Review
Engineering, Electrical & Electronic
Chao Zhao, Zhaonan Li, Tianyi Tang, Jiaqian Sun, Wenkang Zhan, Bo Xu, Huajun Sun, Hui Jiang, Kong Liu, Shengchun Qu, Zhijie Wang, Zhanguo Wang
Summary: This passage discusses the increasing demand for fabricating III-V semiconductor materials on unconventional substrates, highlighting the potential advantages of defect-free epitaxial growth through two-dimensional materials. The unique optical properties of the epitaxy correlating with their growth conditions are explored, along with their applications in optics and nanophotonics. Challenges and remaining obstacles in fully exploiting the potential for practical applications are also addressed.
PROGRESS IN QUANTUM ELECTRONICS
(2021)
Article
Crystallography
Theresa E. Saenz, Manali Nandy, Agnieszka Paszuk, David Ostheimer, Juliane Koch, William E. McMahon, Jeramy D. Zimmerman, Thomas Hannappel, Emily L. Warren
Summary: By studying the surface structure and chemical composition of V-groove Si, it is found that different pretreatment methods can be used to deoxidize and clean the V-groove Si surface, demonstrating that the behavior of V-groove Si is similar to that of reference samples of planar Si surfaces, providing a basis for future studies.
JOURNAL OF CRYSTAL GROWTH
(2022)
Article
Materials Science, Multidisciplinary
Nutthapong Discharoen, Sakuntam Sanorpim, Noppadon Nuntawong, Visittapong Yordsri, Suphakan Kijamnajsuk, Kentaro Onabe
Summary: Cubic AlN films were successfully grown on MgO substrates using a two-step cubic GaN buffer layer. The two-step buffer layer was found to play a crucial role in the epitaxial growth of c-AlN, resulting in improved crystallinity compared to one-step and nonGaN buffer layers.
Article
Chemistry, Physical
Danhao Wang, Ding Wang, Peng Zhou, Mingtao Hu, Jiangnan Liu, Shubham Mondal, Tao Ma, Ping Wang, Zetian Mi
Summary: Through high-resolution X-ray photoelectron spectroscopy measurements, we discovered a thick oxide layer on ScAlN when exposed to air, which significantly affects its characterization and electronic structure evaluation. By excluding the possible impact from the surface oxide layer, the band alignment of Sc0.18Al0.82N/GaN can be accurately determined. Simulation results further demonstrate that the Sc0.18Al0.82N barrier layer offers excellent charge carrier confinement and a high density of two-dimensional electron gas (2DEG) at the heterostructure interface, crucial for high-performance GaN-based high electron mobility transistors (HEMTs).
APPLIED SURFACE SCIENCE
(2023)
Article
Crystallography
Amalia Fernando-Saavedra, Steven Albert, Ana Bengoechea-Encabo, Achim Trampert, Mengyao Xie, Miguel A. Sanchez-Garcia, Enrique Calleja
Summary: Non-polar m-plane GaN films were grown on & gamma;-LiAlO2 (100) substrates using a two-step process that involved coalescence of GaN nanocolumns obtained from a GaN buffer. Transmission electron microscopy data showed a significant reduction in extended defects density in the coalesced film compared to the initial GaN buffer, likely due to a filter effect during the regrowth process. Low temperature photoluminescence spectra confirmed this reduction in defects, with a decrease in stacking faults emission peaks and a dominant donor-bound excitonic emission at 3.472 eV.
JOURNAL OF CRYSTAL GROWTH
(2023)
Article
Chemistry, Multidisciplinary
Mina Moradnia, Sara Pouladi, Jie Chen, Nam-In Kim, Onosetale Aigbe, Jae-Hyun Ryou
Summary: HybCVD technique using chloride and hydride precursors is introduced to obtain ScAlN thin films, addressing the challenges in film quality and manufacturability. Numerical analysis of precursor thermodynamics and vapor-solid reactions evaluate the precursors' suitability and alloy composition control.
CRYSTAL GROWTH & DESIGN
(2022)
Article
Chemistry, Physical
Dmitry Rogilo, Sergey Sitnikov, Sergey Ponomarev, Dmitry Sheglov, Liudmila Fedina, Alexander Latyshev
Summary: Through in situ reflection electron microscopy and ex situ atomic force microscopy, the research investigated the morphological stability of large-scale Si(111)-7x7 terraces during silicon growth and etching by oxygen and selenium. The study identified three modes of morphological instability, with oxygen etching leading to slow multilayer development and selenium-induced etching preserving flat surface morphology with periodic 2D vacancy island formation. Additionally, on step-bunched surfaces, Si or Se adatom diffusion to step bunches results in self-organized pyramidlike or valley-like morphology during Si growth or Se-induced etching.
APPLIED SURFACE SCIENCE
(2021)
Article
Nanoscience & Nanotechnology
Bruno Daudin, Alexandra-Madalina Siladie, Marion Gruart, Martien den Hertog, Catherine Bougerol, Benedikt Haas, Jean-Luc Rouviere, Eric Robin, Maria-Jose Recio-Carretero, Nuria Garro, Ana Cros
Summary: The spontaneous growth of GaN nanowires in the absence of catalyst is controlled by Ga flux, with diffusion barriers causing an uneven distribution of Ga adatoms at the top surface leading to GaN accumulation in the periphery. This promotes the formation of superlattices in InGaN and AlGaN nanowires, while the presence of Mg enhances Al diffusion length along the sidewalls in AlN nanowires, inducing the formation of AlN nanotubes.
Article
Physics, Condensed Matter
M. Nemoz, F. Semond, S. Rennesson, M. Leroux, S. Bouchoule, G. Patriarche, J. Zuniga-Perez
Summary: The diffusion at the AlN/Al0.3Ga0.7N interface was found to be weakly concentration-dependent and more strain-dependent. Unintentional annealing during long growth runs resulted in the formation of AlGaN graded layers at each interface.
SUPERLATTICES AND MICROSTRUCTURES
(2021)
Article
Crystallography
Cheyenne Lynsky, Ryan C. White, Yi Chao Chow, Wan Ying Ho, Shuji Nakamura, Steven P. DenBaars, James S. Speck
Summary: The role of V-defect density on the performance of green III-nitride LEDs grown on sapphire substrates was experimentally investigated in this study. Results showed that V-defect engineering has the potential to achieve low forward voltage and long wavelength LEDs on sapphire substrates.
JOURNAL OF CRYSTAL GROWTH
(2021)
Article
Chemistry, Physical
Mansi Agrawal, Anubha Jain, Vishakha Kaushik, Akhilesh Pandey, B. R. Mehta, R. Muralidharan
Summary: In this study, catalyst-free GaN nanowires were grown on Si (111) substrates by plasma-assisted molecular beam epitaxy, followed by the deposition of a few layers of MoS2 by chemical vapor deposition. The morphology and vibrational properties of the MoS2/GaN nanowires on Si (111) substrates were analyzed using scanning electron microscopy and Raman spectroscopy. The results indicate the potential of MoS2/GaN nanowires heterojunction for future optoelectronic devices due to their exceptional structural and vibrational properties.
JOURNAL OF ALLOYS AND COMPOUNDS
(2021)
Article
Crystallography
Menglin Chang, Jiayi Li, Ziyuan Yuan, Kedong Zhang, Chen Li, Yu Deng, Hong Lu, Yan-Feng Chen
Summary: Single-crystalline aluminum films were grown on Si substrates by molecular beam epitaxy to study the growth mechanism and demonstrate interface modulation. Lowering the growth temperature improved the surface wetting. Post-annealing effectively eliminated twins within a thin aluminum film. The best twin-free aluminum film with atomically sharp Al/Si interface was achieved using a two-step method. Ellipsometry measurements showed overall reduction in ε2 compared to Palik's values, especially in the UV regions.
JOURNAL OF CRYSTAL GROWTH
(2022)
Article
Chemistry, Physical
Dheemahi Rao, Ongira Chowdhury, Ashalatha Indiradevi Kamalasanan Pillai, Gopal K. Pradhan, Satyaprakash Sahoo, Joseph Patrick Feser, Magnus Garbrecht, Bivas Saha
Summary: Researchers introduced native defects into ScN thin films through lithium ion irradiation and found that these defects positively impact ScN's thermoelectric properties by increasing its Seebeck coefficient and reducing its thermal conductivity.
ACS APPLIED ENERGY MATERIALS
(2022)
Article
Chemistry, Multidisciplinary
Vladimir G. Dubrovskii, Egor D. Leshchenko
Summary: A new model is proposed for the radial growth of self-catalyzed III-V nanowires on different substrates, which takes into account the re-emission of group III atoms and the shadowing effect in directional deposition techniques. The model accurately describes the morphological evolution of Ga-catalyzed GaP and GaAs nanowires on different substrates, providing useful insights for morphological control over III-V nanowires.
Article
Chemistry, Multidisciplinary
Qi Chen, Kailai Yang, Bo Shi, Xiaoyan Yi, Junxi Wang, Jinmin Li, Zhiqiang Liu
Summary: Beyond traditional heteroepitaxy, 2D-materials-assisted epitaxy opens opportunities to revolutionize future material integration methods. However, basic principles in 2D-material-assisted nitrides' epitaxy remain unclear, which impedes understanding the essence, thus hindering its progress. Here, the crystallographic information of nitrides/2D material interface is theoretically established, which is further confirmed experimentally. It is found that the atomic interaction at the nitrides/2D material interface is related to the nature of underlying substrates. For single-crystalline substrates, the heterointerface behaves like a covalent one and the epilayer inherits the substrate's lattice. Meanwhile, for amorphous substrates, the heterointerface tends to be a van der Waals one and strongly relies on the properties of 2D materials. Therefore, modulated by graphene, the nitrides' epilayer is polycrystalline. In contrast, single-crystalline GaN films are successfully achieved on WS2. These results provide a suitable growth-front construction strategy for high-quality 2D-material-assisted nitrides' epitaxy. It also opens a pathway toward various semiconductors heterointegration.
ADVANCED MATERIALS
(2023)
Article
Multidisciplinary Sciences
C. Elias, P. Valvin, T. Pelini, A. Summerfield, C. J. Mellor, T. S. Cheng, L. Eaves, C. T. Foxon, P. H. Beton, S. Novikov, B. Gil, G. Cassabois
NATURE COMMUNICATIONS
(2019)
Article
Nanoscience & Nanotechnology
Jamal-Deen Musah, Xiao Yanjun, A. M. Ilyas, Travis G. Novak, Seokwoo Jeon, Clement Arava, S. V. Novikov, D. S. Nikulin, Wei Xu, Liyao Liu, Asaduzzaman Md, Kwok-Ho Lam, Xianfeng Chen, Chi-Man Lawrence Wu, Vellaisamy A. L. Roy
ACS APPLIED MATERIALS & INTERFACES
(2019)
Article
Physics, Applied
K. A. Omari, L. X. Barton, O. Amin, R. P. Campion, A. W. Rushforth, A. J. Kent, P. Wadley, K. W. Edmonds
JOURNAL OF APPLIED PHYSICS
(2020)
Article
Physics, Condensed Matter
Yu. B. Vasiliev, S. N. Novikov, S. N. Danilov, S. D. Ganichev
Article
Multidisciplinary Sciences
Iaroslav A. Mogunov, Sergiy Lysenko, Anatolii E. Fedianin, Felix E. Fernandez, Armando Rua, Anthony J. Kent, Andrey Akimov, Alexandra M. Kalashnikova
NATURE COMMUNICATIONS
(2020)
Article
Materials Science, Multidisciplinary
James Thomas, Jonathan Bradford, Tin S. Cheng, Alex Summerfield, James Wrigley, Christopher J. Mellor, Andrei N. Khlobystov, C. Thomas Foxon, Laurence Eaves, Sergei Novikov, Peter H. Beton
Article
Materials Science, Multidisciplinary
Ia. A. Mogunov, S. Lysenko, F. Fernandez, A. Rua, A. V. Muratov, A. J. Kent, A. M. Kalashnikova, A. V. Akimov
PHYSICAL REVIEW MATERIALS
(2020)
Article
Materials Science, Multidisciplinary
James Wrigley, Jonathan Bradford, Tyler James, Tin S. Cheng, James Thomas, Christopher J. Mellor, Andrei N. Khlobystov, Laurence Eaves, C. Thomas Foxon, Sergei Novikov, Peter H. Beton
Summary: Monolayers of hexagonal boron nitride (hBN) are grown on graphite substrates using high-temperature molecular beam epitaxy (HT-MBE). The growth is temperature-dependent, and significant differences are observed between growth on monolayer and multilayer graphite steps.
Article
Materials Science, Multidisciplinary
G. Lioliou, C. L. Poyser, J. Whale, R. P. Campion, A. J. Kent, A. M. Barnett
Summary: A circular mesa GaAs p(+)-i-n(+) photodiode was characterized for its performance as a detector in photon counting x-ray spectroscopy. The new detector showed improved performance compared to an earlier detector made from the same epiwafer. Using the new detector and low noise readout electronics, an energy resolution of 750 eV 20 eV FWHM at 5.9 keV was achieved at 20 degrees C.
MATERIALS RESEARCH EXPRESS
(2021)
Article
Materials Science, Multidisciplinary
Ricardo Javier Pena Roman, Fabio J. R. Costa Costa, Alberto Zobelli, Christine Elias, Pierre Valvin, Guillaume Cassabois, Bernard Gil, Alex Summerfield, Tin S. Cheng, Christopher J. Mellor, Peter H. Beton, Sergei Novikov, Luiz F. Zagonel
Summary: Through the use of low temperature scanning tunneling microscopy and spectroscopy, the electronic band gap of a defect-free single layer of h-BN was directly measured at (6.8 +/- 0.2) eV, with an exciton binding energy of (0.7 +/- 0.2) eV. Additionally, complex spectra associated with carbon defects and intragap electronic levels around 2.0 eV below the Fermi level were observed in some regions of the monolayer h-BN.
Article
Physics, Multidisciplinary
G. Cassabois, G. Fugallo, C. Elias, P. Valvin, A. Rousseau, B. Gil, A. Summerfield, C. J. Mellor, T. S. Cheng, L. Eaves, C. T. Foxon, P. H. Beton, M. Lazzeri, A. Segura, S. Novikov
Summary: In this study, parallel investigation of exciton and phonon radiative linewidths in atomically thin layers of hexagonal boron nitride (h-BN) was conducted, revealing a significant radiative broadening in the two-dimensional material and indicating the existence of radiative states for optical phonons in 2D. This finding has important implications for fundamental physics and optoelectronic applications.
Article
Chemistry, Multidisciplinary
Wenjing Yan, Andrey Akimov, Maria Barra-Burillo, Manfred Bayer, Jonathan Bradford, Vitalyi E. Gusev, Luis E. Hueso, Anthony Kent, Serhii Kukhtaruk, Achim Nadzeyka, Amalia Patane, Andrew W. Rushforth, Alexey Scherbakov, Dmytro D. Yaremkevich, Tetiana L. Linnik
Summary: Strain engineering using coherent phonons allows for the control of physical properties in 2D-vdW crystals, with the creation of flexural phononic crystals through periodic modulation of elastic coupling in vdW layers. Using an ultrafast pump-probe technique, we have successfully generated and detected these phonons, providing exciting prospects for ultrafast manipulation of states in 2D materials for emerging quantum technologies.
Article
Chemistry, Physical
Noah Mendelson, Dipankar Chugh, Jeffrey R. Reimers, Tin S. Cheng, Andreas Gottscholl, Hu Long, Christopher J. Mellor, Alex Zettl, Vladimir Dyakonov, Peter H. Beton, Sergei V. Novikov, Chennupati Jagadish, Hark Hoe Tan, Michael J. Ford, Milos Toth, Carlo Bradac, Igor Aharonovich
Summary: The visible single-photon emitters in hexagonal boron nitride have been confirmed to be carbon-related, based on evidence from controlling impurity incorporation and conducting implantation experiments. Computational analysis identified the negatively charged VBCN- defect as a likely candidate, with predictions of its environmental sensitivity. This resolves the long-standing debate on the origin of single emitters in hBN and will be crucial for the deterministic engineering of these defects for quantum photonic devices.
Article
Physics, Multidisciplinary
S. Brehm, A. Akimov, R. P. Campion, A. J. Kent
PHYSICAL REVIEW RESEARCH
(2020)
Article
Multidisciplinary Sciences
Alexander Usikov, Konstantin Borodkin, Sergey Novikov, Alexander Roenkov, Andrei Goryachkin, Mikhail Puzyk, Iosif Barash, Sergey Lebedev, Alexander Zubov, Yuri Makarov, Alexander Lebedev
PROCEEDINGS OF THE ESTONIAN ACADEMY OF SCIENCES
(2019)
Article
Crystallography
Jianzheng Hu, Long Yan, Ning Zhou, Yao Chen, Xiaoni Yang, Lianqiao Yang, Shiping Guo
Summary: The effect and mechanism of carrier gas velocity, V/III ratio, and carrier gas velocity match on the growth rate of AlN were investigated in this study. The results showed that the growth rate of AlN initially increased with hydrogen flow rate, reached saturation, and then decreased monotonically. The turning point value depended on the equipment and process. By increasing the MO VM, the growth rate of AlN could be improved, but the uniformity deteriorated due to turbulence and loss of uniform boundary layer. High quality AlN films were successfully grown on nano-patterned sapphire substrates with improved crystalline quality and atomic smooth surfaces.
JOURNAL OF CRYSTAL GROWTH
(2024)
Article
Crystallography
Tingting Ma, Yang Li, Kangning Sun, Qinglin Cheng, Sen Li
Summary: This study investigates the melting process and nucleation behavior of sodium crystals using molecular dynamics simulation. The results show good agreement between simulated and experimental values for the melting temperature, density, and radial distribution function of sodium. The diffusion coefficient of liquid sodium increases linearly with temperature, and the homogeneous nucleation rate of melting in superheated sodium crystal exponentially increases with temperature. The findings provide theoretical support for applications involving heat and mass transfer in sodium-related systems.
JOURNAL OF CRYSTAL GROWTH
(2024)
Article
Crystallography
Hisato Nishii, Shintarou Iida, Akira Yamasaki, Takumi Ikenoue, Masao Miyake, Toshiya Doi, Tetsuji Hirato
Summary: Epitaxial V2O3 films were fabricated on sapphire substrates using mist chemical vapor deposition (mist CVD) method, eliminating the need for high vacuum conditions. The films can be grown on sapphire substrates even under atmospheric pressure, with the optimal growth temperature at 823 K. The films grown at 823 K exhibit a metal-insulator transition at approximately 155 K. The film on C-plane sapphire exhibits a lower transition temperature compared to those on R- and A-plane sapphire substrates.
JOURNAL OF CRYSTAL GROWTH
(2024)
Article
Crystallography
Jani Jesenovec, Kevin Zawilski, Peter Alison, Stephan J. Meschter, Sambit K. Saha, Andrew J. Sepelak, Peter G. Schunemann
Summary: In this study, NiSb needles were successfully formed in InSb by manipulating the growth rate and adding NiSb. These needle structures in InSb can be used to tune the magnetoresistance of devices. Additionally, undoped InSb crystals demonstrated good infrared transmission at low growth rates.
JOURNAL OF CRYSTAL GROWTH
(2024)
Article
Crystallography
D. Joseph Daniel, P. Karuppasamy, H. J. Kim
Summary: The 2-amino 4-methyl pyridinium oxalate (2A4MPO) compound was synthesized and its crystal structure, functional groups, thermal stability, electrical properties, and third-order nonlinear optical properties were studied. The results demonstrate that the synthesized crystal has good structural integrity, thermal stability, and potential for third-order nonlinear optical applications.
JOURNAL OF CRYSTAL GROWTH
(2024)
Article
Crystallography
C. W. Lan
Summary: The past two decades have witnessed a significant transformation in solar silicon crystal growth, especially in the competition between multi-crystalline silicon (Multi-Si) and mono-crystalline silicon (Mono-Si). The demand for this crucial material has exponentially surged, with silicon solar panels capturing over 95% of the global PV market share. The advancements in crystal growth technology during this period have set historical benchmarks, with the market share shifting from high-performance multi-crystalline silicon (HPM-Si) to CZ silicon.
JOURNAL OF CRYSTAL GROWTH
(2024)
Article
Crystallography
Peiyao Hao, Lili Zheng, Hui Zhang
Summary: A novel design of argon gas tube for removing impurities during silicon ingot growth was developed, and numerical simulations showed that it can effectively extract SiO.
JOURNAL OF CRYSTAL GROWTH
(2024)
Article
Crystallography
Geetika Sahu, Chanchal Chakraborty, Subhadeep Roy, Souri Banerjee
Summary: This article discusses the novel fractal nature of hydrothermally synthesized MoS2 QDs. By adjusting the reaction time, the study found that the average size of QDs increases and then decreases with longer reaction times. STEM images indicate that shorter reaction times lead to sheet formation, while extended reaction times cause sheets to fragment into QDs.
JOURNAL OF CRYSTAL GROWTH
(2024)
Article
Crystallography
Pengjian Lu, Wei Huang, Junjun Wang, Haitao Yang, Shiyue Guo, Bin Li, Ting Wang, Chitengfei Zhang, Rong Tu, Song Zhang
Summary: A systematic study on the tetramethylsilane-hydorgen (TMS-H-2) system for the deposition of pure single-crystal SiC by high-temperature chemical vapor deposition (HTCVD) method is conducted. The study investigates the effect of temperature, pressure, and H-2:TMS ratio on the deposition conditions and provides a theoretical basis and guidance for improving the quality and cost of industrial production of single-crystal SiC.
JOURNAL OF CRYSTAL GROWTH
(2024)
Article
Crystallography
Xinyu Jiang, Liangliang Liu, Yanqing Liu, Yan Wang, Zhaoping Hou
Summary: Investigation on the preparation of anisometric templated textured high entropy or multi-element doped ferroelectric ceramics was conducted using A-site disordered niobate microcrystals. The effects of process parameters on the morphology and chemical composition were studied, and the photocatalytic properties of the microcrystals were evaluated.
JOURNAL OF CRYSTAL GROWTH
(2024)
Article
Crystallography
Mobashsara Tabassum, Md. Ashraful Alam, Sabrina Mostofa, Raton Kumar Bishwas, Debasish Sarkar, Shirin Akter Jahan
Summary: In this study, high crystallinity copper nanoparticles were synthesized by altering the reaction medium at low temperatures. The results show that changing the reaction medium can reduce the surface energy of precursors and promote the formation of highly crystalline copper nanoparticles.
JOURNAL OF CRYSTAL GROWTH
(2024)
Article
Crystallography
Ivan Bodnar, Vitaly V. Khoroshko, Veronika A. Yashchuk, Valery F. Gremenok, Mohsin Kazi, Mayeen U. Khandaker, Tatiana I. Zubar, Daria I. Tishkevich, Alex Trukhanov, Sergei Trukhanov
Summary: This work presents the production of single crystals of Cu2ZnGeSe4, a semiconducting quaternary compound, using a gas chemical method with iodine as a transporter. The phase state, crystal structure, and lattice constants of the synthesized samples were refined and determined. The band gap of Cu2ZnGeSe4 was calculated using transmission spectrum and it was found that the band gap increases by 12% with decreasing temperature in the range of 20-300 K.
JOURNAL OF CRYSTAL GROWTH
(2024)
Article
Crystallography
Timur Malin, Igor Osinnykh, Vladimir Mansurov, Dmitriy Protasov, Sergey Ponomarev, Denis Milakhin, Konstantin Zhuravlev
Summary: The effect of growth temperature on the buffer leakage currents of GaN-on-Si layers was investigated. It was found that higher growth temperature results in lower leakage currents. The defects in GaN layers grown at different temperatures were studied using photoluminescence technique, and a correlation between leakage currents, structural perfection, and donor concentration in GaN-on-Si layers was established. It was also observed that reduced growth temperature leads to the formation of inversion domains.
JOURNAL OF CRYSTAL GROWTH
(2024)
Article
Crystallography
Thi-Hoai-Thu Nguyen, Jyh-Chen Chen
Summary: The effect of heater power control on heat, flow, and oxygen transport for CCz crystal growth was studied. Shorter upper side heater design could improve crystal quality and growth, but with higher power consumption.
JOURNAL OF CRYSTAL GROWTH
(2024)
Article
Crystallography
Peter Rudolph
Summary: This article presents an overview of selected contributions to the development of crystal growth technology by the Laudise Prize awardee 2023. It discusses various aspects such as shaped crystal growth, the correlation between melt structure and crystal quality, control of intrinsic defects and inclusions, prevention of dislocation cell patterns, and melt growth experiments under a travelling magnetic field.
JOURNAL OF CRYSTAL GROWTH
(2024)