☆ 4.6 Article

Metal-catalyzed formation of 1,3-cyclohexadienes: a catalyst-dependent reaction

ORGANIC & BIOMOLECULAR CHEMISTRY (2015)

期刊

ORGANIC & BIOMOLECULAR CHEMISTRY

卷 13, 期 4, 页码 1225-1233

出版社

ROYAL SOC CHEMISTRY

DOI: 10.1039/c4ob01922a

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Chemistry, Organic

资金

National Basic Research Program of China (973) [2011CB808600]
NNSFC [21172077, 21372086, 21422204]
Guangdong NSF [10351064101000000]
SRF for ROCS, State Education Ministry
Fundamental Research Funds for the Central Universities (SCUT)

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摘要

A metal-dependent and complementary catalytic method to synthesize the cyclohexadienes has been developed. When gold or indium salts were used as catalysts, 1,3-cyclohexadiene (1,3-CHD) could be obtained; when Cu(OTf)(2) was used as the catalyst, however, another isomer 2,4-cyclohexadiene (2,4-CHD) was furnished instead.

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