Asymmetric metal free β-boration of α,β-unsaturated imines assisted by (S)-MeBoPhoz

A Clear-Cut Example of Selective BpinBdan Activation and Precise Bdan Transfer on Boron Conjugate Addition

(2014) Jessica Cid et al.   CHEMISTRY-A EUROPEAN JOURNAL

Trans-Diborylation of Alkynes: Pseudo-Intramolecular Strategy Utilizing a Propargylic Alcohol Unit

(2014) Yuki Nagashima et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Hydroxyl-Directed Stereoselective Diboration of Alkenes

(2014) Thomas P. Blaisdell et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Total synthesis of fluoxetine and duloxetine through an in situ imine formation/borylation/transimination and reduction approach

(2014) Adam D. J. Calow et al.   ORGANIC & BIOMOLECULAR CHEMISTRY

Base-Free β-Boration of α,β-Unsaturated Imines Catalysed by Cu2O with Concurrent Enhancement of Asymmetric Induction

(2013) Adam D. J. Calow et al.   ChemCatChem

Synthesis of a bicyclic diborane by selective boron carbon bond formation

(2013) Holger Braunschweig et al.   CHEMICAL COMMUNICATIONS

On the structural diversity of [K(18-crown-6)EPh3] complexes (E = C, Si, Ge, Sn, Pb): synthesis, crystal structures and NOESY NMR study

(2013) Christian Kleeberg   DALTON TRANSACTIONS

Quaternizing Diboranes(4): Highly Divergent Outcomes and an Inorganic Wagner–Meerwein Rearrangement

(2013) Holger Braunschweig et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

A Selective Transformation of Enals into Chiral γ-Amino Alcohols

(2013) Adam D. J. Calow et al.   ORGANIC LETTERS

Phosphine Adducts of 1,2-Dibromo-1,2-dimesityldiborane(4): Between Bridging Halides and Rearrangement Processes

(2012) Holger Braunschweig et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Novel transformation of α,β-unsaturated aldehydes and ketones into γ-amino alcohols or 1,3-oxazines via a 4 or 5 step, one-pot sequence

(2012) Adam D. J. Calow et al.   CHEMICAL COMMUNICATIONS

Asymmetric synthesis of α-amino boronate esters via organocatalytic pinacolboryl addition to tosylaldimines

(2012) Cristina Solé et al.   CHEMICAL COMMUNICATIONS

One-Pot Three-Component Highly Selective Synthesis of Homoallylboronates by Using Metal-Free Catalysis

(2012) Ismail Ibrahem et al.   CHEMISTRY-A EUROPEAN JOURNAL

Metal-Free Catalytic Enantioselective C–B Bond Formation: (Pinacolato)boron Conjugate Additions to α,β-Unsaturated Ketones, Esters, Weinreb Amides, and Aldehydes Promoted by Chiral N-Heterocyclic Carbenes

(2012) Hao Wu et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Asymmetric organocatalytic diboration of alkenes

(2012) Amadeu Bonet et al.   ORGANIC & BIOMOLECULAR CHEMISTRY

Catalytic methodologies for the β-boration of conjugated electron deficient alkenes

(2012) Adam D. J. Calow et al.   ORGANIC & BIOMOLECULAR CHEMISTRY

Essential role of phosphines in organocatalytic β-boration reaction

(2012) Cristina Pubill-Ulldemolins et al.   ORGANIC & BIOMOLECULAR CHEMISTRY

Highly Enantio- and Diastereoselective Synthesis of γ-Amino Alcohols from α,β-Unsaturated Imines through a One-Pot β-Boration/Reduction/Oxidation Sequence

(2011) Cristina Solé et al.   ADVANCED SYNTHESIS & CATALYSIS

Transition-Metal-Free Diboration Reaction by Activation of Diboron Compounds with Simple Lewis Bases

(2011) Amadeu Bonet et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Enantioselective formal hydration of α,β-unsaturated acceptors: asymmetric conjugate addition of silicon and boron nucleophiles

(2011) Eduard Hartmann et al.   CHEMICAL COMMUNICATIONS

Catalytic 1,3-Difunctionalisation of Organic Backbones through a Highly Stereoselective, One-Pot, Boron Conjugate-Addition/Reduction/Oxidation Process

(2011) Cristina Solé et al.   CHEMISTRY-A EUROPEAN JOURNAL

Activation of Diboron Reagents with Brønsted Bases and Alcohols: An Experimental and Theoretical Perspective of the Organocatalytic Boron Conjugate Addition Reaction

(2011) Cristina Pubill-Ulldemolins  et al.   CHEMISTRY-A EUROPEAN JOURNAL

Organocatalytic versus Iron-Assisted β-Boration of Electron-Deficient Olefins

(2011) Amadeu Bonet et al.   Chemistry-An Asian Journal

Spectroscopic and Structural Characterization of the CyNHC Adduct of B2pin2 in Solution and in the Solid State

(2011) Christian Kleeberg et al.   JOURNAL OF ORGANIC CHEMISTRY

Metal-Free Catalytic Boration at the β-Position of α,β-Unsaturated Compounds: A Challenging Asymmetric Induction

(2010) Amadeu Bonet et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Enantioselective Conjugate Borylation

(2010) Julia A. Schiffner et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Copper-Catalyzed Asymmetric β-Boration of α,β-Unsaturated Carbonyl Derivatives

(2010) Luca Mantilli et al.   ChemCatChem

A Facile Route to Aryl Boronates: Room-Temperature, Copper-Catalyzed Borylation of Aryl Halides with Alkoxy Diboron Reagents

(2009) Christian Kleeberg et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Boryl ligands and their roles in metal-catalysed borylation reactions

(2009) Li Dang et al.   CHEMICAL COMMUNICATIONS

Copper-Catalyzed Enantioselective β-Boration of Acyclic Enones

(2009) Hak-Suk Sim et al.   CHEMISTRY-A EUROPEAN JOURNAL

Asymmetric induction on β-boration of α,β-unsaturated compounds: an inexpensive approach

(2009) Vanesa Lillo et al.   DALTON TRANSACTIONS

Efficient C−B Bond Formation Promoted by N-Heterocyclic Carbenes: Synthesis of Tertiary and Quaternary B-Substituted Carbons through Metal-Free Catalytic Boron Conjugate Additions to Cyclic and Acyclic α,β-Unsaturated Carbonyls

(2009) Kang-sang Lee et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Catalytic Asymmetric Boration of Acyclic α,β-Unsaturated Esters and Nitriles

(2007) Ji-Eon Lee et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION