4.7 Article

X-ray Absorption Spectroscopy Studies of the Room-Temperature Ferromagnetic Fe-Doped 6H-BaTiO3

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JOURNAL OF THE AMERICAN CERAMIC SOCIETY
卷 98, 期 4, 页码 1156-1161

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WILEY
DOI: 10.1111/jace.13408

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资金

  1. Slovenian Research Agency [P1-0112, P2-0377, PR-04988, N2-0005]
  2. DESY
  3. European Community [CALIPSO n_312284]
  4. HASYLAB [I-20110082 EC]
  5. ELETTRA [20110127]

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We investigated the effect of annealing temperature on magnetic properties of 2% and 10% Fe-doped BaTiO3. To understand the possible structural differences between samples treated at different annealing temperatures, and to correlate them with the magnetic properties, several characterization techniques, such as X-ray diffraction and X-ray absorption spectroscopic methods (XANES and EXAFS) were employed. We found that the 2% Fe-doped BaTiO3 pseudocubic perovskite is paramagnetic regardless of the heat-treatment conditions. Initially paramagnetic 10% Fe-doped 6H-BaTiO3, treated at 1250 degrees C, became ferromagnetic after additional annealing at higher temperature. We have crystalographically characterized the cation ordering processes in the 6H-BaTiO3 that occurred during the high-temperature annealing. The ferromagnetism that is induced in this stage is most probably associated with the observed diffusion processes but it extrinsic character still cannot be fully disregarded.

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