Metal-free methylation of a pyridine N-oxide C–H bond by using peroxides

Regioselective oxidative Pd-catalysed coupling of alkylboronic acids with pyridin-2-yl-substituted heterocycles

(2015) Julian Wippich et al.   CHEMICAL COMMUNICATIONS

Copper-Catalyzed Radical Methylation/C–H Amination/Oxidation Cascade for the Synthesis of Quinazolinones

(2015) Yajie Bao et al.   JOURNAL OF ORGANIC CHEMISTRY

Pd-Catalyzed Direct C–H Bond Sulfonylation of Azobenzenes with Arylsulfonyl Chlorides

(2015) Duo Zhang et al.   JOURNAL OF ORGANIC CHEMISTRY

Palladium-Catalyzed Oxirane-Opening Reaction with Arenes via C–H Bond Activation

(2015) Zhen Wang et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Single-Electron Transmetalation: An Enabling Technology for Secondary Alkylboron Cross-Coupling

(2015) David N. Primer et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Alcohols as alkylating agents in heteroarene C–H functionalization

(2015) Jian Jin et al.   NATURE

Ligand-enabled meta-C–H activation using a transient mediator

(2015) Xiao-Chen Wang et al.   NATURE

Nickel-catalyzed synthesis of diarylsulfides and sulfones via C–H bond functionalization of arylamides

(2015) Vutukuri Prakash Reddy et al.   ORGANIC & BIOMOLECULAR CHEMISTRY

Remote Stereoinduction in the Organocuprate-Mediated Allylic Alkylation of Allylic gem-Dichlorides: Highly Diastereoselective Synthesis of (Z)-Chloroalkene Dipeptide Isosteres

(2015) Takuya Kobayakawa et al.   ORGANIC LETTERS

Rh(III)-Catalyzed C–H Alkylation of Arenes Using Alkylboron Reagents

(2015) He Wang et al.   ORGANIC LETTERS

Easy Access to Amides through Aldehydic C–H Bond Functionalization Catalyzed by Heterogeneous Co-Based Catalysts

(2015) Cuihua Bai et al.   ACS Catalysis

Palladium-Catalyzed C(sp3)H Activation: A Facile Method for the Synthesis of 3,4-Dihydroquinolinone Derivatives

(2014) Jia-Xuan Yan et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Late-Stage Functionalization of Biologically Active Heterocycles Through Photoredox Catalysis

(2014) Daniel A. DiRocco et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Copper-catalyzed phosphorylation of sp2C–H bonds

(2014) Shan Wang et al.   CHEMICAL COMMUNICATIONS

The carbomethylation of arylacrylamides leading to 3-ethyl-3-substituted indolin-2-one by cascade radical addition/cyclization

(2014) Qiang Dai et al.   CHEMICAL COMMUNICATIONS

tert-Butyl Peroxybenzoate-Promoted α-Methylation of 1,3-Dicarbonyl Compounds

(2014) Songjin Guo et al.   JOURNAL OF ORGANIC CHEMISTRY

C–H Methylation of Heteroarenes Inspired by Radical SAM Methyl Transferase

(2014) Jinghan Gui et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

A Versatile Tripodal Cu(I) Reagent for C–N Bond Construction via Nitrene-Transfer Chemistry: Catalytic Perspectives and Mechanistic Insights on C–H Aminations/Amidinations and Olefin Aziridinations

(2014) Vivek Bagchi et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Ligand-Promoted Alkylation of C(sp3)–H and C(sp2)–H Bonds

(2014) Ru-Yi Zhu et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Cobalt(III)-Catalyzed Synthesis of Indazoles and Furans by C–H Bond Functionalization/Addition/Cyclization Cascades

(2014) Joshua R. Hummel et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Highly Site-Selective Direct C–H Bond Functionalization of Phenols with α-Aryl-α-diazoacetates and Diazooxindoles via Gold Catalysis

(2014) Zhunzhun Yu et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Cu(II)-Mediated C–S/N–S Bond Formation via C–H Activation: Access to Benzoisothiazolones Using Elemental Sulfur

(2014) Fa-Jie Chen et al.   ORGANIC LETTERS

Syntheses of Sulfides and Selenides through Direct Oxidative Functionalization of C(sp3)–H Bond

(2014) Bingnan Du et al.   ORGANIC LETTERS

Rh-Catalyzed Sequential Oxidative C–H and N–N Bond Activation: Conversion of Azines into Isoquinolines with Air at Room Temperature

(2014) Wenjia Han et al.   ORGANIC LETTERS

Copper-Catalyzed Direct Amination of Quinoline N-Oxides via C–H Bond Activation under Mild Conditions

(2014) Chongwei Zhu et al.   ORGANIC LETTERS

A Free-Radical Cascade Methylation/Cyclization of N-Arylacrylamides and Isocyanides with Dicumyl Peroxide

(2014) Zhengbao Xu et al.   ORGANIC LETTERS

Single-electron transmetalation in organoboron cross-coupling by photoredox/nickel dual catalysis

(2014) J. C. Tellis et al.   SCIENCE

Silver-catalysed direct amination of unactivated C–H bonds of functionalized molecules

(2014) Mingyu Yang et al.   Nature Communications

Synthesis of Dibenzopyranones through Palladium-Catalyzed Directed C-H Activation/Carbonylation of 2-Arylphenols

(2013) Shuang Luo et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Palladium-Catalyzed Oxidative Acetoxylation of Benzylic C–H Bond Using Bidentate Auxiliary

(2013) Long Ju et al.   JOURNAL OF ORGANIC CHEMISTRY

Copper-Catalyzed Methyl Esterification Reactions via C–C Bond Cleavage

(2013) Yan Zhu et al.   JOURNAL OF ORGANIC CHEMISTRY

Palladium-Catalyzed C–H Activation/Cross-Coupling of Pyridine N-Oxides with Nonactivated Secondary Alkyl Bromides

(2013) Bin Xiao et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

RhIII/CuII-Cocatalyzed Synthesis of 1H-Indazoles through C–H Amidation and N–N Bond Formation

(2013) Da-Gang Yu et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Rhodium-Catalyzed Directed C–H Cyanation of Arenes with N-Cyano-N-phenyl-p-toluenesulfonamide

(2013) Tian-Jun Gong et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Palladium-Catalyzed Picolinamide-Directed Alkylation of Unactivated C(sp3)–H Bonds with Alkyl Iodides

(2013) Shu-Yu Zhang et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Stereoselective Synthesis of β-Alkylated α-Amino Acids via Palladium-Catalyzed Alkylation of Unactivated Methylene C(sp3)–H Bonds with Primary Alkyl Halides

(2013) Shu-Yu Zhang et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Copper-Catalyzed N-Methylation of Amides and O-Methylation of Carboxylic Acids by Using Peroxides as the Methylating Reagents

(2013) Qinqin Xia et al.   ORGANIC LETTERS

Redox-Neutral α-C–H Bond Functionalization of Secondary Amines with Concurrent C–P Bond Formation/N-Alkylation

(2013) Deepankar Das et al.   ORGANIC LETTERS

Mild Palladium-Catalyzed C–H Alkylation Using Potassium Alkyltrifluoroborates in Combination with MnF3

(2013) Sharon R. Neufeldt et al.   ORGANIC LETTERS

Ruthenium-catalyzed ortho-C–H bond alkylation of aromatic amides with α,β-unsaturated ketones via bidentate-chelation assistance

(2013) Guy Rouquet et al.   Chemical Science

Ruthenium(II)-Catalyzed C–H Bond Activation and Functionalization

(2012) Percia Beatrice Arockiam et al.   CHEMICAL REVIEWS

Innate and Guided C–H Functionalization Logic

(2011) Tobias Brückl et al.   ACCOUNTS OF CHEMICAL RESEARCH

Synthesis of Dibenzofurans via Palladium-Catalyzed Phenol-Directed C–H Activation/C–O Cyclization

(2011) Bin Xiao et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Copper-Catalyzed Intermolecular Amination of Acidic Aryl CH Bonds with Primary Aromatic Amines

(2010) Huaiqing Zhao et al.   ADVANCED SYNTHESIS & CATALYSIS

Palladium-Catalyzed Ligand-Directed C−H Functionalization Reactions

(2010) Thomas W. Lyons et al.   CHEMICAL REVIEWS

Direct C−H Transformation via Iron Catalysis

(2010) Chang-Liang Sun et al.   CHEMICAL REVIEWS

Palladium-Catalyzed Methylation of Aryl C−H Bond by Using Peroxides

(2008) Yuhua Zhang et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Potassium Organotrifluoroborates:  New Perspectives in Organic Synthesis

(2007) Sylvain Darses et al.   CHEMICAL REVIEWS