4.4 Article

Unusual corrugated nanowires of zinc oxide

期刊

JOURNAL OF CRYSTAL GROWTH
卷 310, 期 13, 页码 3139-3143

出版社

ELSEVIER SCIENCE BV
DOI: 10.1016/j.jcrysgro.2008.04.002

关键词

crystal morphology; surface structure; physical vapor deposition processes; zinc oxides

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We report an unusual morphology of ZnO nanowires with a hexagonal cross-section and corrugated side walls. Nanowires grow along the [0 0 0 1] direction and possess side walls built predominantly with facets of {10 (1) over bar1} and {10 (1) over bar(1) over bar} families. Such a morphology deviates dramatically from the well-known growth habit of ZnO nanowires that involves smooth side walls represented by {10 (1) over bar0} or {11 (2) over bar0} facets with the lowest surface energy. The formation of corrugated nanowires is attributed to the lateral growth activated by the high vapor supersaturation and the presence of stacking faults. (C) 2008 Elsevier B.V. All rights reserved.

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