期刊
MACROMOLECULAR RAPID COMMUNICATIONS
卷 35, 期 19, 页码 1646-1652出版社
WILEY-V C H VERLAG GMBH
DOI: 10.1002/marc.201400324
关键词
host-guest interaction; photo responsiveness; redox responsiveness; selective adhesion; supramolecular materials
资金
- Core Research for Evolutional Science and Technology program of the Japan Science and Technology Agency
- MEXT of Japan [25107718]
- Grants-in-Aid for Scientific Research [25107718, 26620103] Funding Source: KAKEN
Supramolecular materials based on host-guest interactions should exhibit high selectivity and external stimuli-responsiveness. Among various stimuli, redox and photo stimuli are useful for its wide application. An external stimuli-responsive adhesive system between CD host-gels (CD gels) and guest molecules modified glass substrates (guest Sub) is focused. Here, the selective adhesion between host gels and guest substrates where adhesion depends on molecular complementarity is reported. Initially, it is thought that adhesion of a gel material onto a hard material might be difficult unless many guest molecules modified linear polymers immobilize on the surface of hard materials. However, reversible adhesion of the CD gels is observed by dissociating and re-forming inclusion complex in response to redox and photo stimuli.
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