4.6 Article

Observation of the Binary Coalescence and Equilibration of Micrometer-Sized Droplets of Aqueous Aerosol in a Single-Beam Gradient-Force Optical Trap

期刊

JOURNAL OF PHYSICAL CHEMISTRY A
卷 116, 期 35, 页码 8873-8884

出版社

AMER CHEMICAL SOC
DOI: 10.1021/jp304929t

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资金

  1. EPSRC
  2. Schlumberger Faculty for the Future program
  3. government of Saudi Arabia
  4. King Abdulaziz University
  5. Engineering and Physical Sciences Research Council [EP/G007713/1] Funding Source: researchfish
  6. EPSRC [EP/G007713/1] Funding Source: UKRI

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The binary coalescence of aqueous droplets has been observed in a single-beam gradient-force optical trap. By measuring the time-dependent intensity for elastic scattering of light from the trapping laser, the dynamics of binary coalescence have been examined and the time scale for equilibration of a composite droplet to ambient conditions has been determined. These data are required for modeling the agglomeration of aqueous droplets in dense sprays and atmospheric aerosol. Elastic-light scattering from optically trapped particles has not been used previously to study the time-resolved dynamics of mixing. It is shown to offer a unique opportunity to characterize the binary coalescence of aqueous droplets with radii from 1 to 6 mu m. The study of this size regime, which cannot be achieved by conventional imaging methods, is critical for understanding the interactions of droplets in the environment of dense sprays.

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