4.7 Article

Mesoporous (N, S)-codoped TiO2 nanoparticles as effective photoanode for dye-sensitized solar cells

期刊

JOURNAL OF ALLOYS AND COMPOUNDS
卷 512, 期 1, 页码 23-26

出版社

ELSEVIER SCIENCE SA
DOI: 10.1016/j.jallcom.2011.08.072

关键词

Dye-sensitized solar cells; Codoping; Titania; Mesoporous nanoparticles

资金

  1. National Science Foundation of China [50902056]
  2. Scientific Research Foundation for the Returned Overseas Chinese Scholars of Ministry of Education
  3. Fundamental Research Funds for the Central Universities [HUST 2010MS087]
  4. State Key Lab of Material Processing and Die & Mould Technology

向作者/读者索取更多资源

(N, S)-codoped titania (TiO2) is synthesized by a simple template-free solvothermal method as photoanode for dye-sensitized solar cells (DSSCs). The results confirm that N and S have been doped into the lattice of anatase, which can enhance the visible-light absorbance and promote the electron transportation in TiO2. The prepared (N, S)-codoped TiO2 exhibits pure anatase phase mesoporous nanoparticles with average diameter of 60 nm. Mixing (N, S)-codoped TiO2 with Degussa P25 as photoanode results in the improvement of open-circuit voltage and short-circuit photocurrent density of DSSC. And the corresponding DSSC obtains a high conversion efficiency of 8.0%. (C) 2011 Elsevier B. V. All rights reserved.

作者

我是这篇论文的作者
点击您的名字以认领此论文并将其添加到您的个人资料中。

评论

主要评分

4.7
评分不足

次要评分

新颖性
-
重要性
-
科学严谨性
-
评价这篇论文

推荐

Article Chemistry, Physical

High-performance La0.5(Ba0.75Ca0.25)0.5Co0.8Fe0.2O3-δ cathode for proton-conducting solid oxide fuel cells

Dong Xie, Kai Li, Jun Yang, Dong Yan, Lichao Jia, Bo Chi, Jian Pu, Jian Li

Summary: The perovskite cathode material La-0.5(Ba0.75Ca0.25)(0.5)Co0.8Fe0.2O3-delta, with high electrical conductivity and catalytic activity, was used in proton-conducting solid oxide fuel cells. When combined with the electrolyte BaZr0.1Ce0.7Y0.1Yb0.1O3-delta, it showed excellent electrochemical performance, low polarization resistance, and high peak power density. The oxygen reduction reaction was found to be limited by oxygen adsorption, dissociation, and diffusion processes.

INTERNATIONAL JOURNAL OF HYDROGEN ENERGY (2021)

Article Nanoscience & Nanotechnology

Redox-Reversible Electrode Material for Direct Hydrocarbon Solid Oxide Fuel Cells

Peng Qu, Xin Yang, Wanhua Wang, Tong Wei, Yanying Lu, Jie Lin, Zhihao Yuan, Lichao Jia, Jian Li, Fanglin Chen

ACS APPLIED MATERIALS & INTERFACES (2020)

Article Chemistry, Physical

Mechanism of Proton Conduction in Doped Barium Cerates: A First-Principles Study

Xiaofeng Yang, Lichao Jia, Bicai Pan, Bo Chi, Jian Pu, Jian Li

JOURNAL OF PHYSICAL CHEMISTRY C (2020)

Article Chemistry, Applied

High performance and stability of double perovskite-type oxide NdBa0.5Ca0.5Co1.5Fe0.5O5+delta as an oxygen electrode for reversible solid oxide electrochemical cell

Yunfeng Tian, Yun Liu, Wenjie Wang, Lichao Jia, Jian Pu, Bo Chi, Jian Li

JOURNAL OF ENERGY CHEMISTRY (2020)

Article Chemistry, Physical

Dense and Low Oxygen Permeability Bilayer Ceramic Interconnect for Tubular Anode-Support Solid Oxide Cells

Xin Yang, Peng Qiu, Nansheng Xu, Lichao Jia, Lei Alexander Zhang, Kevin Huang

Summary: This study focuses on developing a chromium-free, easy-to-manufacture, and low-cost ceramic interconnect. Through optimizing compositions, examining compatibility, fabricating bilayer structure, and testing performance, SYTN (Y0.08Nb0.02) is identified as the best composition for the interconnect. The bilayer ceramic IC shows high conductivity and dense microstructure, making it a promising candidate for next-generation durable and low-cost tubular SOCs.

ACS APPLIED ENERGY MATERIALS (2021)

Article Chemistry, Physical

Comparative study on solid oxide fuel cell anode microstructure evolution after long-term operation

Jiaqi Geng, Zhenjun Jiao, Dong Yan, Lichao Jia, Jian Pu, Jian Li

Summary: The evolution of solid oxide fuel cell anode microstructure during operation, including Ni migration and Ostwald ripening, has been found to affect pore structure, concentration polarization, and ultimately electrochemical performance. This impact was revealed through evaluations with various microscopy techniques and electrochemical tests such as Electrochemical Impedance Spectrum and Distribution of Relaxation Time analysis.

JOURNAL OF POWER SOURCES (2021)

Review Chemistry, Physical

Sulfonated poly(arylene ether)s based proton exchange membranes for fuel cells

Minghan Xu, Hao Xue, Qingfu Wang, Lichao Jia

Summary: Proton exchange membrane fuel cells (PEMFCs) are potential clean energy sources attracting attention, with a focus on developing high-performance, low-cost PEMs to replace benchmark Nafion membranes. Sulfonated poly(arylene ether ketone)s (SPAEKs) and sulfonated poly(arylene ether sulfone)s (SPAESs) are promising candidates due to their performance and cost advantages. Efforts are classified and introduced in developing SPAEK and SPAES membranes for promising research directions in the field.

INTERNATIONAL JOURNAL OF HYDROGEN ENERGY (2021)

Article Chemistry, Physical

A direct-methane solid oxide fuel cell with a functionally engineered Ni-Fe metal support

Qihao Li, Xin Wang, Chenzhao Liu, Xinwei Yang, Cheng Li, Lichao Jia, Jian Li

Summary: This study developed a new Ni@CNO catalyst with reduced carbon deposition and increased hydrogen production for use in solid oxide fuel cells (MS-SOFCs). The results showed that it has great potential when used as a catalyst in MS-SOFCs.

JOURNAL OF POWER SOURCES (2022)

Article Engineering, Chemical

Enhanced activity and stability of Ce-doped PrCrO3-supported nickel catalyst for dry reforming of methane

Wen Peng, Zongbao Li, Bo Liu, Peng Qiu, Dong Yan, Lichao Jia, Jian Li

Summary: A nickel catalyst supported by perovskite PrCrO3-delta was developed, which exhibited high conversion rates and excellent stability due to a few Ce doping. It was found that surface oxygen vacancies played a crucial role in suppressing carbon deposition and improving the stability of the catalyst. This strategy provides a potential solution for the efficient conversion of low calorific value fuels.

SEPARATION AND PURIFICATION TECHNOLOGY (2022)

Article Nanoscience & Nanotechnology

Coupling MnS and CoS Nanocrystals on Self-Supported Porous N-doped Carbon Nanofibers to Enhance Oxygen Electrocatalytic Performance for Flexible Zn-Air Batteries

Xiaojun Shi, Juwei Du, Lichao Jia, Yansheng Gong, Jun Jin, Huanwen Wang, Rui Wang, Ling Zhao, Beibei He

Summary: A MnCo-based metal organic framework-derived heterogeneous MnS-CoS nanocrystals anchored on free-standing porous N-doped carbon fibers (PNCFs) by the in situ growth method and vulcanization process exhibit remarkable oxygen electrocatalytic activity and stability. The flexible rechargeable Zn-air battery using this composite as binder-free air cathode offers high power density and large specific capacity, and adapts to different bending degrees of operation.

ACS APPLIED MATERIALS & INTERFACES (2023)

Article Electrochemistry

Influence of Mn Content in the Alloy on the Oxidation, Electrical and Volatilization Behavior of Co-Coated Steel Interconnects

Wenying Zhang, Shijing Wu, Lin Chen, Jiale Liu, Lichao Jia, Dong Yan, Li Jian

Summary: Two Co-alloy-coated steels with different manganese contents underwent thermal exposure in air for 1000 hours. The oxidation rate of the coated steels increased with higher manganese content. The Co coating transformed into a three-layer structure during thermal exposure, containing Cr-rich oxide, mixed oxide with Co, Fe, Mn, and Cr, and doped Co3O4 spinel oxide. The Co-coated steel with 1.0 wt% Mn showed lower area specific resistance and slower increase in polarization resistance compared to the uncoated alloy, indicating effective inhibition of outward diffusion of Cr and prevention of cathode poisoning.

JOURNAL OF THE ELECTROCHEMICAL SOCIETY (2023)

Article Energy & Fuels

Metallic Co with Reactive Element Oxide Composite Coatings for Solid Oxide Fuel Cell Interconnect Applications

Wenying Zhang, Ruyu Shi, Lin Chen, Dong Yan, Chunyan Zang, Lichao Jia

Summary: In this study, metallic Co composite coatings with CeO2, La2O3, and Y2O3 reactive element oxides were prepared on Fe-17Cr alloys by electroplating for solid oxide fuel cell interconnect applications, followed by cyclic oxidation. The results showed that all three composite coatings significantly enhanced the oxidation resistance of the substrate alloy at high temperatures, with no further migration of chromium in the coating region. Among the three coatings, the Co/CeO2 coating showed the best performance after 500 hours of oxidation, exhibiting the slowest oxidation rate and the lowest area specific resistance.

ENERGY & FUELS (2023)

Review Chemistry, Multidisciplinary

Proton uptake and proton distribution in perovskite materials for protonic ceramic fuel cell applications

Bo Liu, Chenzhao Liu, Xiaowei Zou, Dong Yan, Jian Li, Lichao Jia

Summary: Protonic ceramic fuel cells have the potential for practical applications due to their high efficiency, low emissions and fuel flexibility. However, the proton uptake capacity and the conductivity of electrolyte and cathode materials limit their output performance. This review summarizes the methods used to detect proton concentration and distribution, and discusses the impact of the proton environment on its transport.

RUSSIAN CHEMICAL REVIEWS (2022)

Article Chemistry, Physical

Novel mixed H+/e-/O2- conducting cathode material PrBa0.9K0.1Fe1.9Zn0.1O5+δ for proton-conducting solid oxide fuel cells

Bo Liu, Zongbao Li, Xinwei Yang, Dong Yan, Jian Li, Lichao Jia

Summary: The double perovskite material PBKFZ has been designed and synthesized as a new cathode for proton-conducting solid oxide fuel cells. The effects of K-doping on various properties have been investigated, and it has been found that K doping improves thermal expansion behavior and proton uptake capacity. A single cell with the PBKFZ cathode exhibits excellent electrochemical performance compared to the cell with the pristine PBFZ cathode.

JOURNAL OF MATERIALS CHEMISTRY A (2022)

Article Chemistry, Physical

Ce-enhanced LaMnO3 perovskite catalyst with exsolved Ni particles for H2 production from CH4 dry reforming

Tong Wei, Xueyan Pan, Shuohao Wang, Peng Qiu, Xiangbowen Du, Bo Liu, Ziling Wang, Lichao Jia

Summary: The introduction of Ce improved the reducibility and oxygen transfer of La0.9Mn0.8Ni0.2O3, facilitating higher levels of reduction and ensuring the structural stability and catalytic activity of LCMN-05.

SUSTAINABLE ENERGY & FUELS (2021)

Article Chemistry, Physical

Magnetic/optical assessments of RFeO3 (R=La, Pr, Nd, and Sm) ceramics: An experimental and theoretical discernment

J. Zamora, T. Bautista, N. S. Portillo-Velez, A. Reyes-Montero, H. Pfeiffer, F. Sanchez-Ochoa, H. A. Lara-Garcia

Summary: Experimental and DFT studies were conducted on the structural, magnetic, and optical properties of RFeO3 perovskites. The perovskites exhibited an orthorhombic crystal structure and weak ferromagnetic behavior. They were confirmed to be semiconductors with a bandgap of approximately 2.1 eV.

JOURNAL OF ALLOYS AND COMPOUNDS (2024)

Article Chemistry, Physical

The effect of Ti-based surface layer on AlSi thin film as a high-performance anode for the lithium-ion battery

Xianxiang Lv, Jing Jin, Weiguang Yang

Summary: By depositing TiN and TiO2 surface layers on AlSi films, the electrochemical performance of silicon-based anodes can be significantly improved, suppressing volume expansion and promoting the formation of a stable SEI layer.

JOURNAL OF ALLOYS AND COMPOUNDS (2024)

Article Chemistry, Physical

Bifunctional phosphate-modulated Cu2O/CeO2 redox heterojunction: A promising approach for proficient CO2 reduction

Sharafat Ali, Haider Ali, Syedul Hasnain Bakhtiar, Sajjad Ali, Muhammad Zahid, Ahmed Ismail, Pir Muhammad Ismail, Amir Zada, Imran Khan, Huahai Shen, Rizwan Ullah, Habib Khan, Mohamed Bououdina, Xiaoqiang Wu, Fazal Raziq, Liang Qiao

Summary: The construction and optimization of redox-heterojunctions using a bifunctional phosphate as an electron-bridge demonstrated significant improvements in photo catalytic activity, including enhanced dispersion, reduced interfacial migration resistance, and increased abundance of active-sites.

JOURNAL OF ALLOYS AND COMPOUNDS (2024)

Article Chemistry, Physical

Engineering heterogeneous synergistic interface and multifunctional cobalt-iron site enabling high-performance oxygen evolution reaction

Ren-Ni Luan, Na Xu, Chao-Ran Li, Zhi-Jie Zhang, Yu-Sheng Zhang, Jun Nan, Shu-Tao Wang, Yong-Ming Chai, Bin Dong

Summary: Extensive research has revealed that oxygen evolution reaction (OER) in alkaline conditions involves dynamic surface restructuring. The development and design of sulfide/oxide pre-catalysts can reasonably adjust the composition and structure after surface reconstruction, which is crucial for OER. This study utilized a simple two-step hydrothermal method to achieve in situ S leaching and doping, inducing the composition change and structure reconstruction of CoFe oxides. The transformed FeOOH and CoOOH exhibited excellent OER activity and could be easily mass-produced using low-cost iron based materials and simple methods.

JOURNAL OF ALLOYS AND COMPOUNDS (2024)

Article Chemistry, Physical

Highly efficiency blue emissive from Bi3+ions in zero-dimensional organic bismuth halide for white LED applications

Jun'an Lai, Daofu Wu, Peng He, Kang An, Yijia Wang, Peng Feng, WeiWei Chen, Zixian Wang, Linfeng Guo, Xiaosheng Tang

Summary: Zero-dimensional organic-inorganic metal halides (OMHs) are gaining attention in the fabrication of light-emitting diodes due to their broad emission band and high photoluminescence quantum yield. This work synthesized a zero-dimensional organic tetraphenylphosphonium bismuth chloride (TBC) that showed efficient blue light emission, with the emission mechanism attributed to the transition of Bi3+ ions. White light-emitting diodes (WLEDs) were fabricated using TBC, along with green-emitting and red-emitting single crystals, achieving single-component white emissions. These findings demonstrate the different emission mechanism of ns2 ions-based OMHs and highlight the potential of bismuth-based OMHs in WLEDs applications.

JOURNAL OF ALLOYS AND COMPOUNDS (2024)

Article Chemistry, Physical

Study on the wear resistance and mechanism of AlCrCuFe2NiTix high-entropy surfacing alloys

Xuewei Liang, Yunhai Su, Taisen Yang, Zhiyong Dai, Yingdi Wang, Xingping Yong

Summary: The revolutionary design concept of high-entropy alloys has brought new opportunities and challenges to the development of advanced metal materials. In this work, AlCrCuFe2NiTix high-entropy flux cored wires were prepared by combining the design idea of a high-entropy alloy with the characteristics of flux cored wire. AlCr-CuFe2NiTix high-entropy surfacing alloys were prepared using gas metal arc welding technology. The wear properties of the alloys were analyzed, and the phase composition, microstructure, strengthening mechanism, and wear mechanism were discussed. The results show that the alloys exhibit a dendritic microstructure with BCC/B2 + FCC phases. Increasing Ti content leads to the precipitation of Laves phase. The alloys show improved microhardness and wear resistance due to the precipitation of coherent B2 and Laves phases. However, excessive Ti addition results in the increase of Laves phase and reduced wear resistance of the alloys.

JOURNAL OF ALLOYS AND COMPOUNDS (2024)

Article Chemistry, Physical

Facile synthesis of ternary g-C3N4/polyacrylic acid/CoFe2O4 nanocomposites for solar light irradiated photocatalytic and supercapacitor applications

M. Vadivel, M. Senthil Pandian, P. Ramasamy, Qiang Jing, Bo Liu

Summary: This work presents the enhanced photocatalytic and electrochemical performance of g-C3N4 assisted PAA on CoFe2O4 ternary nanocomposites. The incorporation of PAA and g-C3N4 improves the separation efficiency of photogenerated charge carriers, resulting in superior photocatalytic degradation and high specific capacitance values.

JOURNAL OF ALLOYS AND COMPOUNDS (2024)

Article Chemistry, Physical

Investigation on bio-synthesized Ni- and Al-doped cobalt ferrite using lemon juice as eco-fuel

Vibhu T. Sivanandan, Ramany Revathy, Arun S. Prasad

Summary: In this study, pure and doped cobalt ferrite nanoparticles were prepared using the sol-gel auto-combustion method with the aid of lemon juice as eco-fuel. The crystal structure, lattice parameter, crystallite size, microstrain, optical parameters, and room temperature magnetic properties of the samples were analyzed. The effect of doping on the magnetic properties was also investigated.

JOURNAL OF ALLOYS AND COMPOUNDS (2024)

Article Chemistry, Physical

Cu, Ni and Ag ions assisted preparation of nonpolar preferential oriented ZnO films with controlled morphology and optical properties

Qing Guo, Bowen Zhang, Benzhe Sun, Yang Qi

Summary: This study prepared ZnO films with various nonpolar preferred orientations using conventional chemical bath deposition method and characterized their growth process and mechanism. It was found that the type and concentration of nitrate could control the preferred orientation and surface roughness of ZnO films. Additionally, ZnO films with different preferred orientations exhibited different optical properties.

JOURNAL OF ALLOYS AND COMPOUNDS (2024)

Article Chemistry, Physical

Characterization of magnetic FeCo particles with controlled bimetallic composition

Chong Zhang, Yan Liu, Zhaoyan Wang, Hang Yang

Summary: In this study, six bimetallic FeCo particles were synthesized via the hydrothermal method at different Fe:Co ratios. The Fe:Co ratio not only modulates the composition of the particles but also influences their structure and magnetic properties. The FeCo alloys showed a transformation from an Fe-based structure to a Co-based structure with increasing Co content. The Fe:Co ratio of 1:1 and 3:1 resulted in particles with the highest and lowest saturation magnetization, respectively.

JOURNAL OF ALLOYS AND COMPOUNDS (2024)

Article Chemistry, Physical

Micro-alloying effects of Ta and B on nano-oxides and grain boundaries in 13CrWTi-ODS ferritic alloys

Jianning Zhang, Jing Li, Yiren Wang, Xiaodong Mao, Yong Jiang

Summary: We conducted a study on the formation of ultra-fine Y-Ti-Ta-O nano-oxides in Ta+B micro-alloyed 13CrWTi-ODS alloys using electron microscopy and first-principles calculations. The Y-Ti-Ta-O nano-oxides were found to be mainly Y2(Ti,Ta)2O7, with an average size of 7 nm and a number density of 6.8 x 1023 m-3. Excess boron was found to enhance the adhesion of some low-sigma grain boundaries but weaken the Fe/Y2Ti2O7 interface, while excess tantalum enhanced the Fe/Y2Ti2O7 interface but caused serious degradation of grain boundaries.

JOURNAL OF ALLOYS AND COMPOUNDS (2024)

Article Chemistry, Physical

Nitrogen-doped reduced graphene oxide/black phosphorus quantum dot composites for electrocatalytic treatment of choroidal melanoma

Yirong Fang, Pei Cheng, Hang Yuan, Hao Zhao, Lishu Zhang

Summary: A new composite system of nitrogen-doped reduced graphene oxide and black phosphorus quantum dots has been developed for tumor therapy, showing improved electrochemical properties and stability. The system generates hydrogen peroxide and hydroxyl radical to effectively kill tumor cells.

JOURNAL OF ALLOYS AND COMPOUNDS (2024)

Article Chemistry, Physical

Significantly enhanced magnetism in cobalt ferrite by manganese and terbium co-doping

Xiufang Qin, Yuanli Ma, Hui Zhang, Ting Zhang, Fang Wang, Xiaohong Xu

Summary: The structure and magnetism of cobalt ferrites after Mn2+-Tb3+ co-doping were studied. Co-doped samples exhibited cubic spinel structure and spherical shape of ferrite nanoparticles. The redistribution of Co2+ and Fe3+ ions between octahedral and tetrahedral sites was observed due to Mn2+-Tb3+ co-doping. The coercivity and magnetization saturation of co-doped samples were significantly improved, leading to a maximum energy product that is 190% higher than that of the un-doped sample.

JOURNAL OF ALLOYS AND COMPOUNDS (2024)

Article Chemistry, Physical

High-performance low-temperature solid oxide fuel cell with nanostructured lanthanum strontium cobaltite/yttria-stabilized zirconia cathode via advanced co-sputtering

Ho Yeon Lee, Wonjong Yu, Yoon Ho Lee

Summary: Recently, there has been an increasing interest in developing ultra-fine nanostructured electrodes with extensive reaction areas to enhance the performance and low-temperature operation of solid oxide fuel cells. The use of a refined approach involving co-sputtering metal alloys and oxide targets has demonstrated the feasibility of nano-columnar structures in perovskite-based electrodes, expanding the temperature range of thin film electrodes. This study systematically examines the effects of chamber pressure control in the co-sputtering process and identifies the intricate relationship between sputtering pressure and film structure. By fine-tuning the columnar growth in the electrode, significant improvements in performance and thermo-mechanical properties were achieved, resulting in high-performance all-sputtered solid oxide fuel cells.

JOURNAL OF ALLOYS AND COMPOUNDS (2024)

Article Chemistry, Physical

Amorphous quaternary alloy nanoplates for efficient catalysis of hydrogen evolution reaction

Qianyun Bai, Xiaoxiao Yan, Da Liu, Kang Xiang, Xin Tu, Yanhui Guo, Renbing Wu

Summary: This study proposes a simple method to develop a non-precious transition metal-based electrocatalyst with high catalytic activity and robustness for the hydrogen evolution reaction. The as-synthesized electrode exhibits a low overpotential and high current density, indicating its potential in energy conversion.

JOURNAL OF ALLOYS AND COMPOUNDS (2024)