期刊
JOURNAL OF PHYSICAL CHEMISTRY A
卷 116, 期 30, 页码 7992-8000出版社
AMER CHEMICAL SOC
DOI: 10.1021/jp300942n
关键词
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The directionality of inter- and intramolecular OHO hydrogen bonds has been compared. For intramolecular bridges it is determined by an orbital formed in the proton transfer process. For intermolecular bonds, the hydrogen-bonded proton is attached to two lone pairs of the acceptor and the OHO angle is not fixed but can change in a broad range. Depending on the OHO angle, the interaction changes continuously from electrostatic interaction to strong OHO hydrogen bond.
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