Lewis pair polymerization by classical and frustrated Lewis pairs: acid, base and monomer scope and polymerization mechanism

Fullerenes as Neutral Carbon-Based Lewis Acids

(2012) Javier Iglesias-Sigüenza et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Conjugate-Addition Organopolymerization: Rapid Production of Acrylic Bioplastics by N-Heterocyclic Carbenes

(2012) Yuetao Zhang et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Reaction of a 6-Dimethylaminopentafulvene with the Mes2PCH2CH2B(C6F5)2 Frustrated Lewis Pair

(2012) Bao-Hua Xu et al.   CHEMISTRY-A EUROPEAN JOURNAL

Heterolytic Cleavage of Dihydrogen by “Frustrated Lewis Pairs” Comprising Bis(2,4,6-tris(trifluoromethyl)phenyl)borane and Amines: Stepwise versus Concerted Mechanism

(2011) Zhenpin Lu et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Capture of NO by a Frustrated Lewis Pair: A New Type of Persistent N-Oxyl Radical

(2011) Allan Jay P. Cardenas et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Stoichiometric Reduction of CO2 to CO by Aluminum-Based Frustrated Lewis Pairs

(2011) Gabriel Ménard et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

N-Heterocyclic Carbene Catalyzed Umpolung of Michael Acceptors for Intermolecular Reactions

(2011) Akkattu T. Biju et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Reaction of Frustrated Lewis Pairs with Conjugated Ynones-Selective Hydrogenation of the Carbon-Carbon Triple Bond

(2011) Bao-Hua Xu et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Geminal Phosphorus/Aluminum-Based Frustrated Lewis Pairs: CH versus CC Activation and CO2Fixation

(2011) Christian Appelt et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

A New Synthesis of Triarylsilylium Ions and Their Application in Dihydrogen Activation

(2011) André Schäfer et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

The frustrated Lewis pair induced formation of a pentafulvene [6 + 4] cycloaddition product

(2011) Cornelia M. Mömming et al.   CHEMICAL COMMUNICATIONS

Bis-boranes in the frustrated Lewis pair activation of carbon dioxide

(2011) Xiaoxi Zhao et al.   CHEMICAL COMMUNICATIONS

Metal-free diastereoselective catalytic hydrogenations of imines using B(C6F5)3

(2011) Zachariah M. Heiden et al.   CHEMICAL COMMUNICATIONS

Catalytic Hydrogenation with Frustrated Lewis Pairs: Selectivity Achieved by Size-Exclusion Design of Lewis Acids

(2011) Gábor Erős et al.   CHEMISTRY-A EUROPEAN JOURNAL

On the Accuracy of DFT Methods in Reproducing Ligand Substitution Energies for Transition Metal Complexes in Solution: The Role of Dispersive Interactions

(2011) Heiko Jacobsen et al.   CHEMPHYSCHEM

Organometallic frustrated Lewis pair chemistry

(2011) Gerhard Erker   DALTON TRANSACTIONS

Mechanistic Aspects of Bond Activation with Perfluoroarylboranes

(2011) Warren E. Piers et al.   INORGANIC CHEMISTRY

Metal-Free Catalytic Hydrogenation of Polar Substrates by Frustrated Lewis Pairs

(2011) Douglas W. Stephan et al.   INORGANIC CHEMISTRY

Dihydrogen Activation by Frustrated Carbene-Borane Lewis Pairs: An Experimental and Theoretical Study of Carbene Variation

(2011) Sabrina Kronig et al.   INORGANIC CHEMISTRY

P−C Bond Activation Chemistry: Evidence for 1,1-Carboboration Reactions Proceeding with Phosphorus−Carbon Bond Cleavage

(2011) Olga Ekkert et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Olefin–Borane “van der Waals Complexes”: Intermediates in Frustrated Lewis Pair Addition Reactions

(2011) Xiaoxi Zhao et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Frustrated Lewis Pairs beyond the Main Group: Cationic Zirconocene–Phosphinoaryloxide Complexes and Their Application in Catalytic Dehydrogenation of Amine Boranes

(2011) Andy M. Chapman et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Dihydrogen Activation withtBu3P/B(C6F5)3: A Chemically Competent Indirect Mechanism via in Situ-Generatedp-tBu2P–C6F4–B(C6F5)2

(2011) Adam J. V. Marwitz et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Preorganized Frustrated Lewis Pairs

(2011) Federica Bertini et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Fullerene–Carbene Lewis Acid–Base Adducts

(2011) Huaping Li et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Dinuclear Silylium-enolate Bifunctional Active Species: Remarkable Activity and Stereoselectivity toward Polymerization of Methacrylate and Renewable Methylene Butyrolactone Monomers

(2011) Yuetao Zhang et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Organocatalytic Tail-to-Tail Dimerization of Olefin: Umpolung of Methyl Methacrylate Mediated by N-Heterocyclic Carbene

(2011) Shin-ichi Matsuoka et al.   ORGANIC LETTERS

Formation of Cyclic Allenes and Cumulenes by Cooperative Addition of Frustrated Lewis Pairs to Conjugated Enynes and Diynes

(2010) Cornelia M. Mömming et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Heterolytic SS Bond Cleavage by a Purely Carbogenic Frustrated Lewis Pair

(2010) Blanca Inés et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Exploring the Reactivity of Carbon(0)/Borane-Based Frustrated Lewis Pairs

(2010) Manuel Alcarazo et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Alane-Based Classical and Frustrated Lewis Pairs in Polymer Synthesis: Rapid Polymerization of MMA and Naturally Renewable Methylene Butyrolactones into High-Molecular-Weight Polymers

(2010) Yuetao Zhang et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Expanding the Scope of Metal-Free Catalytic Hydrogenation through Frustrated Lewis Pair Design

(2010) Gábor Erős et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Enantioselective Hydrogenation with Chiral Frustrated Lewis Pairs

(2010) Dianjun Chen et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

The Mechanism of Dihydrogen Activation by Frustrated Lewis Pairs Revisited

(2010) Stefan Grimme et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Coordination polymerization of renewable butyrolactone-based vinyl monomers by lanthanide and early metal catalysts

(2010) Garret M. Miyake et al.   DALTON TRANSACTIONS

Tandem Frustrated Lewis Pair/Tris(pentafluorophenyl)borane-Catalyzed Deoxygenative Hydrosilylation of Carbon Dioxide

(2010) Andreas Berkefeld et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

The Catalytic Role of N-Heterocyclic Carbene in a Metal-Free Conversion of Carbon Dioxide into Methanol: A Computational Mechanism Study

(2010) Fang Huang et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Room Temperature Reduction of CO2to Methanol by Al-Based Frustrated Lewis Pairs and Ammonia Borane

(2010) Gabriel Ménard et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Homogeneous CO Hydrogenation: Dihydrogen Activation Involves a Frustrated Lewis Pair Instead of a Platinum Complex

(2010) Alexander J. M. Miller et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

An Investigation of Free Radical Copolymerization Kinetics of the Bio-renewable Monomerγ-Methyl-α-methylene-γ-butyrolactone with Methyl methacrylate and Styrene

(2010) Robert A. Cockburn et al.   MACROMOLECULAR CHEMISTRY AND PHYSICS

Polymerization of Naturally Renewable Methylene Butyrolactones by Half-Sandwich Indenyl Rare Earth Metal Dialkyls with Exceptional Activity

(2010) Yangjian Hu et al.   MACROMOLECULES

Living Polymerization of Naturally Renewable Butyrolactone-Based Vinylidene Monomers by Ambiphilic Silicon Propagators

(2010) Garret M. Miyake et al.   MACROMOLECULES

The synthesis and exchange chemistry of frustrated Lewis pair–nitrous oxide complexes

(2010) Rebecca C. Neu et al.   Chemical Science

Non-Metal-Mediated Homogeneous Hydrogenation of CO2 to CH3OH

(2009) Andrew E. Ashley et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Reversible Metal-Free Carbon Dioxide Binding by Frustrated Lewis Pairs

(2009) Cornelia M. Mömming et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Frustrated Lewis Pairs: Metal-free Hydrogen Activation and More

(2009) Douglas W. Stephan et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

1,4-Addition reactions of frustrated Lewis pairs to 1,3-dienes

(2009) Matthias Ullrich et al.   CHEMICAL COMMUNICATIONS

Coordination Polymerization of Polar Vinyl Monomers by Single-Site Metal Catalysts

(2009) Eugene Y.-X. Chen   CHEMICAL REVIEWS

Transformation of polymerization of polar vinyl monomers by discrete and hybrid metal catalysts

(2009) Eugene Y.-X. Chen   DALTON TRANSACTIONS

Heterolytic Cleavage of Disulfides by Frustrated Lewis Pairs

(2009) Meghan A. Dureen et al.   INORGANIC CHEMISTRY

Terminal Alkyne Activation by Frustrated and Classical Lewis Acid/Phosphine Pairs

(2009) Meghan A. Dureen et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Catalytic Hydrogenation of Sensitive Organometallic Compounds by Antagonistic N/B Lewis Pair Catalyst Systems

(2009) Kirill V. Axenov et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Group Transfer Polymerization of (Meth)acrylic Monomers Catalyzed byN-Heterocyclic Carbenes and Synthesis of All Acrylic Block Copolymers: Evidence for an Associative Mechanism

(2009) Jean Raynaud et al.   MACROMOLECULES

Cover Picture: Facile Heterolytic H2Activation by Amines and B(C6F5)3(Angew. Chem. Int. Ed. 32/2008)

(2008) Victor Sumerin et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Harnessing the Potential of N‐Heterocyclic Carbenes for the Rejuvenation of Group‐Transfer Polymerization of (Meth)Acrylics

(2008) Jean Raynaud et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Hydrogen and Amine Activation by a Frustrated Lewis Pair of a Bulky N-Heterocyclic Carbene and B(C6F5)3

(2008) Preston A. Chase et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Heterolytic Dihydrogen Activation by a Frustrated Carbene-Borane Lewis Pair

(2008) Dirk Holschumacher et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

B–H Activation by frustrated Lewis pairs: borenium or boryl phosphonium cation?

(2008) Meghan A. Dureen et al.   CHEMICAL COMMUNICATIONS

Relevance of cis- and trans-dichloride Ru intermediates in Grubbs-II olefin metathesis catalysis (H2IMesCl2RuCHR)

(2008) Diego Benitez et al.   CHEMICAL COMMUNICATIONS

Gas-Phase Thermochemistry of Ruthenium Carbene Metathesis Catalysts

(2008) Sebastian Torker et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Mechanism of Stereocontrol in Methyl Methacrylate Polymerization Promoted byC1-Symmetric Metallocenes

(2008) Lucia Caporaso et al.   MACROMOLECULES

Atom Transfer Radical Polymerization of Tulipalin A: A Naturally Renewable Monomer

(2008) Jaroslav Mosnáček et al.   MACROMOLECULES

Syndioselective MMA Polymerization by Group 4 Constrained Geometry Catalysts: A Combined Experimental and Theoretical Study

(2008) Yalan Ning et al.   MACROMOLECULES

Group Transfer Polymerization of Acrylates Catalyzed by N-Heterocyclic Carbenes

(2008) Marc D. Scholten et al.   MACROMOLECULES

Structure−Reactivity Relationships in Bimolecular-Activated Monomer Polymerization of (Meth)acrylates Using Oxidatively Activated Group 14 Ketene Acetals

(2008) Yuetao Zhang et al.   MACROMOLECULES

Gas-Phase Lewis Acidity of Perfluoroaryl Derivatives of Group 13 Elements

(2008) Alexey Y. Timoshkin et al.   ORGANOMETALLICS

Controlled Polymerization of Methacrylates to High Molecular Weight Polymers Using Oxidatively Activated Group Transfer Polymerization Initiators

(2007) Yuetao Zhang et al.   MACROMOLECULES