Article
Chemistry, Physical
Edgars Butanovs, Alexei Kuzmin, Sergei Piskunov, Krisjanis Smits, Aleksandr Kalinko, Boris Polyakov
Summary: The study demonstrates the growth of high-quality few-layer ReS2 using pre-deposited rhenium oxide coating on different semiconductor material nanowires, creating novel core-shell heterostructures for energy applications involving photocatalytic and electrocatalytic hydrogen evolution.
APPLIED SURFACE SCIENCE
(2021)
Article
Chemistry, Physical
E. Zielony, R. Szymon, A. Wierzbicka, A. Reszka, M. Sobanska, W. Pervez, Z. R. Zytkiewicz
Summary: In this study, Raman scattering and X-ray diffraction techniques were used to investigate strain and lattice vibration mechanisms in self-assembled GaN-AlxGa1-xN nanowire structures. The analysis of Raman spectra and XRD data provided insights into the chemical composition, strain, and lattice vibration mechanisms in these nanowires.
APPLIED SURFACE SCIENCE
(2022)
Article
Electrochemistry
Aida Raauf, David Graf, Yakup Gonullu, Praveen K. Sekhar, Michael Frank, Sanjay Mathur
Summary: The nanostructured thin film of Nd2Sn2O7 pyrochlore obtained through solution processing shows unprecedented selectivity towards hydrogen sensing, with the highest sensitivity towards H-2 detected at 300 degrees Celsius. The high efficiency and reproducibility of the investigated sensor devices indicate the potential of Nd2Sn2O7 based sensors for hydrogen safety applications.
JOURNAL OF THE ELECTROCHEMICAL SOCIETY
(2021)
Article
Chemistry, Multidisciplinary
Jaemyung Kim, Okkyun Seo, L. S. R. Kumara, Toshihide Nabatame, Yasuo Koide, Osami Sakata
Summary: The crystal quality of a 6 inch free-standing GaN substrate grown using a Na-flux based liquid phase epitaxy method was demonstrated by recording rocking curve profiles and analyzing lattice plane anisotropic bowing. The competition between crystallinity and homogeneity was observed in the substrate, with a mean rocking curve width of 0.024 degrees indicating almost single crystal quality.
Article
Chemistry, Physical
Khalid Mujasam Batoo, Ritesh Verma, Ankush Chauhan, Rajesh Kumar, Muhammad Hadi, Omar M. Aldossary, Y. Al-Douri
Summary: This study reported the synthesis of Gd and Nb co-doped BT ceramic oxides and investigated their structural and electrical properties. Various analysis techniques were used to characterize the samples, revealing the influence of Gd and Nb doping on the electrical properties of the ceramic materials, which were found to improve with increasing dopant concentration.
JOURNAL OF ALLOYS AND COMPOUNDS
(2021)
Article
Physics, Multidisciplinary
Amit Kumar Mauraya, Debashrita Mahana, Prashant Tyagi, Ch Ramesh, Ajay Kumar Shukla, Sudhir Husale, Sunil Singh Kushvaha, Muthusamy Senthil Kumar
Summary: The influence of using different types of GaN targets on the surface morphology and structural quality of GaN epilayers was studied, with confirmation through X-ray rocking curve measurements and X-ray photoelectron spectroscopy. Further investigation was conducted on the effect of threading dislocation density on the ultraviolet photoresponse properties of GaN layers using metal-semiconductor-metal structures.
Article
Chemistry, Multidisciplinary
Hajime Kameo, Yudai Tanaka, Yoshihiro Shimoyama, Daisuke Izumi, Hiroyuki Matsuzaka, Yumiko Nakajima, Pierre Lavedan, Arnaud Le Gac, Didier Bourissou
Summary: A T-shaped Pt-0 complex with a diphosphine-borane (DPB) ligand was prepared. The Pt -> B interaction enhances the electrophilicity of the metal and triggers the addition of Lewis bases to give the corresponding tetracoordinate complexes. For the first time, anionic Pt-0 complexes are isolated and structurally authenticated.
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION
(2023)
Article
Multidisciplinary Sciences
Ulrich Burkhardt, Aimo Winkelmann, Horst Borrmann, Andreea Dumitriu, Markus Koenig, Grzegorz Cios, Yuri Grin
Summary: This study investigates the assignment of enantiomorphs using diffraction methods for X-rays and electrons. By comparing experimental and simulated Kikuchi patterns, enantiomorphs in polycrystalline materials of beta-Mn and Pt2Cu3B can be accurately determined.
Article
Chemistry, Physical
Yogesh Kumar, S. Tripathi, Mangla Nand, R. Jangir, V. Srihari, A. Das, R. Singh, U. Deshpande, S. N. Jha, A. Arya
Summary: This study investigated the effect of Nd doping on the structural, optical, and electronic properties of lanthanum monazite structure. Pure and Nd-doped LaPO4 powders were prepared and analyzed for their composition, oxidation states, crystal structure, and bandgaps. The results confirmed the successful substitution of Nd in the LaPO4 matrix and provided insights into the local structure using extended X-ray absorption fine structure analysis.
JOURNAL OF ALLOYS AND COMPOUNDS
(2022)
Article
Nanoscience & Nanotechnology
Kyle P. Kelley, Vinit Sharma, Wenrui Zhang, Arthur P. Baddorf, Von B. Nascimento, Rama K. Vasudevan
Summary: The study reveals an unprecedented surface reconstruction in La₁-xSrₓMnO₃, indicating its potential for applications and the ability to tune surface ordering by controlling cation segregation.
ACS APPLIED MATERIALS & INTERFACES
(2021)
Article
Chemistry, Multidisciplinary
Samuel R. Baird, Emanuel Hupf, Ian C. Watson, Michael J. Ferguson, Eric Rivard
Summary: A tetramer shaped indium(I) organometallic compound supported by anionic N-heterocyclic olefin ligands is reported. The monomeric unit of this compound shows both Lewis acidic and basic properties at indium, and the steric profile of the N-heterocyclic olefin ligand enables the isolation of a rare monomeric imide.
CHEMICAL COMMUNICATIONS
(2023)
Article
Chemistry, Physical
Ritesh Verma, Ankush Chauhan, Khalid Mujasam Batoo, Muhammad Hadi, Emad H. Raslan, Rajesh Kumar, Muhammad Farzik Ijaz, Abdulaziz K. Assaifan
Summary: The synthesis of vanadium-doped BCZT ceramic oxides was reported in this paper, confirming the existence of a solubility limit of V in BCZT ceramics. Analysis revealed the influence of crystal structure and formation of oxygen vacancies on the luminescence and electrical properties of the material.
JOURNAL OF ALLOYS AND COMPOUNDS
(2021)
Article
Chemistry, Physical
Yuki Tsujikawa, Xiaoni Zhang, Masafumi Horio, Tetsuya Wada, Masashige Miyamoto, Toshihide Sumi, Fumio Komori, Takahiro Kondo, Iwao Matsuda
Summary: The growth of novel two-dimensional materials, especially boron-based, on Cu(110) substrate has shown great potential in exploring 1D anisotropic ordered phases and understanding their electronic properties. Through the deposition of boron atoms, a 3x1 ordered phase with anisotropic characteristics has been discovered, which exhibits similarity to carbon polymers like bumulene. This finding provides a new platform for investigating the properties of 1D boron materials and deepening our understanding of their potential applications.
Article
Materials Science, Ceramics
Ayano Nakamoto, Kohta Nambu, Hiroshi Masuda, Hidehiro Yoshida
Summary: Undoped Y2O3 polycrystals were densified by flash sintering under DC or AC electric field with varying holding times up to 60 min. The chemical bonding state and crystal structure were investigated by X-ray photoelectron spectroscopy (XPS) and X-ray diffraction (XRD), respectively. DC flash sintering with longer holding times (>= 30 min) resulted in blackening in cathodic regions, indicating the electrode-dependent introduction of neutral oxygen vacancies. The Y 3d3/2 and Y 3d5/2 binding energies decreased with increasing holding time in both DC- and AC-flash-sintered Y2O3 specimens, regardless of polarity, indicating that positively charged oxygen vacancies were introduced by the flash sintering in an electrode-independent manner, even under DC electric field. XRD analysis revealed short-range structural fluctuations in flash-sintered specimens with longer holding times. These electrode-dependent and independent point defect generations under electric fields may be related to the enhanced atomic diffusion during flash sintering.
JOURNAL OF THE EUROPEAN CERAMIC SOCIETY
(2023)
Article
Chemistry, Physical
A. A. Yadav, Y. M. Hunge, Bo-Kyong Kim, Seok-Won Kang
Summary: A NiCo2O4 nanowire/NiCo2O4 nanosheet composite with a hierarchically arranged morphology showed enhanced electrochemical performance as a high-performance supercapacitor, with higher specific capacitance and cycling stability.
SURFACES AND INTERFACES
(2022)
Article
Physics, Applied
Uwe Jahn, Vladimir M. Kaganer, Karl K. Sabelfeld, Anastasya E. Kireeva, Jonas Laehnemann, Carsten Pfueller, Timur Flissikowski, Caroline Cheze, Klaus Biermann, Raffaella Calarco, Oliver Brandt
Summary: This study investigates the accurate knowledge about the spatial distribution of generated carriers needed for determining the carrier diffusion length of semiconductors such as GaN and GaAs through cathodoluminescence imaging. By measuring the cathodoluminescence intensity profiles across single quantum wells embedded in thick GaN and GaAs layers, the lateral distribution of generated carriers between sample temperatures of 10 and 300 K is obtained. The experimental cathodoluminescence profiles are observed to be wider than the calculated energy loss distributions, with the width increasing monotonically as the temperature decreases. This phenomenon is present in both GaN and GaAs and becomes more pronounced at higher acceleration voltages. The electron-phonon interaction and the shape of the initial carrier distribution are discussed as possible factors influencing this effect. Finally, a phenomenological approach is presented for simulating the carrier generation volume and investigating the temperature dependence of carrier diffusion.
PHYSICAL REVIEW APPLIED
(2022)
Review
Physics, Applied
Jonas Laehnemann, Vladimir M. Kaganer, Karl K. Sabelfeld, Anastasya E. Kireeva, Uwe Jahn, Caroline Cheze, Raffaella Calarco, Oliver Brandt
Summary: Threading dislocations with an edge component were found to impact carrier recombination and diffusion in GaN material, particularly near the surface and in deep layers. Experimental techniques such as cathodoluminescence imaging and Monte Carlo simulations were used to demonstrate the existence of an exciton dead zone around the dislocation, and reliable values of carrier diffusion length were extracted from dipole-like energy shifts.
PHYSICAL REVIEW APPLIED
(2022)
Article
Physics, Applied
Oliver Brandt, Vladimir M. Kaganer, Jonas Laehnemann, Timur Flissikowski, Carsten Pfueller, Karl K. Sabelfeld, Anastasya E. Kireeva, Caroline Cheze, Raffaella Calarco, Holger T. Grahn, Uwe Jahn
Summary: The diffusion length of excess carriers in GaN was determined using spatially resolved cathodoluminescence spectroscopy, and an increase in the participation of excitons in the diffusion process at low temperatures was observed.
PHYSICAL REVIEW APPLIED
(2022)
Article
Chemistry, Multidisciplinary
Roman Volkov, Nikolai Borgardt, Oleg Konovalov, Sergio Fernandez-Garrido, Oliver Brandt, Vladimir M. Kaganer
Summary: The study of GaN nanowires by transmission electron microscopy and X-ray scattering reveals that the cross-sectional shape of the nanowires evolves differently along the length, with {1100} side facets at the top and roundish shapes at the bottom. This is attributed to the different growth environments at the top and bottom of the nanowires, where axial growth and annealing processes occur, respectively. Grazing incidence small-angle X-ray scattering independently confirms these trends in the shape evolution of the sidewall facets.
NANOSCALE ADVANCES
(2022)
Article
Physics, Applied
T. Auzelle, C. Sinito, J. Laehnemann, G. Gao, T. Flissikowski, A. Trampert, S. Fernandez-Garrido, O. Brandt
Summary: We compared the properties of GaN/(Al,Ga)N multiple quantum wells grown by PA MBE and found that different polarity samples are comparable in terms of their morphological and structural perfection. At room temperature, N-polar samples exhibit better performance.
PHYSICAL REVIEW APPLIED
(2022)
Article
Chemistry, Physical
O. Romanyuk, A. Paszuk, I Gordeev, R. G. Wilks, S. Ueda, C. Hartmann, R. Felix, M. Baer, C. Schlueter, A. Gloskovskii, I Bartos, M. Nandy, J. Houdkova, P. Jiricek, W. Jaegermann, J. P. Hofmann, T. Hannappel
Summary: This study investigates the epitaxial growth of GaP films on As-terminated Si substrates and reveals the localization of As atoms in the GaP lattice and at the GaP/Si interface. Chemical shifts in As core levels were observed, and similar valence band offset values were obtained regardless of the doping type, substrate miscut, or As-terminated surface of the Si substrate. The band alignment diagram of the GaP(As)/Si(100) heterostructure was also deduced.
APPLIED SURFACE SCIENCE
(2022)
Article
Nanoscience & Nanotechnology
M. Oliva, V Kaganer, M. Pudelski, S. Meister, A. Tahraoui, L. Geelhaar, O. Brandt, T. Auzelle
Summary: We present a simple method for fabricating ordered arrays of GaN nanowires with high aspect ratios and small diameters. The process involves lithographic patterning, dry and wet etching, and utilizes a bilayer Ni/SiNx hard mask. The resulting nanowires are highly uniform and suitable for photonic applications. However, nanowire breaking or bundling occurs for diameters below approximately 20 nm, which is attributed to capillary forces during drying. Overall, the process shows good compatibility with optoelectronic applications and allows for regrowth after mask removal.
Article
Physics, Applied
Duc V. Dinh, Jonas Laehnemann, Lutz Geelhaar, Oliver Brandt
Summary: Using high-resolution x-ray diffractometry, the lattice parameters of undoped ScxAl1-xN layers grown on GaN templates were determined. The Sc content x of the layers was measured independently and ranged from 0 to 0.25. The in-plane lattice parameter of the layers increased linearly with increasing x, while the out-of-plane lattice parameter remained constant. Layers with x≈0.09 were lattice matched to GaN, resulting in a smooth surface and comparable structural perfection. In addition, a two-dimensional electron gas was induced at the ScxAl1-xN/GaN heterointerface, with the highest sheet electron density and mobility observed for lattice-matched conditions.
APPLIED PHYSICS LETTERS
(2023)
Article
Nanoscience & Nanotechnology
T. Auzelle, M. Oliva, P. John, M. Ramsteiner, A. Trampert, L. Geelhaar, O. Brandt
Summary: The self-assembly of GaN nanowires on TiN(111) substrates is examined using SiN x patches as nucleation seeds. The density of the nanowires can be tuned by three orders of magnitude by varying the amount of pre-deposited SiN x , bridging the density regimes achievable by direct self-assembly with MBE or MOVPE. This approach has potential applications in tuning the density of III-V semiconductors grown on inert surfaces like 2D materials.
Article
Chemistry, Multidisciplinary
Vladimir M. Kaganer, Oleg Konovalov, Gabriele Calabrese, David van Treeck, Albert Kwasniewski, Carsten Richter, Sergio Fernandez-Garrido, Oliver Brandt
Summary: GaN nanowires grown on Ti films sputtered on Al2O3 were studied using X-ray diffraction and grazing-incidence small-angle X-ray scattering. Different crystallites, including Ti, TiN, Ti3O, Ti3Al, and Ga2O3, were observed in the Ti film. The GaN nanowires exhibited a high degree of epitaxial orientation with the substrate due to the topotaxial crystallites in the Ti film. The size distributions and relative fractions of different side facets of the nanowires were determined using the Monte Carlo method and GISAXS.
JOURNAL OF APPLIED CRYSTALLOGRAPHY
(2023)
Article
Nanoscience & Nanotechnology
David van Treeck, Jonas Laehnemann, Oliver Brandt, Lutz Geelhaar
Summary: In this study, (In,Ga)N shells emitting in the green spectral range were grown around very thin GaN core nanowires using molecular beam epitaxy. A qualitative shell growth model was proposed to explain the influence of growth conditions on the sample morphology and In content. The results showed that with In acting as surfactant, the ternary (In,Ga)N shells exhibited higher thickness uniformity along the nanowire length compared to binary GaN.
Article
Nanoscience & Nanotechnology
P. John, M. Gomez Ruiz, L. van Deurzen, J. Laehnemann, A. Trampert, L. Geelhaar, O. Brandt, T. Auzelle
Summary: This study investigates the molecular beam epitaxy of AlN nanowires and identifies 1150 degrees C as the optimal growth temperature. The growth process involves the grain growth of the TiN film and the formation of preferred {111} facets for AlN nucleation. Luminescence experiments on the nanowires reveal a steep increase in deep-level signals above 1050 degrees C, potentially due to oxygen incorporation from the Al2O3 substrate.
Article
Nanoscience & Nanotechnology
David van Treeck, Jonas Laehnemann, Guanhui Gao, Sergio Fernandez Garrido, Oliver Brandt, Lutz Geelhaar
Summary: Taking advantage of directed atomic fluxes in molecular beam epitaxy, we have developed a method for sequentially depositing lateral (In, Ga)N shells on GaN nanowires. By manipulating the growth temperature and the In/Ga flux ratio, we have systematically investigated the incorporation of In and the resulting emission spectra.
Article
Nanoscience & Nanotechnology
L. van Deurzen, J. Singhal, J. Encomendero, N. Pieczulewski, C. S. Chang, Y. Cho, D. A. Muller, H. G. Xing, D. Jena, O. Brandt, J. Laehnemann
Summary: Using low-temperature cathodoluminescence spectroscopy, the properties of N- and Al- polar AlN layers grown on bulk AlN{0001} by molecular beam epitaxy are studied. Both polarities of layers exhibit a suppression of deep-level luminescence compared to the bulk AlN substrate, a total absence of the prevalent donor with an exciton binding energy of 28 meV, and a much increased intensity of the emission from free excitons. The dominant donor in these layers has an associated exciton binding energy of 13 meV. Additionally, the observation of excited exciton states up to the exciton continuum allows for the direct extraction of the Γ(5) free exciton binding energy of 57 meV.
Article
Nanoscience & Nanotechnology
Miriam Oliva, Timur Flissikowski, Michal Gora, Jonas Lahnemann, Jesus Herranz, Ryan B. Lewis, Oliver Marquardt, Manfred Ramsteiner, Lutz Geelhaar, Oliver Brandt
Summary: In this study, the spontaneous emission of zincblende GaAs/(Al,Ga)As core/shell nanowires was investigated using mu-photoluminescence spectroscopy. The results revealed the low degree of polytypism and high efficiency of these nanowires in terms of their internal quantum efficiency, extraction efficiency, and dependence on carrier density and temperature. Furthermore, the methodology established in this study can be applied to nanowires of other materials systems for optoelectronic applications.
ACS APPLIED NANO MATERIALS
(2023)