期刊
JOURNAL OF PHYSICAL CHEMISTRY A
卷 115, 期 33, 页码 9188-9191出版社
AMER CHEMICAL SOC
DOI: 10.1021/jp205011v
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资金
- Research Grants Council of Hong Kong [CityU 102609]
- National Natural Foundation of China [11074315]
- DFG [436 RUS 113/437/0-3]
- RFBR [10-02-91167-NNSF, 10-03-90305]
- European Community [FP7/2007-2013, 226716]
The low-temperature absorption and excitation spectra of interconfigurational 4f-5d transitions of Tb3+ in a cubic fluoride host demonstrate the appearance of a first-order linear Jahn-Teller effect for the high-spin excited states of the excited electronic configuration 4f(7)5d involving 5d t(2g) orbitals. The tau(2g) mode is observed to be responsible for the splitting of the otherwise degenerate 5d t(2g) orbitals.
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