Article
Materials Science, Ceramics
Weibai Bian, Jiqiang Jia, Ruixuan Zhang
Summary: Pt/SrTiO3(STO)/LaNiO3(LNO) and Pt/STO/Pt structures were fabricated on Si substrates using sol-gel method. Dielectric tunability characteristics of these two structures are investigated over temperature range of 300-80 K. STO prepared on LNO exhibits better crystallinity and dielectric tunability than that prepared on Pt. Furthermore, LNO/STO/LNO structure exhibits similar tunability, lower tan delta, higher figure-of-merit (FOM) values, and better tunability symmetry compared with Pt/STO/LNO structure, demonstrating the better performance of LNO electrode than conventional inert metal electrodes.
CERAMICS INTERNATIONAL
(2023)
Article
Chemistry, Physical
Alina V. Semchenko, Vitaly V. Sidsky, Igor Bdikin, Vladimir E. Gaishun, Svitlana Kopyl, Dmitry L. Kovalenko, Oleg Pakhomov, Sergei A. Khakhomov, Andrei L. Kholkin
Summary: La doping and higher crystallization temperature result in increased grain size and preferred orientation, while decreasing effective piezoelectric coefficient and increasing non-polar phase surface area. La doping enhances grain size and self-polarization, important for future piezoelectric applications.
Article
Chemistry, Physical
Yanjiang Xie, Hua Hao, Juan Xie, Zichen He, Shuo Zhang, Zongxin Li, Minghe Cao, Zhonghua Yao, Hanxing Liu
Summary: By controlling the amount of SrTiO3 introduced into the BNT-BT thin films, the maximum polarization and dielectric properties of the films can be enhanced, leading to high energy-storage density and low dielectric loss under certain conditions.
JOURNAL OF ALLOYS AND COMPOUNDS
(2021)
Article
Materials Science, Ceramics
Chang-Chang Zhang, Jian-Qing Dai, Xia-Li Liang
Summary: The influence of (Zn, Ti) equivalent co-doping on the structure, surface morphology, and ferroelectric properties of BFZTO films was systematically investigated. Co-doping resulted in structural transformations, improved film density and uniformity, reduced oxygen vacancy concentration, and enhanced dielectric and magnetic properties. Additionally, the co-doped BiFe0.96Zn0.02Ti0.02O3 film exhibited the lowest leakage current density, highest remnant polarization, and stable overall performance.
CERAMICS INTERNATIONAL
(2021)
Article
Chemistry, Physical
Boying Wang, Hao Wang, Jiantao Wang, Chaolong Li, Feng Wang, Chunli Diao, Haiwu Zheng
Summary: In this study, lead-free 0.8STO-0.2BFO thin films with coexisting amorphous and nanocrystalline structure were prepared by a sol-gel method. By adjusting the heat-treatment temperature to form polar-nano regions, the energy storage density of the films was increased. The optimized 0.8STO-0.2BFO film exhibited excellent energy storage properties with high discharge energy storage density, temperature and frequency stability, as well as fatigue endurance.
JOURNAL OF ALLOYS AND COMPOUNDS
(2023)
Article
Chemistry, Multidisciplinary
V. Dolezal, V. Jakes, J. Petrasek, P. Ctibor, O. Jankovsky, K. Rubesova, D. Sedmidubsky
Summary: The perovskite-type phase CaCu3Ti4O12 has promising dielectric properties, but the phenomenon of giant permittivity in this material has not been fully explained. In this study, Europium with similar electronegativity and ionic radius as Calcium was tested as a partial or complete substitute. A series of materials, including CaCu3Ti4O12, Eu0.4Ca0.6Cu3Ti4O12, and EuCu3Ti4O12, were prepared using a sol-gel method and sintering. The influence of microstructure and phase composition on the dielectric properties of the samples, as well as the effect of sintering temperature, was investigated. Secondary phases and microstructure were found to play a significant role in improving the permittivity values, which were found to be giant at higher frequencies but significantly different for specific compositions.
JOURNAL OF PHYSICS AND CHEMISTRY OF SOLIDS
(2023)
Article
Materials Science, Multidisciplinary
M. Arifuzzaman, M. B. Hossen, Md. Harun-Or-Rashid, M. L. Rahman
Summary: A series of nanocrystalline Ni0.7-xCuxCd0.3Fe2O4 materials were synthesized through an auto-combusted Sol-gel approach and annealed at 700 degrees C. The materials exhibited cubic spinel phase with increasing Cu content resulting in larger crystallite size, particle size, lattice constant, and unit cell volume. Magnetic characterizations showed a decrease in saturation magnetization and experimental magnetic moment with Cu substitution up to 20%, followed by an increase with further Cu content.
MATERIALS CHARACTERIZATION
(2021)
Article
Materials Science, Ceramics
S. Chahib, G. Leroy, B. Duponchel, C. Poupin, H. Ez-zahraouy, D. Fasquelle
Summary: This study compares the dielectric properties of BaSnO3 ceramics and thin films in terms of structure, morphology, frequency (20 Hz-1 MHz), and temperature (30℃-300℃). BaSnO3 solution was prepared using the sol-gel method, and thin films were deposited by spin-coating on substrates. Both ceramics and films showed a pure BaSnO3 phase with a cubic structure according to the X-ray diffraction spectra. The sintering temperature was adjusted to improve the crystalline quality of the ceramics. SEM photos confirmed the high quality of the film surface, with an average roughness of 1.8 nm measured by AFM. The dielectric constant (epsilon') at room temperature was found to be around 17 for ceramics and 13 for thin films at 1 MHz. The dielectric properties of BaSnO3 ceramics could be successfully replicated on thin films using a cost-effective deposition method.
CERAMICS INTERNATIONAL
(2023)
Article
Chemistry, Physical
Marin Cernea, Roxana Radu, Harvey Amorin, Bogdan Stefan Vasile, Vasile Adrian Surdu, Roxana Trusca, Raluca Gavrila, Carmen Galassi
Summary: Motivated by the goal of developing ultralow power, smart and multifunctional nano (micro) electronic devices, research has shown unwavering interest in synthesis methods, architectures and interphase connectivity of composites containing magnetostrictive and piezoelectric phases, known as magnetoelectric (ME) materials. Herein we report on CoFe2O4/0.92Bi0.5Na0.5TiO3-0.08BaTiO3 biphasic ME composites, obtained by sol-gel chemistry, by mixing the precursor sols of the two phases into one precursor sol and further transforming it into gel, with the goal of obtaining homogeneous nanocomposites with magnetoelectric properties. The structural properties, the temperature dependance of dielectric properties, the magnetic and magnetoelectric properties of these biphasic mixtures, with various molar ratios CoFe2O4/ BNT-BT0.08 = 0.5:1, 1:1 and 1.5:1, are investigated. It is observed that the amount of CoFe2O4 and the synthesis in situ of these composites influences their macroscopic properties showing a high difficulty of carrying out an efficient poling resulting in small piezoelectric and magnetoelectric response. It was concluded that the synthesis procedure, the type of architecture and the interphase connectivity are of outmost importance for magnetoelectric properties based on lead-free materials. (c) 2023 Published by Elsevier B.V.
JOURNAL OF ALLOYS AND COMPOUNDS
(2023)
Article
Materials Science, Ceramics
Guo-Dong Zhang, Jian-Qing Dai, Xia-Li Liang
Summary: High-quality spin-coated Bi1-xLaxFeO3 films were produced using a sol-gel approach. The doping of La in the films resulted in structural alterations and improved ferroelectric properties. The incorporation of La3+ reduced Fe2+ and oxygen vacancies, leading to higher residual polarization and lower leakage current density.
JOURNAL OF SOL-GEL SCIENCE AND TECHNOLOGY
(2023)
Article
Materials Science, Multidisciplinary
Zhenchuan Lu, Kamale Tuokedaerhan, Haotian Cai, Hongguo Du, Renjia Zhang
Summary: This article introduces the sol-gel method for depositing La2O3 thin films on n-type Si substrates and quartz substrates, with a focus on the impact of annealing temperature on the microcomposition, surface morphology, optical properties, and band characteristics of the films. The results show that annealing leads to the formation of a hexagonal-phase La2O3 and new impurities. The La2O3 film exhibits a smooth, uniform surface without cracks, and its transmittance is above 75%. The calculated band offset of the La2O3 film meets the minimum requirements for MOS devices, indicating its promising prospects in MOS applications.
Article
Chemistry, Physical
Yong-Shen Lu, Jian-Qing Dai
Summary: Lead-free 0.7BiFe(1-2x)Zn(x)Mn(x)O(3)-0.3BaTiO(3) (BFZMx-BT) piezoceramics were prepared via sol-gel method and two-step sintering process. The addition of Zn and Mn ions significantly modified the microstructure, resulting in enhanced Curie temperature, dielectric properties, and polarization magnitude. The codoping of (Zn, Mn) in BF-BT induced improved performance in terms of remnant polarization, leakage current, Curie temperature, piezoelectric constant, strain response, and piezoelectric actuator constant.
JOURNAL OF ALLOYS AND COMPOUNDS
(2022)
Article
Chemistry, Physical
Yongtao Li, Liqing Liu, Dehao Wang, Hongguang Zhang, Xuemin He, Qi Li
Summary: In this study, the magnetic properties of BiFeO3 were investigated by doping Cu and (Cu, Zn). It was found that doping Zn can enhance the magnetism, while co-doping Cu and Zn has no impact on the local structure of Fe and Bi atoms. The results suggest that the modification of magnetism by doping Zn can be explained by the occupation site of non-magnetically active Zn2+.
Article
Physics, Multidisciplinary
V. S. Sharon, E. Veena Gopalan, K. A. Malini
Summary: Doped multiferroic (BFO) nanoparticles, Bi1-x Sr x FeO3 (x = 0, 0.3, 0.5, 0.7), were synthesized using a modified sol-gel auto-combustion process. The samples' structural, electrical, optical, and magnetic properties were discussed. Structural analysis showed a transition in structure from rhombohedral to cubic for Sr doping of x = 0.3. Scanning electron microscopy revealed the morphology of the prepared samples. Dielectric constant and ac conductivity were studied. The doped samples exhibited improved dielectric properties and can be used in optoelectronic devices. Dielectric dispersion and relaxation were observed in all samples. Cole-Cole plots were used to analyze dispersion parameters, and the bandgap was calculated using diffuse reflectance spectral analysis. The samples also showed strong photoluminescence in the infrared region. Magnetization studies indicated superparamagnetic behavior with improved magnetic properties due to doping.
Article
Physics, Applied
Haiwen Chen, Shengli Hu, Ge Zhang, Zhengming Jiang, JiaJun Mo, Min Liu
Summary: Multiferroic nanocrystalline Bi1-xSrxFeO3 samples were synthesized using the sol-gel method and characterized through various techniques. The increase of Sr content led to a phase transition and reduction of impurities. Substitution of Bi3+ by Sr2+ ions generated oxygen vacancy equilibrium valence state in the samples.
INTERNATIONAL JOURNAL OF MODERN PHYSICS B
(2021)
Article
Chemistry, Physical
Chia-Chuan Chen, Xiaoding Qi, Wei-Che Chang, Mu-Gong Tsai, In-Gann Chen, Cen-Ying Lin, Ping-Han Wu, Kuang-Po Chang
APPLIED SURFACE SCIENCE
(2015)
Article
Materials Science, Ceramics
Cheng-Chung Hsieh, Chii-Shyang Hwang, Chia-Hung Kuo, Xiao-ding Qi, Chun-Lung Hsiao
CERAMICS INTERNATIONAL
(2015)
Article
Materials Science, Ceramics
Yu-Ling Liang, Shih-Zong Lu, Hsin-Ying Lee, Xiaoding Qi, Jow-Lay Huang
CERAMICS INTERNATIONAL
(2015)
Article
Materials Science, Multidisciplinary
Chun-Lung Hsiao, Xiaoding Qi
Article
Materials Science, Multidisciplinary
Shih-Zong Lu, Xiaoding Qi
JOURNAL OF MATERIALS CHEMISTRY C
(2016)
Article
Chemistry, Physical
Shih-Zong Lu, Xiaoding Qi
JOURNAL OF ALLOYS AND COMPOUNDS
(2017)
Article
Chemistry, Physical
Yu-Jhan Siao, Xiaoding Qi
JOURNAL OF ALLOYS AND COMPOUNDS
(2017)
Article
Chemistry, Physical
Yen-Wen Lu, Xiaoding Qi
JOURNAL OF ALLOYS AND COMPOUNDS
(2019)
Article
Materials Science, Multidisciplinary
Chen-Yuan Guo, Xiaoding Qi
MATERIALS & DESIGN
(2019)
Article
Materials Science, Ceramics
Chi-Chimg Yeh, Jhe-Wei Li, Guo-Sen Tu, Xiaoding Qi
Summary: The sintered CFO-KNN composites showed higher relative density when the volume fraction of KNN reached 50% or more. The highest relative density of 94% was obtained with the composites of 80 vol% KNN. Transmission electron microscopy did not observe any secondary phase at the interface between CFO and KNN grains. However, elemental analyses showed traces of interdiffusion of ions within the solubility limit of both lattices without segregation of other phases.
INTERNATIONAL JOURNAL OF APPLIED CERAMIC TECHNOLOGY
(2022)
Article
Materials Science, Multidisciplinary
Yi-Ping Luo, Mei-Jing Huang, Xiaoding Qi
Summary: In this study, epitaxial films of BiCuSeO were successfully grown on SrTtO(3) substrates with different orientations using RF magnetron sputter deposition. The orientation and growth rate of the films exhibited different patterns at different temperatures.
Article
Materials Science, Ceramics
Chieh-Jui Chang, Xiaoding Qi
Summary: In this study, BFO-STO-xKNN ceramics were synthesized and their microstructure and properties were analyzed. The experimental results showed that adding an appropriate amount of KNN can change the grain size and lattice parameter of the material, and also have a significant impact on its dielectric response and conductivity. Among them, the x=0.01 KNN sample showed a high recoverable energy density and efficiency at an applied field of 273 kV/cm.
CERAMICS INTERNATIONAL
(2022)
Article
Chemistry, Physical
Tzu-Chiao Lin, Xiaoding Qi
Summary: The study investigated the mixed valences and oxygen vacancies in Eu1-xBaxTi1-yMyO3 materials, as well as the impact of Co2+/Ni2+ co-doping on the material properties. Sintered at 1400 degrees Celsius, the Co2+/Ni2+ co-doping in Eu1-xBaxTi1-yMyO3 materials can result in a transition from antiferromagnetic to ferromagnetic, possibly due to the asymmetric distortion of the Eu-O polyhedron.
Article
Materials Science, Multidisciplinary
Edmund H. H. Lim, Josephine Y. C. Liew, M. M. Awang Kechik, S. A. Halim, S. K. Chen, K. B. Tan, X. Qi
APPLIED PHYSICS A-MATERIALS SCIENCE & PROCESSING
(2017)
Correction
Materials Science, Ceramics
Shih-Zong Lu, Xiaoding Qi
JOURNAL OF THE AMERICAN CERAMIC SOCIETY
(2015)
Article
Materials Science, Ceramics
Zilong Xiong, Wenzhuo Xue, Mujun Li, Feihu Tan, Yupeng Chen, Hongyu Yu
Summary: In this study, CBS glass/Al2O3 composites were developed for LTCC applications based on a CaO-B2O3-SiO2 (CBS) glass system with a high boron content. The study revealed that the softening of glass and interfacial reaction between the glass and Al2O3 were the two most important factors affecting LTCC's densification process. Real-time shrinkage rate of LTCC during sintering was successfully simulated, and it was proven that the formation of the CaAl2(BO3)O phase played a significant role in reducing glass viscosity and promoting dense structure formation. The resulting LTCC composite exhibited excellent performance for high-frequency applications.
JOURNAL OF THE AMERICAN CERAMIC SOCIETY
(2024)
Article
Materials Science, Ceramics
Saurabh Kumar Sharma, Vinita Grover, Rakesh Shukla, Abid Hussain, Ambuj Mishra, Pawan Kumar Kulriya
Summary: In this study, the disordering caused by swift heavy ion irradiation in two different compositions of pyrochlore structures was investigated. X-ray diffraction, Raman spectroscopy, and high-resolution transmission electron microscopy were used to analyze the samples before and after irradiation. It was found that both compositions underwent amorphization due to irradiation, with a slower rate observed in Nd1.8Zr2.2O7.1. The irradiation-induced modified track region in Nd1.8Zr2.2O7.1 consisted of defect-rich pyrochlore structure, anion-deficient fluorite structure, and amorphous domains.
JOURNAL OF THE AMERICAN CERAMIC SOCIETY
(2024)
Article
Materials Science, Ceramics
Jiabei He, Mengshan Song, Ming Yang, Miaomiao Zhu
Summary: This study investigates the influence of ion irradiation on high-entropy ceramics and finds that irradiation-induced lattice rearrangement can improve the radiation resistance of these ceramics.
JOURNAL OF THE AMERICAN CERAMIC SOCIETY
(2024)
Article
Materials Science, Ceramics
Yajie Yu, Shi He, Zhengang Zhang, Haihua Chen, Peipeng Jin, Binnian Zhong, Linhui Zhang, Liping Wang, Cheng Lu
Summary: Silicide ceramics, including tantalum disilicide (TaSi2), are known for their exceptional physical properties but are limited in practical applications due to their inherent brittleness at room temperature. In this study, we successfully improved the mechanical properties of TaSi2 ceramics and increased their electrical conductivity by modifying the preparation methods and sintering conditions. These findings provide valuable insights for future applications of TaSi2 and the design of advanced ceramic materials.
JOURNAL OF THE AMERICAN CERAMIC SOCIETY
(2024)
Article
Materials Science, Ceramics
Jian Li, Jia Liu, Yongcui Zhang, Wei Sun, Yang Wang, Haitao Wu, Ling Li, Chuanbing Cheng, Yingying Wang, Ke Tan, Futian Liu
Summary: Microstructure design plays a crucial role in regulating the microwave dielectric properties of materials, however, the understanding of frequency temperature stability and related micromechanism remains limited. In this study, a combination of first-principles calculations and experimental observation was used to investigate the correlation among sintering behavior, crystal structure, bonding nature, and microwave dielectric properties of LnPO(4) (Ln = Eu, Pr) ceramics. The research findings systematically clarify the optimized effect and micromechanism of lanthanides on the dielectric properties of monazite ceramics, providing insights into the design and enhancement of microwave dielectric materials.
JOURNAL OF THE AMERICAN CERAMIC SOCIETY
(2024)
Article
Materials Science, Ceramics
Wenqian Pan, Xizhen Xia, Wei Zhou, Yang Li
Summary: The study investigates the frictional and wear behaviors of carbon fiber-reinforced SiC ceramic matrix composites with different fiber orientations mating with ceramic balls. The results show that fiber orientation significantly affects the friction and wear properties of the composites. Pads with randomly arranged fibers demonstrate better friction stability and lower wear volume, potentially suitable for bearing material applications. The research also explores the factors influencing the formation of continuous tribo-film and identifies abrasive wear and oxidation wear as the dominant wear mechanisms for the friction pairs.
JOURNAL OF THE AMERICAN CERAMIC SOCIETY
(2024)
Article
Materials Science, Ceramics
Sergey Nikolaevich Perevislov, Ilya Evgenievich Arlashkin, Valentina Leonidovna Stolyarova
Summary: This paper describes the synthesis and sintering of MAX phases in the Zr-Al-C system. Different mixtures of initial Zr/Al/C and Zr/Al/ZrC powders were used to synthesize Zr2AlC and Zr3AlC2 MAX phases. The highest content of Zr3AlC2 MAX phase was obtained using a component ratio of 1:1.5:2-51.1 vol.% of Zr/Al/ZrC powders.
JOURNAL OF THE AMERICAN CERAMIC SOCIETY
(2024)
Article
Materials Science, Ceramics
Weijia Luo, Xubin Wang, Baiheng Bai, Jianli Qiao, Xingcong Chen, Yongzheng Wen, Jingbo Sun, Lingxia Li, Ji Zhou
Summary: This study successfully establishes the relationship between internal strain and dielectric loss by synthesizing and designing specific structure of tungsten bronze ceramics, and concludes that controlling internal strain can effectively reduce dielectric loss. This research is of great significance for the development of future all-ceramic non-Hermitian devices.
JOURNAL OF THE AMERICAN CERAMIC SOCIETY
(2024)
Article
Materials Science, Ceramics
Santanu Mondal, Juan Diego Shiraishi Lombard, Sreenivasulu Gollapudi, Carolina Tallon, Jie-Fang Li, Dwight Viehland
Summary: Ultrafast high-temperature sintering (UHS) is an effective method for rapidly densifying ZrB2 powders. The final grain size increases with longer sintering duration. X-ray diffraction and energy-dispersive spectroscopy show crystalline phase and compositional uniformity in ZrB2 after UHS.
JOURNAL OF THE AMERICAN CERAMIC SOCIETY
(2024)
Article
Materials Science, Ceramics
JiaNan Wang, ZhiQiang Li, YongZheng Zhu, Yao Liang, Yan Cui, HuaLong Tao, Bo Song, Alexander Nikiforov, ZhiHua Zhang
Summary: First-principles calculations were performed to investigate the crystal structure, electronic structure, and ion diffusion of sulfur-doped Li2FeSiO4. The results showed that sulfur doping can improve the electronic conductivity and reduce the energy barrier for ion diffusion.
JOURNAL OF THE AMERICAN CERAMIC SOCIETY
(2024)
Article
Materials Science, Ceramics
Xiaodi Dai, Serdar Aydin, Mert Yuecel Yardimci, Gunter Reekmans, Peter Adriaensens, Geert De Schutter
Summary: This study investigates the rheological behavior, solidification process, and nanostructure changes of sodium hydroxide-activated slag (NH-AAS) and sodium silicate-activated slag (SS-AAS) pastes over time. The results show that NH-AAS and SS-AAS release similar heat and reach a similar reaction degree at their initial setting times, but have different gel structures.
JOURNAL OF THE AMERICAN CERAMIC SOCIETY
(2024)
Article
Materials Science, Ceramics
Yanliang Ji, Simon Becker, Zichen Lu, Alexander Mezhov, Regine von Klitzing, Schmidt Wolfram, Dietmar Stephan
Summary: This study reveals the significant influence of resting time on the rheological properties of cement suspensions, which is closely related to non-absorbed polycarboxylate superplasticizers (PCEs) size variation. Adsorbed PCE during resting tends to bridge particles instead of dispersing them, leading to an increased yield stress.
JOURNAL OF THE AMERICAN CERAMIC SOCIETY
(2024)
Article
Materials Science, Ceramics
Yifeng Huang, Xin Wang, Yinchang Ma, Xiang Lv, Jiagang Wu
Summary: This study investigates the effect of K/Na ratio on the phase structure, ferroelectric domains, and piezoelectric properties of potassium sodium niobate (KNN)-based ceramics. It reveals that high Na+ content leads to large ferroelectric domains, while high K+ content results in local polarity heterogeneity and distinct dielectric relaxational behavior. The balanced local polarity and stress heterogeneities contribute to improved piezoelectricity.
JOURNAL OF THE AMERICAN CERAMIC SOCIETY
(2024)
Article
Materials Science, Ceramics
Zun Xia, Yedong Rong, Hao Li, Ye Dong, Hongbo Yu, Jie Xu, Xiuhui Wang, Jinlong Yang
Summary: This study presents the synthesis of hollow MgAl2O4 particles in situ within porous ceramics, resulting in volume expansion and the formation of a hierarchical pore structure, leading to a significant improvement in compressive strength.
JOURNAL OF THE AMERICAN CERAMIC SOCIETY
(2024)
Article
Materials Science, Ceramics
Honglong Wang, Zhiguo Sun, Faming Xia, Chenguang Yang, Xiaoguang Wang, Jintang Li, Linxu Jiang
Summary: In this study, the micro-geometry morphology variation and microstructural transformation mechanism of muscovite crystals under electron beam irradiation were explored. The results revealed the instability of the muscovite lattice under irradiation, as well as the expansion and shrinkage of the lattice with increasing dose. The study also identified changes in chemical structure and other mechanisms involved. These findings are significant for the design of radiation-resistant silicate materials and the manufacturing of electronic components used in the aerospace industry.
JOURNAL OF THE AMERICAN CERAMIC SOCIETY
(2024)