期刊
JOURNAL OF THE AMERICAN CERAMIC SOCIETY
卷 97, 期 7, 页码 2177-2184出版社
WILEY
DOI: 10.1111/jace.12941
关键词
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资金
- NSFC [11174112, 51002065]
- Shandong Provincial Science Foundation [JQ201214]
- Ministry of Education, China [NCET-11-1027, 213021A]
- Taishan Scholar Professorship at University of Jinan [TSHW20091007]
Sodium-doped ZnO (ZnO:Na) nanowires were grown with a high-pressure pulsed-laser deposition process on silicon substrates using sputtered gold particles as catalysts. The introduction of sodium dopants into ZnO nanowires was confirmed by both X-ray diffraction spectrum and X-ray photoelectron spectroscopy. The morphology and microstructural changes in ZnO nanowires due to sodium doping were investigated with scanning electron microscope, high-resolution transmission electron microscope, and Raman spectrum. Detailed photoluminescence studies of ZnO: Na nanowires revealed characteristic sodium acceptor-related peaks, for example, neutral acceptor-bound exciton emission (A(0)X, 3.356 eV), free-to-neutral-acceptor emission (e, A(0), 3.314 eV), and donor-to-acceptor pair emission (DAP, 3.241 eV). This indicated that sodium doping induces stable acceptor level with a binding energy of 133 meV in ZnO:Na nanowires.
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