Article
Energy & Fuels
Melissa Bariani, Elzeario Boix, Francisco Cassella, Maria Noel Cabrera
Summary: Furfural production from rice husks via acid hydrolysis offers a valuable approach for generating high-value chemicals. Optimal conditions for production are shown to be 200 degrees C temperature, 0.10% sulphuric acid concentration, and 40 minutes reaction time. Additionally, the remaining solid material shows potential for power generation, enhancing the economic viability of the process.
BIOMASS CONVERSION AND BIOREFINERY
(2021)
Article
Agronomy
M. C. Barrero-Moreno, C. A. Diaz-Vargas, E. Restrepo-Parra
Summary: The use of rice husk in a laboratory-scale biofilter to remove heavy metals was studied. Langmuir isotherms showed the best correlation for Cd(II), Cu(II), and Cr(VI) removal, with a maximum operating temperature of 303.15 K and maximum removal efficiency at pH 9.0 for Cd(II) and Cu(II), and pH 3.0 for Cr(VI). Blockage times were found to be the longest at h=0.55 for Cd(II), and h=0.40 for both Cu(II) and Cr(VI).
Article
Environmental Sciences
Guangyin Chen, Hainan Cao, Yaling Tang, Keye Ni, Jing Wang, Pei Wu
Summary: To improve the biogas yield of rice straw, an innovative cascade utilization process named FSD was proposed, which involves first digestion, NaOH treatment, and second digestion. Lab-scale batch experiments were conducted to study the effect of first digestion time on biogas production and lignocellulose structure destruction. Results showed that the FSD-15 process yielded the highest biogas production and had significant effects on the composition and structure of rice straw. Therefore, FSD-15 is recommended for cascade utilization of rice straw in biogas production.
ENVIRONMENTAL SCIENCE AND POLLUTION RESEARCH
(2023)
Article
Environmental Sciences
Jing Wang, Dongmei Ma, Yu Lou, Jun Ma, Defeng Xing
Summary: Lignocellulosic biomass presents a promising feedstock for carbon management, offering carbon neutrality and substantial environmental and economic benefits. This paper explores recent advances in pretreatment methods for efficient biogas production from lignocellulosic biomass, providing a comprehensive overview of performance, benefits, and drawbacks. The utilization of physical-chemical pretreatment and nanomaterials-based techniques show potential in improving methane production and compensating for the limitations of natural enzymes. Economic effectiveness, environmental impact, and operational feasibility are also considered in the implementation of pretreatment processes. Techno-economic analysis, life cycle assessment, and artificial intelligence technologies are efficient means for evaluating and selecting pretreatment methods.
SCIENCE OF THE TOTAL ENVIRONMENT
(2023)
Article
Plant Sciences
Mario J. Rosado, Jorge Rencoret, Gisela Marques, Ana Gutierrez, Jose C. del Rio
Summary: Rice is a major cereal crop worldwide, and its by-products such as rice husks and straw contain lignins that can be used for producing chemicals and materials. Analysis showed that the lignins from rice husks and straw are enriched in guaiacyl units, but depleted in p-hydroxyphenyl and syringyl units.
FRONTIERS IN PLANT SCIENCE
(2021)
Article
Materials Science, Composites
Ramesh Kumar Madhappan, Senthilkumar Krishnasamy, Pasupathy Sangareddy Alagirisamy
Summary: This article introduces the importance of Thickness Swelling (TS) as a test for the hydration property of materials in the built environment, and proposes a prediction model to reduce development costs and time for building materials. By measuring and predicting the TS of rice straw-based MgO slabs, using FCC and REPTree algorithms as expert systems for prediction, it is shown that these models have an accuracy of 95% and 89% respectively.
JOURNAL OF THERMOPLASTIC COMPOSITE MATERIALS
(2021)
Article
Energy & Fuels
Taysnara Simioni, Caroline Borges Agustini, Aline Dettmer, Mariliz Gutterres
Summary: The combination of carbon and nitrogen-rich co-substrates improves the stability and balance of the anaerobic co-digestion process; the addition of untreated oat straw significantly increases biogas production in AcoD process. Different pretreatment techniques have varying effects on oat straw, with alkali treatment showing the most significant increase in cellulose content but also potential formation of toxic compounds.
BIOENERGY RESEARCH
(2022)
Article
Green & Sustainable Science & Technology
Karina Rodriguez Espejel, Jose de Jesus Perez Bueno, Coraquetzali Magdaleno Lopez, Maria Luisa Mendoza Lopez, Marcos Algara Siller, Jose Luis Reyes Araiza, Alejandro Manzano-Ramirez, Jorge Morales Hernandez
Summary: Geopolymer composites reinforced with agro-waste materials have attracted interest in engineering applications due to their easy processing, low cost, low density, and high strength-to-weight ratio. This study investigated the mechanical properties of composites made with a geopolymer matrix and agro-waste as aggregate material. The results showed that the addition of different agro-wastes influenced the performance of the geopolymer composites, and the microstructural analysis revealed good interaction between the husk and matrix. The waste-based compounds have the potential to replace natural wood in certain applications.
Article
Energy & Fuels
Tae Hoon Kim, Hyun Kwak, Tae Hyun Kim, Kyeong Keun Oh
Summary: The organosolv-fractionation process is suitable for separating main components such as lignin and hemicellulose from biomass, and can be applied for resource utilization of waste materials like rice husks. By adjusting reaction conditions, efficient extraction of different components can be achieved.
Article
Agricultural Engineering
Jyoti Rani, Abhishek S. Dhoble
Summary: In this study, the potential of two less explored fungal strains, Trichoderma longibrachiatum (TL) and Pycnoporus sanguineus (PS), in improving the hydrolysis and bioavailability of rice straw in anaerobic digestion (AD) was evaluated. The fungal treatment of rice straw for 10 days by TL and PS increased biogas production and reduced soluble chemical oxygen demand (sCOD). The microbial communities in treated samples showed increased diversity, contributing to better process performance and enhanced resilience against pH fluctuations.
BIORESOURCE TECHNOLOGY
(2023)
Article
Polymer Science
Huicheng Xu, Mengyuan Dun, Zhengqi Zhang, Lei Zhang, Weidong Shan, Weihong Wang
Summary: A new method of preparing straw-reinforced LLDPE composites using waste plastic film and straw was developed to reduce pollution. The new method improved the physical and mechanical properties of the composites, and the combination of straw and LLDPE formed a dense composite material with excellent interfacial bonding.
Article
Thermodynamics
Neeraj Kumar Singh, Rajesh Singh
Summary: The study explores the potential of sulfate-reducing bacteria (SRB) rich in hydrogenase enzyme activity for hydrogen production and examines the effects of different metal co-factors concentrations on hydrogen production efficiency. The results show that Fe2+ and Se4+ ions play a crucial role in hydrogenase expression in SRB, while the impact of Ni2+ ions on hydrogenase expression is minor. A higher Acetate/Butyrate ratio is favorable for increased hydrogen production. The application of potential further enhances hydrogen production.
Article
Agricultural Engineering
Hao Ren, Fangfang Wu, Hanxun Ju, Di Wu, Zimin Wei
Summary: This study explores the effect of adding the surfactant rhamnolipids and fungi inoculation on the formation of humic substances during composting of rice straw. The results show that rhamnolipids accelerate the degradation of organic matter and the formation of humic substances. Key fungal species and modules were identified using statistical analysis. This study provides a theoretical basis for the high-quality transformation of agricultural wastes.
BIORESOURCE TECHNOLOGY
(2023)
Article
Materials Science, Multidisciplinary
Liangpeng Jiang, Peng Du, Hao Wang
Summary: Seawater modification of lignocellulosic fibers can improve their physicochemical and thermal properties, including increasing surface roughness, crystallinity, and pyrolysis temperature, while decreasing silicon, hemicellulose, and lignin content. This modification also enhances the fiber-polymer compatibility.
MATERIALS RESEARCH EXPRESS
(2021)
Article
Energy & Fuels
Yiming Sun, Shan Tong, Xian Li, Zhenzhong Hu, Mingyue Sun, Li Guo, Huan Liu, Hongyun Hu, Guangqian Luo, Hong Yao
Summary: The study found that the partial pressure of volatiles is the root cause of accelerating biomass decomposition and deoxygenation in gas-pressurized torrefaction. It can be seen as a self-promoted deoxygenation process consisting of three stages. These findings have implications not only for gas-pressurized torrefaction, but also for pressurized pyrolysis and gasification of biomass.
Review
Automation & Control Systems
Tomy Muringayil Joseph, Anoop Kallingal, Akshay Maniyeri Suresh, Debarshi Kar Mahapatra, Mohamed S. Hasanin, Jozef Haponiuk, Sabu Thomas
Summary: Bio-based polymers are a class of polymers made by living organisms, with only a few known and commercialized so far. They have not been widely applied due to poor mechanical strength and economic constraints, but have become suitable candidates for biological applications. As consumers become more aware of the environmental impact of petrochemical polymers and the global transition away from long-lasting plastics, there is increasing interest in previously unattainable sectors. Bio-based polymers can be direct replacements or completely novel polymers, such as polylactide, with improved technical specifications. Polylactic acid (PLA) has gained recognition as a biodegradable thermoplastic for use in 3D printing, particularly in extrusion-based technologies. This review examines the chemical structure, manufacturing techniques, standard features, and market situation of PLA, focusing on its use in extrusion-based 3D printing with highlighted examples of 3D-printed PLA items.
INTERNATIONAL JOURNAL OF ADVANCED MANUFACTURING TECHNOLOGY
(2023)
Article
Biotechnology & Applied Microbiology
Mohamed S. Hasanin, Mohamed Abdelraof, Amr H. Hashem, Houssni El Saied
Summary: Newly BC producing bacteria were successfully isolated from acidic fruits, with the most potent producer identified as Achromobacter S3. Mango peel waste (MPW) hydrolysate was found to be a significant alternative medium for BC production, with the yield increased from 0.52 g/L to 1.22 g/L. The physicochemical analysis showed that BC produced by Achromobacter S33 on HS and MPW media had crystallinity of 72% and 79% respectively, and the topographical study revealed nanofibers with a diameter of approximately 10 nm and a length of 200 nm.
MICROBIAL CELL FACTORIES
(2023)
Review
Chemistry, Multidisciplinary
Tomy Muringayil Joseph, Debarshi Kar Mahapatra, Amin Esmaeili, Lukasz Piszczyk, Mohamed S. Hasanin, Mashhoor Kattali, Jozef Haponiuk, Sabu Thomas
Summary: The nature of human curiosity, wonder, and ingenuity has existed since ancient times. Alongside the development of human civilization, there has been a growing interest in the scientific understanding of natural phenomena. In recent years, there has been significant progress in the use of nanotechnology in medicine and drug delivery. Nanomaterials have emerged as essential tools in modern medicine, with applications ranging from imaging to tumor-targeted drug delivery. However, the use of nanoparticles also presents environmental and societal challenges, particularly regarding toxicity. This review highlights the contributions of nanoparticles to medicine and pharmaceuticals and discusses the future impact of nanotechnology in these fields.
Review
Pharmacology & Pharmacy
Ugo D'Amora, Sawsan Dacrory, Mohamed Sayed Hasanin, Angela Longo, Alessandra Soriente, Samir Kamel, Maria Grazia Raucci, Luigi Ambrosio, Stefania Scialla
Summary: Graphene oxide (GO) and its reduced form (rGO) have attracted significant interest in the field of biomedical applications, particularly in wound healing, due to their unique physico-chemical properties. The large surface area and functional groups of GO and rGO enable their easy dispersion within various polymeric matrices, resulting in the development of advanced hybrid nanocomposites with tailored properties. These nanocomposites have demonstrated efficient antimicrobial and angiogenic properties, making them advantageous for wound care management. This review discusses the relationship between the structural and physico-chemical properties of GO or rGO/cellulose nanocomposites and their effects on antimicrobial and angiogenic mechanisms in wound healing.
Article
Energy & Fuels
Altaf H. Basta, Vivian F. Lotfy
Summary: Criteria for minimizing and upgrading agricultural biomass are crucial for environmental and health preservation. This study aimed to utilize rice straw, an undesirable agricultural waste, to prepare effective nanogels for controlled drug release. Different pulping processes were optimized to produce nanocellulose, which was then combined with chitosan and demonstrated the formation of nanogels through ionic interaction. The safety and performance of these gels were evaluated, and the sulphatic and organosolv pulping processes were recommended for achieving maximum drug release.
BIOMASS CONVERSION AND BIOREFINERY
(2023)
Article
Microbiology
Amr H. Hashem, Abdulaziz A. Al-Askar, Jozef Haponiuk, Kamel A. Abd-Elsalam, Mohamed S. Hasanin
Summary: In this study, trimetallic copper-selenium-zinc oxide nanoparticles (Tri-CSZ NPs) were successfully mycosynthesized using Aspergillus niger for the first time. The physiochemical and topographical analysis confirmed the biosynthesis of Tri-CSZ NPs and their promising antifungal activity against mucormycosis-causing fungi.
Article
Multidisciplinary Sciences
Mohamed S. Hasanin, Mona Nassar, Youssef R. Hassan, Lukasz Piszczyk, Mohammad Reza Saeb, Agata Kot-Wasik
Summary: Fluorescence is an efficient anti-counterfeiting technique, and zinc oxide quantum dots (ZnOQds) possess strong fluorescence under ultraviolet (UV) light, making them suitable for anti-counterfeiting printing. In this study, ZnOQds were prepared using a green method and characterized by various techniques. The resulting ZnOQds nanocrystals showed stability and resistance against organic dyes. Furthermore, hybrid sheets made with ZnOQds demonstrated greater mechanical stability, long-term stability, and antimicrobial activity.
Article
Materials Science, Paper & Wood
Altaf H. Basta, Vivian F. Lotfy
Summary: This work demonstrates the potential of cellulose-based nanoparticles mixed with palm extract to produce nanogels for prolonged drug release. The nanogels showed sustained release behavior and outperformed other drug carriers reported in the literature.
Article
Green & Sustainable Science & Technology
Altaf H. Basta, Vivian F. Lotfy
Summary: The objective of this study was to use pulping by-product (black liquors) as an effective component in preparing high surface area carbon nanostructure adsorbents. The results showed that the adsorption capacities of the carbon nanostructures from black liquor-based aerogels were higher than those without black liquors. Different pulping reagents and dyes had different effects on the adsorption capacities. The black liquor from pulping with alkaline reagents provided the highest adsorption capacity for methylene blue, while the sulfite reagent provided the highest adsorption capacity for brilliant blue.
JOURNAL OF CLEANER PRODUCTION
(2023)
Review
Food Science & Technology
Mohamed S. Hasanin, Housni El Saied, Samir Kamel
Summary: Biopolymers have gained significant interest for sustainable and biodegradable solutions, reducing the reliance on petroleum-based resources and carbon dioxide emissions. Polysaccharides, a unique class of biopolymers, exhibit biocompatibility and editability. Functionalizing polysaccharides plays a crucial role in various applications, such as biosensors for medical diagnosis, although these sensors have limitations in durability, moldability, and sensitivity.
Article
Multidisciplinary Sciences
Emad S. Shafik, Vivian F. Lotfy, Altaf H. Basta
Summary: This study evaluates the utilization of polyester wastes in enhancing the production of polymers in rice straw polyol composites. The data shows the positive role of the polyester waste in production, providing increased thermal stability and mechanical properties.
SCIENTIFIC REPORTS
(2023)
Article
Polymer Science
Ayed S. Allogmani, Roushdy M. Mohamed, Mohamed S. Hasanin
Summary: This study examined the preparation of biomaterial-based multifunctional biopolymers via an eco-friendly formulation method using ultrasound. The formulated nanocomposite showed a thermally stable nanostructure and demonstrated excellent cytocompatibility, antimicrobial activity, and antioxidant activity.
Article
Chemistry, Multidisciplinary
Amr H. Hashem, Abdulaziz A. Al-Askar, Mohammad Reza Saeb, Kamel A. Abd-Elsalam, Ahmad S. El-Hawary, Mohamed S. Hasanin
Summary: This study successfully biosynthesized sustainable bimetallic ZnO@SeO nanoparticles using pomegranate peel extract, showing antibacterial, antifungal, and anticancer activities. These nanoparticles exhibited efficient inhibitory effects on various pathogens and cancer cells, indicating their potential applications in biomedical engineering.
Article
Nanoscience & Nanotechnology
Reda M. Abdelhameed, Mohamed S. Hasanin, Amr H. Hashem
Summary: In this study, a novel composite material based on carboxymethyl cellulose (CMC) and sulfur-functionalized titanium-based metal-organic framework (MOF) was synthesized. The composite showed antimicrobial, antiviral, and anticancer activities.
Article
Plant Sciences
Hamada R. Beheiry, Mohamed S. Hasanin, Amr Abdelkhalek, Hamdy A. Z. Hussein
Summary: This study aims to investigate the effects of preharvest spraying with potassium and postharvest dipping in edible coatings on the quality and storability of acid lime fruits. The results showed that the combination treatment of preharvest spraying with potassium tartrate and postharvest dipping in nanocoating improved the fruit quality of acid lime.