期刊
MACROMOLECULAR RAPID COMMUNICATIONS
卷 29, 期 1, 页码 52-56出版社
WILEY-V C H VERLAG GMBH
DOI: 10.1002/marc.200700646
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The B-ala/AIBN PBZ system has a high extent of ring-opening of oxazine because phenol-containing oligomers are formed at the early stage of the curing process. As a result, the B-ala/AIBN PBZ system possesses a relatively stronger intramolecular hydrogen bonding and lower surface energy than the pure B-ala system at low temperature curing. In this context, poly(4-vinyl pyridine), poly(4-vinyl phenol) thin films and polycarbonate substrates, which lack liquid resistance, possess low surface free energy after modification with B-ala/AIBN = 5/1 PBZ.
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