Review
Chemistry, Multidisciplinary
Conghui Tang, Xu Qiu, Zengrui Cheng, Ning Jiao
Summary: Molecular oxygen, as a green and non-toxic oxidant, offers various advantages in organic transformations for the synthesis of oxygen-containing compounds. Recent advances in radical processes using molecular oxygen as an oxidant have been discussed, along with reaction scopes, limitations, and mechanisms, providing insights for future developments in this field.
CHEMICAL SOCIETY REVIEWS
(2021)
Article
Chemistry, Multidisciplinary
Mrinal Bhunia, Christian Sandoval-Pauker, Mehrafshan G. Jafari, Lauren N. Grant, Michael R. Gau, Balazs Pinter, Daniel J. Mindiola
Summary: A dinuclear hafnium complex with a parent imido ligand was synthesized by reduction reaction and exhibited short Hf-N bond lengths. DFT calculations revealed the formation mechanism of the complex and showcased its reactivity with various electrophiles.
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION
(2022)
Article
Multidisciplinary Sciences
Hoimin Jung, Jeonguk Kweon, Jong-Min Suh, Mi Hee Lim, Dongwook Kim, Sukbok Chang
Summary: To overcome the challenge of isolating and characterizing Rhodium (Rh) acylnitrene complexes, a chromophoric octahedral Rh complex with a bidentate dioxazolone ligand was designed. X-ray photocrystallographic analysis allowed structural elucidation of the Rh-acylnitrenoid and provided evidence that the singlet nitrenoid species is responsible for acylamino transfer reactions. In-crystallo reaction of a nucleophile with the in-situ-generated Rh-acylnitrenoid provided a traceable reaction system to capture mechanistic snapshots of nitrenoid transfer.
Article
Chemistry, Multidisciplinary
Alexander Reckziegel, Manjinder Kour, Beatrice Battistella, Stefan Mebs, Katrin Beuthert, Robert Berger, C. Gunnar Werncke
Summary: In this study, a variety of trigonal imido cobalt complexes were synthesized with very long Co-N-Aryl bonds. Their electronic structure was investigated using physical and spectroscopic methods, leading to the description of highly unusual imidyl cobalt complexes. Computational analyses supported these findings and revealed the role of the high-spin state in the imidyl character.
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION
(2021)
Article
Chemistry, Physical
Tyler G. Saint-Denis, Nelson Y. S. Lam, Nikita Chekshin, Paul F. Richardson, Jason S. Chen, Jeff Elleraas, Kevin D. Hesp, Daniel C. Schmitt, Yajing Lian, Chan Woo Huh, Jin-Quan Yu
Summary: Enantioselective C(sp(3))-H activation has attracted significant interest, but the mechanisms responsible for enantioselection remain unclear. This study found extreme sensitivity differences in two substrate classes, leading to high enantiomeric ratios for thioether-directed-C(sp(3))-H arylation. The exploitation of transient chirality at sulfur was key to achieving stereochemical information transfer from ligand backbone to substrate carbons.
Article
Chemistry, Organic
Qinxuan Wang, Jiun-Le Shih, Ka Yi Tsui, Croix J. Laconsay, Dean J. Tantillo, Jeremy A. May
Summary: This study investigated various types of Huisgen cyclization or nitrene/carbene alkyne cascade reactions with different types of termination. Accessible nitrene precursors were evaluated, and carbonazidates were found to be the only effective initiators. The reaction outcome can be influenced by solvents, terminal alkynyl substituents, and catalysts. The mechanism was studied both computationally (using density functional theory) and experimentally, revealing relevant intermediates and plausible reaction pathways.
JOURNAL OF ORGANIC CHEMISTRY
(2022)
Article
Chemistry, Multidisciplinary
Tongyu Li, Dongwei Wang, Yi Heng, Guohua Hou, Guofu Zi, Wanjian Ding, Marc D. D. Walter
Summary: Terminal uranium oxido, sulfido, and selenido metallocenes were synthesized and their reactivity was studied. A cycloaddition-elimination methodology was used to prepare the metallocenes employing a useful precursor. The metallocenes showed different reactivities towards alkynes and isothiocyanates, and the results were supported by DFT computations.
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
(2023)
Review
Chemistry, Multidisciplinary
Anna Roglans, Anna Pla-Quintana, Miquel Sola
Summary: The review in this article covers the mechanistic aspects of the transition-metal-catalyzed [2 + 2 + 2] cycloaddition reaction involving various unsaturated substrates with metals such as Co, Ni, Ru, Rh, Ir, Pd, etc. It provides an overview from the early studies to the present day, focusing on the key mechanistic aspects that influence reactivity and selectivity, comparing different unsaturated substrates and transition metals used.
Article
Chemistry, Multidisciplinary
Chaosheng Luo, Juan V. Alegre-Requena, Stephen J. Sujansky, Spencer P. Pajk, Liliana C. Gallegos, Robert S. Paton, Jeffrey S. Bandar
Summary: This study investigates the mechanism of nucleophilic addition of alcohols to simple alkenes, revealing the influence of alcohol stoichiometry on reaction rate and proposing a new solution. The improved method does not require excess alcohol, expands the substrate scope, and utilizes more practical catalyst systems.
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
(2022)
Article
Chemistry, Multidisciplinary
Ethan Zars, Lisa Pick, Abinash Swain, Mrinal Bhunia, Patrick J. Carroll, Dominik Munz, Karsten Meyer, Daniel J. Mindiola
Summary: In this study, a base metal complex was used as a catalyst for the intermolecular amination reaction of Csp3-H bonds. The reaction exhibited high selectivity and good substrate tolerance.
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION
(2023)
Editorial Material
Chemistry, Multidisciplinary
Dipankar Sahoo, Diana A. Iovan
Summary: A recent study reported the isolation and characterization of an N-trifluoromethyl-substituted Fe(IV) bisimido species that undergoes intramolecular C-H activation. This discovery opens up new possibilities for N-group-transfer chemistry.
Article
Chemistry, Inorganic & Nuclear
Alfredo Pereira, Camilo Albornoz, Oleksandra S. Trofymchuk
Summary: This study presents a data-driven approach to analyze reactions catalyzed using [Cp*Co(CO)I-2]. By analyzing different parameters, the screening process in the laboratory is accelerated to yield favorable combinations. The research also demonstrates the effects of reaction conditions and directing groups on the reaction performance.
Article
Chemistry, Organic
Yuan Zhang, Lan-Yu Li, Cheng Hou
Summary: Homogeneous organometallic catalysts based on ancillary ligands have important applications in organic synthesis. In recent years, the introduction of multiple functional sites into the ancillary ligand represents a new direction for metal-ligand cooperation (MLC) catalyst design. A theoretical study is presented to illuminate the mechanistic preference in transfer hydrogenation of alkynes catalyzed by an MLC catalyst with multiple functional sites in the ancillary ligand.
ORGANIC CHEMISTRY FRONTIERS
(2023)
Article
Chemistry, Organic
Kelin Wang, Xia Song, Yongdi Xin, Xinying Zhang, Xuesen Fan
Summary: In this study, a condition-controlled selective synthesis of pyranone-tethered indazoles or carbazole derivatives was achieved via cascading reactions of N-nitrosoanilines with iodonium ylides. The formation mechanisms of the products were elucidated, and the developed protocols demonstrated easily controllable selectivity, mild reaction conditions, a clean and sustainable oxidant (air), and structurally diverse valuable products. Furthermore, the utility of the products was showcased by their facile and diverse transformations into synthetically and biologically interesting compounds.
Article
Chemistry, Inorganic & Nuclear
Deqiang Wang, Shichun Wang, Tongyu Li, Yi Heng, Guohua Hou, Guofu Zi, Marc D. Walter
Summary: A novel terminal uranium phosphinidene metallocene complex was isolated and its reactivity towards various heterounsaturated molecules was investigated, leading to the formation of carbodithioates, sulfidos, oxidos, metallaheterocycles, and imido complexes in good yields. Additionally, a pseudophosphinimido uranium(III) complex was obtained in good yield by reacting with a diazoalkane derivative. This study provides new insights into the synthesis and applications of organouranium complexes.
DALTON TRANSACTIONS
(2021)
Article
Crystallography
Benjamin F. Wicker, Rachel Seaman, Norris W. Hoffman, James H. Davis, Richard E. Sykora
ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE
(2011)
Article
Chemistry, Inorganic & Nuclear
Benjamin F. Wicker, Maren Pink, Daniel J. Mindiola
DALTON TRANSACTIONS
(2011)
Article
Chemistry, Inorganic & Nuclear
Falguni Basuli, Benjamin Wicker, John C. Huffman, Daniel J. Mindiola
JOURNAL OF ORGANOMETALLIC CHEMISTRY
(2011)
Article
Chemistry, Multidisciplinary
Benjamin F. Wicker, Jennifer Scott, Jose G. Andino, Xinfeng Gao, Hyunsoo Park, Maren Pink, Daniel J. Mindiola
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
(2010)
Article
Chemistry, Inorganic & Nuclear
Benjamin F. Wicker, Jennifer Scott, Alison R. Fout, Maren Pink, Daniel J. Mindiola
Article
Chemistry, Inorganic & Nuclear
Timothy A. Jackson, J. Krzystek, Andrew Ozarowski, Gayan B. Wijeratne, Benjamin F. Wicker, Daniel J. Mindiola, Joshua Telser
Correction
Chemistry, Inorganic & Nuclear
Timothy A. Jackson, J. Krzystek, Andrew Ozarowski, Gayan B. Wijeratne, Benjamin F. Wicker, Daniel J. Mindiola, Joshua Telser
Meeting Abstract
Chemistry, Multidisciplinary
Kaycee Gass, Yufei Wang, Richard Sykora, James Davis, Benjamin Wicker
ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY
(2016)
Meeting Abstract
Chemistry, Multidisciplinary
Benjamin Wicker, Kaycee Gass, Matthew St Lawrence, Yufei Wang, James Davis, Richard Sykora
ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY
(2016)
Meeting Abstract
Chemistry, Multidisciplinary
Matthew St Lawrence, Richard Sykora, Benjamin Wicker
ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY
(2016)
Meeting Abstract
Chemistry, Multidisciplinary
Joshua Telser, A. Skye Fortier, Alger Liang, Benjamin Wicker, Daniel J. Mindiola, Gayan Wijeratne, Timothy A. Jackson, J. Krzystek, Andrew Ozarowski
ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY
(2014)
Meeting Abstract
Chemistry, Multidisciplinary
RaeAnn D. Hirschy, Benjamin F. Wicker, Jennifer Scott, Daniel J. Mindiola
ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY
(2010)
Meeting Abstract
Chemistry, Multidisciplinary
Andrew Gordon Harris, Jason W. Clements, Benjamin F. Wicker, Jamie T. Wiggins, Jake LeBlanc, Norris W. Hoffman
ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY
(2008)
Meeting Abstract
Chemistry, Multidisciplinary
Jason W. Clements, Benjamin F. Wicker, Norris W. Hoffman
ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY
(2008)