Oxa-Michael addition polymerization of acrylates catalyzed by N-heterocyclic carbenes

On the Mechanism of N-Heterocyclic Carbene-Catalyzed Reactions Involving Acyl Azoliums

(2014) Jessada Mahatthananchai et al.   ACCOUNTS OF CHEMICAL RESEARCH

On the Involvement of a Spiroepoxide Intermediate in N-Heterocyclic Carbene (NHC)-Catalyzed Benzoin Condensations - An Approach by Oxygenation of Deoxy-Breslow Intermediates

(2014) Albrecht Berkessel et al.   ADVANCED SYNTHESIS & CATALYSIS

N-Heterocyclic Carbene Catalyzed Activation of Esters: A New Option for Asymmetric Domino Reactions

(2014) Pankaj Chauhan et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Proton-Transfer Polymerization (HTP): Converting Methacrylates to Polyesters by an N-Heterocyclic Carbene

(2014) Miao Hong et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

N-Heterocyclic carbene-catalyzed formal cross-coupling reaction of α-haloenals with thiols: organocatalytic construction of sp2 carbon–sulfur bonds

(2014) Lin He et al.   CHEMICAL COMMUNICATIONS

Cyclodimerization versus Polymerization of Methyl Methacrylate Induced byN-Heterocyclic Carbenes: A Combined Experimental and Theoretical Study

(2014) Winnie Nzahou Ottou et al.   CHEMISTRY-A EUROPEAN JOURNAL

Cooperative N-Heterocyclic Carbene/Brønsted Acid Catalysis for the Tail-to-Tail (Co)dimerization of Methacrylonitrile

(2014) Terumasa Kato et al.   JOURNAL OF ORGANIC CHEMISTRY

N-Heterocyclic Carbene Catalyzed Carba-, Sulfa-, and Phospha-Michael Additions with NHC·CO2 Adducts as Precatalysts

(2014) Morgan Hans et al.   JOURNAL OF ORGANIC CHEMISTRY

Air Stable and Latent Single-Component Curing of Epoxy/Anhydride Resins Catalyzed by Thermally Liberated N-Heterocyclic Carbenes

(2014) Stefan Naumann et al.   MACROMOLECULES

An overview of N-heterocyclic carbenes

(2014) Matthew N. Hopkinson et al.   NATURE

The mechanism of the NHC catalyzed aza-Morita–Baylis–Hillman reaction: insights into a new substrate-catalyzed bimolecular pathway

(2014) Pritha Verma et al.   ORGANIC & BIOMOLECULAR CHEMISTRY

N-Heterocyclic Carbene Catalyzed Umpolung of Styrenes: Mechanistic Elucidation and Selective Tail-to-Tail Dimerization

(2014) Michael Schedler et al.   ORGANIC LETTERS

Liberation of N-heterocyclic carbenes (NHCs) from thermally labile progenitors: protected NHCs as versatile tools in organo- and polymerization catalysis

(2014) Stefan Naumann et al.   Catalysis Science & Technology

Zwitterionic Ring-Opening Polymerization for the Synthesis of High Molecular Weight Cyclic Polymers

(2013) Hayley A. Brown et al.   ACCOUNTS OF CHEMICAL RESEARCH

Diverse reactions of N-heterocyclic carbenes with an alkynylborane and isolation of a reactive zwitterionic borataallene

(2013) Rüdiger Bertermann et al.   CHEMICAL COMMUNICATIONS

N-Heterocyclic carbenes (NHCs) as organocatalysts and structural components in metal-free polymer synthesis

(2013) Maréva Fèvre et al.   CHEMICAL SOCIETY REVIEWS

Acyl anion free N-heterocyclic carbene organocatalysis

(2013) Sarah J. Ryan et al.   CHEMICAL SOCIETY REVIEWS

N-Heterocyclic Carbene Catalyzed [4+2] Cycloaddition of Nitroalkenes with Oxodienes

(2013) Xiang-Yu Chen et al.   CHEMISTRY-A EUROPEAN JOURNAL

Catalysis with N-Heterocyclic Carbenes under Oxidative Conditions

(2013) Suman De Sarkar et al.   CHEMISTRY-A EUROPEAN JOURNAL

Experimental Mechanistic Studies of the Tail-to-Tail Dimerization of Methyl Methacrylate Catalyzed by N-Heterocyclic Carbene

(2013) Terumasa Kato et al.   JOURNAL OF ORGANIC CHEMISTRY

Organocatalytic Conjugate-Addition Polymerization of Linear and Cyclic Acrylic Monomers by N-Heterocyclic Carbenes: Mechanisms of Chain Initiation, Propagation, and Termination

(2013) Yuetao Zhang et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Catalytic MBH reaction of β-substituted nitroalkenes with azodicarboxylates

(2013) Xiang-Yu Chen et al.   ORGANIC & BIOMOLECULAR CHEMISTRY

N-heterocyclic carbene-catalyzed reactions of C–C unsaturated bonds

(2013) Xiang-Yu Chen et al.   ORGANIC & BIOMOLECULAR CHEMISTRY

N-Heterocyclic Carbene-Catalyzed Cyclotetramerization of Acrylates

(2013) Shin-ichi Matsuoka et al.   ORGANIC LETTERS

Polymerization of methyl methacrylate by latent pre-catalysts based on CO2-protected N-heterocyclic carbenes

(2013) Stefan Naumann et al.   Polymer Chemistry

Conjugate-Addition Organopolymerization: Rapid Production of Acrylic Bioplastics by N-Heterocyclic Carbenes

(2012) Yuetao Zhang et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Nucleophilic Reactivities of Deoxy Breslow Intermediates: How Does Aromaticity Affect the Catalytic Activities of N-Heterocyclic Carbenes?

(2012) Biplab Maji et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

A quantitative approach to nucleophilic organocatalysis

(2012) Herbert Mayr et al.   Beilstein Journal of Organic Chemistry

Organocatalytic umpolung: N-heterocyclic carbenes and beyond

(2012) Xavier Bugaut et al.   CHEMICAL SOCIETY REVIEWS

Lewis pair polymerization by classical and frustrated Lewis pairs: acid, base and monomer scope and polymerization mechanism

(2012) Yuetao Zhang et al.   DALTON TRANSACTIONS

N-Heterocyclic carbene-catalysed synthesis of polyurethanes

(2012) Olivier Coutelier et al.   Polymer Chemistry

Organo-catalyzed synthesis of aliphatic polycarbonates in solvent-free conditions

(2012) Prashant U. Naik et al.   Polymer Chemistry

Sequential one-pot and three-component reactions of an N-heterocyclic carbene to form 4-(1,2,4-triazol-5-ylidene)pyrrolidine-2,5-diones: a tandem umpolung/annulation sequence via deoxy-Breslow intermediates

(2012) Shin-ichi Matsuoka et al.   TETRAHEDRON

Extending NHC-Catalysis: Coupling Aldehydes with Unconventional Reaction Partners

(2011) Akkattu T. Biju et al.   ACCOUNTS OF CHEMICAL RESEARCH

N-Heterocyclic Carbenes: Organocatalysts with Moderate Nucleophilicity but Extraordinarily High Lewis Basicity

(2011) Biplab Maji et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

N-Heterocyclic Carbene Catalyzed Domino Reactions

(2011) André Grossmann et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

N-Heterocyclic Carbene Catalyzed Umpolung of Michael Acceptors for Intermolecular Reactions

(2011) Akkattu T. Biju et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

N-Heterocyclic Carbene-Promoted Rauhut - Currier Reactions between Vinyl Sulfones and α,β-Unsaturated Aldehydes

(2011) Roxanne L. Atienza et al.   AUSTRALIAN JOURNAL OF CHEMISTRY

Employing homoenolates generated by NHC catalysis in carbon–carbon bond-forming reactions: state of the art

(2011) Vijay Nair et al.   CHEMICAL SOCIETY REVIEWS

Dual Activation in N-Heterocyclic Carbene-organocatalysis

(2011) Keiichi Hirano et al.   CHEMISTRY LETTERS

N-Heterocyclic Carbene-Catalyzed Michael Additions of 1,3-Dicarbonyl Compounds

(2011) Thomas Boddaert et al.   CHEMISTRY-A EUROPEAN JOURNAL

Computational Mechanistic Study of PMe3andN-Heterocyclic Carbene Catalyzed Intramolecular Morita−Baylis−Hillman-Like Cycloalkylations: The Origins of the Different Reactivity

(2011) Lili Zhao et al.   JOURNAL OF ORGANIC CHEMISTRY

N-Heterocyclic carbene-catalyzed aza-Michael addition

(2011) Qiang Kang et al.   ORGANIC & BIOMOLECULAR CHEMISTRY

Organocatalytic Tail-to-Tail Dimerization of Olefin: Umpolung of Methyl Methacrylate Mediated by N-Heterocyclic Carbene

(2011) Shin-ichi Matsuoka et al.   ORGANIC LETTERS

Organocatalytic head-to-tail dimerization of methacrolein via conjugate addition of methanol: an alcohol activation mechanism proved by electrospray ionization mass spectrometry

(2011) Shin-ichi Matsuoka et al.   TETRAHEDRON LETTERS

N-heterocyclic carbene-catalyzed rearrangements of vinyl sulfones

(2011) Roxanne L. Atienza et al.   Chemical Science

Cooperative Lewis acid/N-heterocyclic carbene catalysis

(2011) Daniel T. Cohen et al.   Chemical Science

Intramolecular Stereoselective Protonation of Aldehyde-Derived Enolates

(2010) Anastasie Kena Diba et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Alane-Based Classical and Frustrated Lewis Pairs in Polymer Synthesis: Rapid Polymerization of MMA and Naturally Renewable Methylene Butyrolactones into High-Molecular-Weight Polymers

(2010) Yuetao Zhang et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

N-Heterocyclic Carbene-Catalyzed Conjugate Additions of Alcohols

(2010) Eric M. Phillips et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Organocatalysis: Opportunities and Challenges for Polymer Synthesis

(2010) Matthew K. Kiesewetter et al.   MACROMOLECULES

On new N-heterocyclic carbene derived alkylidene imidazolines

(2010) Christiane E. I. Knappke et al.   ORGANIC & BIOMOLECULAR CHEMISTRY

CO2and SnIIAdducts of N-Heterocyclic Carbenes as Delayed-Action Catalysts for Polyurethane Synthesis

(2009) Bhasker Bantu et al.   CHEMISTRY-A EUROPEAN JOURNAL

CO2, Magnesium, Aluminum, and Zinc Adducts of N-Heterocyclic Carbenes as (Latent) Catalysts for Polyurethane Synthesis

(2009) Bhasker Bantu et al.   EUROPEAN JOURNAL OF INORGANIC CHEMISTRY

Step-Growth Polymerization of Terephthaldehyde Catalyzed byN-Heterocyclic Carbenes

(2009) Julien Pinaud et al.   MACROMOLECULES

Group Transfer Polymerization of (Meth)acrylic Monomers Catalyzed byN-Heterocyclic Carbenes and Synthesis of All Acrylic Block Copolymers: Evidence for an Associative Mechanism

(2009) Jean Raynaud et al.   MACROMOLECULES

Nucleophilic heterocyclic carbene as a novel catalyst for cyclopropanation of cyano acrylates

(2009) Anabha E. Raveendran et al.   ORGANIC & BIOMOLECULAR CHEMISTRY

13C NMR Spectroscopic Determination of Ligand Donor Strengths Using N-Heterocyclic Carbene Complexes of Palladium(II)

(2009) Han Vinh Huynh et al.   ORGANOMETALLICS

Harnessing the Potential of N‐Heterocyclic Carbenes for the Rejuvenation of Group‐Transfer Polymerization of (Meth)Acrylics

(2008) Jean Raynaud et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Recent advances in carbon–carbon bond-forming reactions involving homoenolates generated by NHC catalysis

(2008) Vijay Nair et al.   CHEMICAL SOCIETY REVIEWS

N-Heterocyclic carbene-catalyzed dehydration of α,ω-disilanol oligomers

(2008) Sébastien Marrot et al.   JOURNAL OF ORGANOMETALLIC CHEMISTRY

Group Transfer Polymerization of Acrylates Catalyzed by N-Heterocyclic Carbenes

(2008) Marc D. Scholten et al.   MACROMOLECULES