4.4 Article

Synthesis and size-dependent magnetic properties of single-crystalline hematite nanodiscs

期刊

JOURNAL OF CRYSTAL GROWTH
卷 328, 期 1, 页码 62-69

出版社

ELSEVIER SCIENCE BV
DOI: 10.1016/j.jcrysgro.2011.05.030

关键词

Nanostructures; Hydrothermal crystal growth; Oxides; Magnetic materials

资金

  1. National Natural Science Foundation of China [21073116]
  2. Natural Science Foundation of Shanxi Province [2010JM2011]
  3. Fundamental Research Funds for the Central Universities [Gk200901003]

向作者/读者索取更多资源

Single-crystalline alpha-Fe(2)O(3) nanodiscs with diameters of 132-150 nm were synthesized by a facile and efficient hydrothermal reaction of FeCl(3) with NaH(2)PO(4) and H(2)O at 200 degrees C for 12 h. The diameters of the nanodiscs can be decreased to 91-112 and 78-92 nm by adding ethanol glycol into the hydrothermal system. The alpha-Fe(2)O(3) nanodiscs are formed by the cooperative action of selective adsorption and etching of the phosphate ions. The as-synthesized alpha-Fe(2)O(3) nanodiscs exhibit weak ferromagnetic behaviours. The remanent magnetization and coercivity of the nanodiscs with the diameters of 132-150 nm are 0.01743 emu g(-1) and 214.8 Oe, respectively, and the remanent magnetization and coercivity decrease with deceasing the nanodisc size. (C) 2011 Elsevier B.V. All rights reserved.

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