructures in ionic liquids, emphasizing the production of various nanomaterials and nanoscale polymer films. It highlights the potential application of ILs as an electrochemical medium and the relative simplicity of experimental procedures.
Review
Chemistry, Analytical
Pushpesh Ranjan, Shalu Yadav, Mohd Abubakar Sadique, Raju Khan, Jamana Prasad Chaurasia, Avanish Kumar Srivastava
Summary: The article discusses the potential of functional nanocomposites consisting of ionic liquids and carbon nanomaterials in electrochemical sensors and biosensor applications, enhancing sensor sensitivity and detection limits.
Article
Chemistry, Analytical
Ahmet Cetinkaya, S. Irem Kaya, Merve Yence, Fatma Budak, Sibel A. Ozkan
Summary: Ionic liquids (ILs) are widely used in various fields due to their unique properties. Their combination with nanostructures in electrochemical sensors has become popular. ILs-based materials are used to improve sensor performance and sensitivity. This review focuses on the applications of ILs-based materials modified electrochemical sensors for detecting environmental contaminants.
TRENDS IN ENVIRONMENTAL ANALYTICAL CHEMISTRY
(2023)
Article
Chemistry, Multidisciplinary
Yueting Xu, Yanfei Zhao, Fengtao Zhang, Yuepeng Wang, Ruipeng Li, Junfeng Xiang, Zhimin Liu
Summary: The alcoholysis of propylene oxide using azolate ionic liquids at room temperature results in high yields and excellent selectivity due to the cooperative hydrogen-bonding interactions between the anion and methanol, as well as between the cation and PO.
CHEMICAL COMMUNICATIONS
(2021)
Article
Chemistry, Multidisciplinary
Silke Wolf, Claus Feldmann
Summary: This article presents the synthesis and characterization of the pseudo-ternary tin(II) halide [BMPyr]2[SnCl4] by simply mixing the starting materials [BMPyr]Cl and SnCl2 at room temperature. The compound exhibits bright Sn(II)-based emission of deep-red light with a quantum yield of 88±3% after optimized synthesis. Characterization is performed using X-ray structure analysis, infrared, and fluorescence spectroscopy, and exemplary fluorescent thin films are achieved by solvent processing.
CHEMICAL COMMUNICATIONS
(2023)
Article
Chemistry, Multidisciplinary
Silke Wolf, Claus Feldmann
Summary: The pseudo-ternary tin(ii) halide [BMPyr]2[SnCl4] can be easily synthesized by mixing [BMPyr]Cl and SnCl2 at room temperature without additional solvents. The compound exhibits bright deep-red emission (lambda max: 740 nm) with a high quantum yield (88 +/- 3%) after optimized synthesis. Characterization includes X-ray structure analysis, infrared and fluorescence spectroscopy. Exemplary fluorescent thin films are prepared through solvent processing.
CHEMICAL COMMUNICATIONS
(2023)
Article
Chemistry, Inorganic & Nuclear
Andreia Forte, Sandra Gago, Manuela Ribeiro Carrott, Peter Carrott, Celso Alves, Fernando Teodoro, Rui Pedrosa, Isabel M. Marrucho, Luis C. Branco
Summary: Organic salts based on different choline derivative cations and metal ions were immobilized in mesoporous silica nanoparticles through a two-step synthetic method, characterized using various techniques and evaluated for cytotoxicity in different cell lines. The characterization data confirmed successful functionalization and provided insights into the materials' properties, while the cytotoxicity results revealed differences between the metal organic salts and their immobilized analogues.
DALTON TRANSACTIONS
(2021)
Article
Chemistry, Multidisciplinary
Patrice Perrenot, Adrien Fauchier-Magnan, Marta Mirolo, Laureline Lecarme, Pierre-Henri Jouneau, Adrien Boulineau, Pascale Bayle-Guillemaud, Claire Villevieille
Summary: This study provides a comprehensive understanding of the influence of room temperature sintering on thiophosphate solid electrolytes. It reveals that room temperature sintering is not straightforward and the commonly accepted rule of less porosity = better ionic conductivity is not always true. Multiple additional parameters should be considered for proper sintering of solid electrolytes.
ADVANCED FUNCTIONAL MATERIALS
(2023)
Article
Chemistry, Physical
Chandrakant Mukesh, Shokat Sarmad, Ajaikumar Samikannu, Dariush Nikjoo, William Siljebo, Jyri-Pekka Mikkola
Summary: In this study, porous ionic liquids (ILs) utilizing microporous ZIF-8 moieties and functional ILs were prepared and thoroughly characterized. The prepared porous ILs exhibited low viscosity, high thermal stability, and reusability, and showed enhanced CO2 sorption capacity compared to neat ILs.
JOURNAL OF MOLECULAR LIQUIDS
(2022)
Article
Materials Science, Multidisciplinary
Fanghua Tian, Jiale Guo, Qizhong Zhao, Kaili Li, Kaiyan Cao, Zhiyong Dai, Kaige Chang, Xiaoqin Ke, Minxia Fang, Yin Zhang, Chao Zhou, Sen Yang
Summary: This study found an unusual positive exchange bias effect in Co-CoO film at room temperature after zero-field cooling. The presence of crystallized Co/CoO and amorphous Co + CoO in the film leads to an exchange interaction between ferromagnetic, antiferromagnetic, and uncompensated antiferromagnetic components.
Article
Chemistry, Physical
Beichen Liu, Wenxiao Guo, Matthew A. Gebbie
Summary: In this study, we investigate the influence of ionic correlations on the reaction rates and selectivity of CO2 electroreduction. Through experiments, we find that at intermediate concentrations, the reduction rates of CO2 are accelerated and the efficiency of CO production is enhanced. The acceleration of CO2 reduction is due to the amplification of potential-dependent driving forces, rather than changes in onset potential. These findings are applicable to both cocatalytic and noncatalytic ions.
Article
Chemistry, Multidisciplinary
Tianqi Guo, Pengfei Hu, Lidong Li, Zhongchang Wang, Lin Guo
Summary: This article summarizes the important characteristics and applications of amorphous materials in the field of electrochemical energy storage and conversion, with particular emphasis on the significant roles of amorphous nanomaterials in lithium-ion batteries, lithium-metal batteries, and supercapacitors. It also discusses the challenges and future research directions for amorphous materials in various electrochemical techniques.
Article
Chemistry, Physical
H. Yu, Z. Wang, W. Tian, Z. Dai, Y. Xu, X. Li, L. Wang, H. Wang
Summary: A boron and sulfur co-doped mesoporous Rh film catalyst on Ni foam (B, S-mRh/NF) has been developed for electrochemical ammonia synthesis. The catalyst effectively inhibits competitive hydrogen evolution reaction and achieves high NH3 yield in neutral electrolyte, showing great potential for electrochemical ammonia synthesis.
MATERIALS TODAY ENERGY
(2021)
Article
Chemistry, Analytical
Simon Doblinger, Catherine E. Hay, Liliana C. Tome, David Mecerreyes, Debbie S. Silvester
Summary: This research investigates the use of mixed membranes composed of conductive poly(IL)s and ionic liquids in amperometric gas sensors. The study finds that the membranes exhibit high robustness and non-flowing properties, while also showing excellent and reproducible analytical responses towards gases. The results demonstrate the potential of these membranes as designer gas sensor materials for robust sensor devices.
ANALYTICA CHIMICA ACTA
(2022)
Article
Chemistry, Physical
Erik Piatti, Luca Guglielmero, Giorgio Tofani, Andrea Mezzetta, Lorenzo Guazzelli, Felicia D'Andrea, Stefano Roddaro, Christian Silvio Pomelli
Summary: Ionic gating is an effective tool for tuning material properties and developing low-temperature devices. Ionic liquids are promising gating agents due to their high thermal and electrochemical stability. This study aims to determine guidelines for synthesizing ionic liquids suitable for low-temperature electrolytes. Experimental results show that cations affect both cathodic and anodic limits, asymmetric ammonium cations have higher electrochemical stability, longer chain lengths decrease electrochemical stability, alkyl long chains have larger anodic limits but smaller cathodic limits compared to ether long chains of the same length, and the ether chain with the largest electrochemical stability contains three carbon atoms and one oxygen.
JOURNAL OF MOLECULAR LIQUIDS
(2022)
Article
Nanoscience & Nanotechnology
Xiong Zhang, Yanping Zhou, Bin Luo, Huacheng Zhu, Wei Chu, Kama Huang
NANO-MICRO LETTERS
(2018)
Article
Chemistry, Applied
Zhao Yan, Shuzhuang Liu, Yuanyuan Zhang, Ting Wang, Shizhong Luo, Wei Chu, Fangli Jing
Article
Chemistry, Physical
Jiang Jing, Luming Li, Wei Chu, Yahui Wei, Chengfa Jiang
INTERNATIONAL JOURNAL OF HYDROGEN ENERGY
(2018)
Article
Chemistry, Multidisciplinary
Jie Gao, Qian Jiang, Yuefeng Liu, Wei Liu, Wei Chu, Dang Sheng Su
Article
Chemistry, Physical
Hui Zhang, Qinmei Gong, Shan Ren, Mahmood Ali Arshid, Wei Chu, Chen Chen
CATALYSIS SCIENCE & TECHNOLOGY
(2018)
Article
Chemistry, Physical
Rui Yu, Rui Liu, Jie Deng, Maofei Ran, Ning Wang, Wei Chu, Zhiwei He, Zheng Du, Chengfa Jiang, Wenjing Sun
CATALYSIS SCIENCE & TECHNOLOGY
(2018)
Article
Chemistry, Physical
Yan Cao, Hongmei Zhang, Fujiao Song, Tao Huang, Jiayu Ji, Qin Zhong, Wei Chu, Qi Xu
Article
Chemistry, Applied
Min Wei, Qingsong Huang, Yanping Zhou, Zhu Peng, Wei Chu
JOURNAL OF ENERGY CHEMISTRY
(2018)
Article
Chemistry, Inorganic & Nuclear
Lei Li, Lin Sun, Hui Cang, Wei Chu, Jingling Shao, Jinlong Yan
JOURNAL OF SOLID STATE CHEMISTRY
(2018)
Article
Chemistry, Multidisciplinary
Rui Zhou, Dong Ge Tong
JOURNAL OF INDUSTRIAL AND ENGINEERING CHEMISTRY
(2020)
Article
Multidisciplinary Sciences
Qing Liang Wang, Dong Ge Tong
SN APPLIED SCIENCES
(2020)
Article
Nanoscience & Nanotechnology
De Li Xiang, Shu Mei Hou, Dong Ge Tong
ACS APPLIED NANO MATERIALS
(2019)
Article
Engineering, Chemical
Peng Zhou, Song Wang, ChuanLan Tao, Xingkui Guo, Luhan Hao, Qian Shao, Lei Liu, Ya-Ping Wang, Wei Chu, Bin Wang, Shi-Zhong Luo, Zhanhu Guo
ADVANCES IN POLYMER TECHNOLOGY
(2018)
Article
Chemistry, Applied
Di Zhang, Jingjie Luo, Jiajie Wang, Xin Xiao, Yuefeng Liu, Wei Qi, Dang Sheng Su, Wei Chu
CHINESE JOURNAL OF CATALYSIS
(2018)
Article
Green & Sustainable Science & Technology
Housseinou Ba, Wei Wang, Sergey Pronkin, Thierry Romero, Walid Baaziz, Lam Nguyen-Dinh, Wei Chu, Ovidiu Ersen, Cuong Pham-Huu
ADVANCED SUSTAINABLE SYSTEMS
(2018)
Article
Materials Science, Multidisciplinary
Deyong Zheng, Huihui Jin, Yucong Liao, Pengxia Ji
Summary: In this study, a highly stable and efficient catalyst, fluorine-doped Co3O4 (F-Co3O4), was developed for hydrogen production by water electrolysis. The F-Co3O4 catalyst exhibited a remarkable reduction in overpotential and demonstrated excellent stability for over 100 hours.
Article
Materials Science, Multidisciplinary
Ziwen Lv, Jintao Wang, Fengyi Wang, Jianqiang Wang, Fuquan Li, Hongtao Chen
Summary: Adding Cu6Sn5 nano particles can effectively inhibit the overgrowth of intermetallic compounds at the interfaces of solder joints in electronic devices, providing a solution to this issue. A new growth mechanism of intermetallic compounds at the interfaces was identified.
Article
Materials Science, Multidisciplinary
Jun Wang, Jiawei Chen, Wanru Liao, Fangyang Liu, Min Liu, Liangxing Jiang
Summary: A BiOI/AgI/Ag plasmonic heterostructure photocathode was successfully designed through electrodeposition, ion-exchange, and illumination methods. This photocathode exhibits superior performance in photoelectrochemical water splitting.
Article
Materials Science, Multidisciplinary
Xiaoxiao Liu, Xianxian Zhou, Xiaotao Ma, Qinbo Yuan, Shibin Liu
Summary: In this study, the authors propose a method to accelerate the reaction of polysulfides in lithium-sulfur batteries using a Ni@OC Mott-Schottky heterojunction as a catalyst. The experimental results demonstrate that the charge redistribution at the Ni@OC interface accelerates electron transfer and enhances catalytic activity, leading to improved reaction kinetics and battery performance.
Article
Materials Science, Multidisciplinary
Dayou Ma, Mohammad Rezasefat, Joziel Aparecido da Cruz, Sandro Campos Amico, Marco Giglio, Andrea Manes
Summary: The matrix has a significant effect on the impact resistance of composite materials. Replacing a brittle polymer with a more flexible one can improve impact resistance, but it poses challenges to standard testing methods. This study designs a new fixture for testing the low-velocity impact of soft composites and investigates the effect of the fixture on the mechanical performance.
Article
Materials Science, Multidisciplinary
Lingchang Wang, Qihang Yang, Huzhen Li, Ming Wei, Qian Wang, Zhenzhong Hu, Mengmeng Zhen
Summary: Bronze titanium dioxide (TiO2(B)) is a promising anode material for lithium-ion batteries due to its high specific capacity. However, its practical applications are hindered by poor conductivity and limited electrochemical kinetics. In this study, TiO2(B)-carbon nanosheets heterostructures are synthesized to enhance the cycling performance and rate capability of TiO2(B).
Article
Materials Science, Multidisciplinary
Atul Thakur, Ritesh Verma, Ankush Chauhan, Fayu Wan, Preeti Thakur
Summary: In this study, BaFe12O19 and BaFe12O19: Epoxy (50:50) nanocomposites were synthesized using the co-precipitation method. The structural information and material properties, such as crystallite size and electrical conductivity, were characterized by XRD, FESEM, EDX, and TEM techniques.
Article
Materials Science, Multidisciplinary
Jingyu Wu, Xinyan Ma, Yong Yang
Summary: A well-defined CoS2@NC(CS-500) hierarchical binder-free catalyst cathode is constructed through in-situ grown of ZIF-67 on carbon cloth and high-temperature carbonization. The cathode shows excellent reaction kinetics and electrochemical performance, providing inspiration for developing advanced Li-CO2 battery catalysts.
Article
Materials Science, Multidisciplinary
Svetlana M. Posokhova, Vladimir A. Morozov, Kirill N. Boldyrev, Dina Deyneko, Erzhena T. Pavlova, Bogdan I. Lazoryak
Summary: This study explores the impact of synthesis method and composition on the structure and luminescence properties of K5Eu1-xHox(MoO4)4 with the palmierite-type matrix. The co-doping of Eu3+ and Ho3+ ions plays a critical role in manipulating charge transfer and luminescence efficiency in the visible and infrared regions.
Article
Materials Science, Multidisciplinary
Jian Wang, Yeting Tao, Jingsheng Wang, Youtian Tao
Summary: A new electron-transport material iTPyBI-CN is developed through non-catalytic C-N coupling reaction. It exhibits better electroluminescence efficiency in organic light-emitting diodes compared to the commercial material TPBI, due to its twisted geometry and higher energy levels.
Article
Materials Science, Multidisciplinary
Tao Zhu, Feng Huang, Shuo Li, Yang Zhou
Summary: This article combines XRD analysis and microscopic structural observation to investigate the changes in limestone after high-temperature treatment. It finds that 500 degrees C is the critical temperature for crystalline and spatial arrangement changes in limestone, and the thermal conductivity, specific heat capacity, and heat storage coefficient gradually decrease after thermal treatment.
Article
Materials Science, Multidisciplinary
Muhammad Haekal Habibie, Fransiska Sri Herwahyu Krismastuti, Abdi Wira Septama, Faiza Maryani, Vivi Fauzia
Summary: This study focuses on the synthesis of zinc oxide nanostructure from zinc recovered from galvanization ash and highlights its potential as a sustainable source of zinc and as an antibacterial agent.
Article
Materials Science, Multidisciplinary
Jingyi Li, Yixin Xing, Wei Gu, Shousi Lu
Summary: In this study, PC@CaP microparticles were fabricated using biomimetic mineralization. The results showed that under environmental stress, PC@CaP exhibited improved stability and antioxidative activity, indicating its potential use in high-added value fields.
Article
Materials Science, Multidisciplinary
Yan Liu, Shunyou Chen
Summary: In this study, TNTs were used as a drug carrier and modified with ZIF-8 and silk fibroin to obtain a new drug loading platform. The results showed that this drug-loaded platform had a good drug release effect in vitro and could promote cell proliferation and osteogenic differentiation.
Article
Materials Science, Multidisciplinary
Chunhui Zhu, Wentao Wang, Qing Zhen, Xinning Huang, Shixin Li, Shaochang Wang, Xiaoping Ma, Xiaoxia Liu, Yalong Jiao, Kai Sun, Zhuangzhi Li, Huaixin Yang, Jianqi Li
Summary: A type of stacking fault is revealed in e-InSe crystal, which is associated with a small stacking-fault energy and shows exceptional plasticity.