Article
Chemistry, Multidisciplinary
Nao Nagatomo, Hisashi Oishi, Yutaka Kuwahara, Makoto Takafuji, Reiko Oda, Taisuke Hamada, Hirotaka Ihara
Summary: By using a chiral molecular gelation system with a carboxylic acid functional group, enantioselectivity was effectively induced by forming highly ordered aggregates with negatively charged surfaces for carboxyl groups to assemble in highly ordered states and attaching the cationic groups of the guest molecule to this surface through multiple interactions.
Article
Polymer Science
Jihae Han, Mayu Osugi, Namie Ikeda, Kenta Fujii
Summary: In this study, a lithium salt-concentrated organogel was prepared via one-step gelation. The organogel exhibited efficient polymer network formation and good electrochemical properties, making it a promising quasi-solid electrolyte material for lithium-ion capacitors.
Article
Energy & Fuels
Sebastian Grott, Amir Kotobi, Lennart K. Reb, Christian L. Weindl, Renjun Guo, Shanshan Yin, Kerstin S. Wienhold, Wei Chen, Tayebeh Ameri, Matthias Schwartzkopf, Stephan Roth, Peter Mueller-Buschbaum
Summary: Non-fullerene acceptor (NFA)-based organic solar cells have shown significant progress in recent years. The choice of solvent for spin coating the active layers affects the film morphology and crystallinity. Among the compared chlorinated solvents (CB, chloroform, and dichlorobenzene), CB offers the best combination of small domain sizes, high number of edge-on crystallites, and small distances between neighboring domains. The smooth blend films obtained with CB have correlated roughness with the substrates and no large aggregates, leading to the highest power conversion efficiencies (PCEs).
Article
Engineering, Marine
Haifan Su, Shanying Zhu, Ziwen Yang, Cailian Chen, Xinping Guan
Summary: This paper investigates the bearing-based formation tracking control problem of multiple autonomous underwater vehicles (AUVs) with consideration of linear velocity and actuator constraints. A leader-follower structure is adopted, where the leaders' motion is characterized by a time-varying and unknown linear velocity. Consensus-based orientation estimator and adaptation law for estimating leaders' linear velocity are proposed. A bearing-based formation tracking controller is designed for the followers to achieve the desired formation shape. The global asymptotic stability of the overall system is analyzed using cascade system theories. The gains of the estimator and controller are determined by an optimal gains tuning method.
Article
Chemistry, Multidisciplinary
Dan Liu, Shanshan Dai, Li Wang, Ya Liu, Hongsheng Lu
Summary: In this study, an organogelator with pH-triggered recyclable property was developed, allowing the separation and recovery of organic solvents/oil and organogelator. This new approach provides a promising solution for the recovery of leaked organic solvents/oil by utilizing organogelators with pH responsiveness.
NEW JOURNAL OF CHEMISTRY
(2021)
Article
Chemistry, Applied
Naoaki Ikeda, Kenji Aramaki
Summary: This study investigated the formation of hydrogels using glutamic-acid-based organogelators. The hydrogels exhibited different properties depending on the type of micelles formed in the aqueous surfactant solution.
JOURNAL OF OLEO SCIENCE
(2022)
Review
Chemistry, Analytical
Ivan Torres-Moya, Jose Ramon Carrillo, Angel Diaz-Ortiz, Pilar Prieto
Summary: BTz is an excellent candidate in material science, with self-assembly ability, acceptor character, and ease of modulation. It can be used to produce various derivatives for applications in different fields such as optoelectronics or biomedicine.
Article
Polymer Science
Jonathan Bietsch, Mary Olson, Guijun Wang
Summary: Carbohydrate-based low molecular weight gelators have been synthesized and studied for their self-assembly and gel formation capabilities in various solvents. The compounds were found to form stable gels at low concentrations, potentially useful for drug delivery and water treatment applications.
Article
Chemistry, Multidisciplinary
Nicolas Zigon, Narcis Avarvari
Summary: Electrocrystallization is a common tool for assembling electroactive precursors into crystalline assemblies. Researchers have observed exotic physical effects by introducing chirality in molecular materials. In this study, organic electrolytes were synthesized to obtain crystals with different structures.
Article
Chemistry, Multidisciplinary
Tainan Duan, Wanying Feng, Yulu Li, Zhixiang Li, Zhe Zhang, Huazhe Liang, Hongbin Chen, Cheng Zhong, Seonghun Jeong, Changduk Yang, Shanshan Chen, Shirong Lu, Oleg A. Rakitin, Chenxi Li, Xiangjian Wan, Bin Kan, Yongsheng Chen
Summary: A new strategy was employed to synthesize acceptors with conjugation-extended electron-deficient cores, which can tune the energy levels, reduce nonradiative energy loss, enhance intramolecular packing, facilitate charge transport, and improve device performance.
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION
(2023)
Article
Materials Science, Multidisciplinary
Yuejie Zhu, Long Zhao, Zhengyin Du, GuanFan Chen, Yuexin Li, Lejia Wang, Xunwen Xiao
Summary: By optimizing the active layer morphology, effectively extracting charges, and reducing charge recombination, using TTF-PZ as a hole transport material can achieve high performance in the field of organic photovoltaics.
Article
Chemistry, Multidisciplinary
Usman Ali, Amina Tariq, Adeela Kiran, Faheem Abbas, Muhammad Tahir Khalil
Summary: Naphthalene diimide based non-fullerene organic solar cells were studied using density functional theory, resulting in the design of four novel structures with enhanced photovoltaic properties. Analysis included evaluation of reorganization energy, charge mobility, and open circuit voltage, showing improved optoelectronic properties for further solar cell device construction.
Article
Chemistry, Physical
Xuying Guo, Rugang Yao, Maogong Wang, Ryan Michael, Ethan Hoard, Jie Song, Fengqian Liang, Liujun Liu, Jianxin Jiang, Chunrui Han
Summary: The design and synthesis of rosin-based sulfonamide compounds with controllable weak forces is important for solving industrial problems. In this study, three such compounds were designed and formed different morphologies of organogels. The organogels successfully captured volatile organic solvents and formed stable supermolecular assemblies through the presence of conjugation. Among them, DBS-1 exhibited remarkable anti-settling ability in synthetic oil-based drilling fluids.
COLLOIDS AND SURFACES A-PHYSICOCHEMICAL AND ENGINEERING ASPECTS
(2024)
Article
Biochemistry & Molecular Biology
Junge Shang, Fang Zhong, Song Zhu, Dejian Huang, Yue Li
Summary: This study constructed a TP-loaded beeswax gelator to improve the oxidative stability of oleogels in soybean oil. The TP improved dispersity in lipids and inhibited lipid oxidation without participating in the internal network structure of the oleogel. The formation of needle-like crystals by beeswax restricted liquid oil flow, leading to a significant decrease in peroxide value during storage.
Article
Computer Science, Artificial Intelligence
Wendi Li, Ting Wang, Wing W. Y. Ng
Summary: In this work, a population-based hyperparameter tuning framework with multitask collaboration is proposed. The framework utilizes parallel and sequential phases to enhance generalization abilities and incorporates meta-information from existing tasks to assist the initialization of new tasks. Experimental results show significant improvements in neural network generalization abilities and better performance in multitask metalearning.
IEEE TRANSACTIONS ON NEURAL NETWORKS AND LEARNING SYSTEMS
(2023)