期刊
MACROMOLECULAR RAPID COMMUNICATIONS
卷 31, 期 8, 页码 714-717出版社
WILEY-V C H VERLAG GMBH
DOI: 10.1002/marc.200900789
关键词
amphiphilic polymer; block copolymers; isotactic; nanostructures; poly(methacrylic acid)
资金
- Kinki Regional Invention Center
- [21750220]
A novel approach is employed to produce core corona nanospheres, which introduces a stereoregular hydrophilic part to an amphiphilic block copolymer. The resultant morphology is reported using isotactic-poly(methacrylic acid)-block-poly(butyl acrylate). Infrared spectroscopy revealed a supramolecular interaction, and X ray diffraction revealed the crystallization of the outer isotactic-poly(methacrylic acid) part. The nanostructure, which looks like a nanosized 'grape', was formed when nanospheres and nanofibers coexisted simultaneously and partially fused.
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