期刊
MACROMOLECULAR RAPID COMMUNICATIONS
卷 30, 期 7, 页码 504-508出版社
WILEY-V C H VERLAG GMBH
DOI: 10.1002/marc.200800655
关键词
conjugated polymers; energy transfer; fluorescence; self-assembly; two-photon excitation
资金
- National University of Singapore [R-143-000-302-112, R-143-000-341-112]
- Singapore Agency for Science, Technology and Research [R-143-000-284-305]
Porphyrin-based systems are widely used as photosensitizers for photodynamic therapy, photocatalysis, and drug release. Strategies to enhance one- or two-photon excitation emission of porphyrin sensitizers have been of great interest and significance. Here we report an electrostatic assembly, which comprises a cationic conjugated polyelectrolyte, PFP, and a negatively charged hematoporphyrin (HP). An enhancement of over 9-fold in the HP emission intensity for one-photon excitation Forster resonance energy transfer (FRET), and an enhancement factor of 30-fold for two-photon excitation FRET were obtained. This electrostatic assembly can be easily modified in the future to construct DNA- or protein-programmed enhancement of porphyrin emission, which will be of great interest in porphyrin-based applications.
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