4.7 Article

Lipase-Catalyzed Preparation of Human Milk Fat Substitutes from Palm Stearin in a Solvent-Free System

期刊

JOURNAL OF AGRICULTURAL AND FOOD CHEMISTRY
卷 59, 期 11, 页码 6055-6063

出版社

AMER CHEMICAL SOC
DOI: 10.1021/jf200619v

关键词

Human milk fat substitutes; lipozyme RM IM; acidolysis; palm stearin; response surface methodology; solvent-free system

向作者/读者索取更多资源

Human milk fat substitutes (HMFSs) were synthesized by lipozyme RM IM-catalyzed acidolysis of chemically interesterified palm stearin (mp =58 degrees C) with mixed FM from rapeseed oil, sunflower oil, palm kernel oil, stearic acid, and myristic acid in a solvent-free system. Response surface methodology (RSM) was used to model and optimize the reactions, and the factors chosen were reaction time, temperature, substrate molar ratio, and enzyme load. The optimal conditions generated from the models were as follows: reaction time, 3.4 h; temperature, 57 degrees C; substrate molar ratio, 14.6 mol/mol; and enzyme load, 10.7 wt % (by the weight of total substrates). Under these conditions, the contents of palmitic acid (PA) and PA at sn-2 position (sn-2 PA) were 29.7 and 62.8%, respectively, and other observed FM were all within the range of FM of HMF. The product was evaluated by the cited model, and a high score (85.8) was obtained, which indicated a high degree of similarity of the product to HMF.

作者

我是这篇论文的作者
点击您的名字以认领此论文并将其添加到您的个人资料中。

评论

主要评分

4.7
评分不足

次要评分

新颖性
-
重要性
-
科学严谨性
-
评价这篇论文

推荐

Review Food Science & Technology

New insights into food O/W emulsion gels: Strategies of reinforcing mechanical properties and outlook of being applied to food 3D printing

Xueqing Li, Liuping Fan, Yuanfa Liu, Jinwei Li

Summary: This article discusses the application potential of food emulsion gels in food 3D printing and the issue of their mechanical properties. Four strategies for improving the mechanical properties of emulsion gels are summarized, including internal reinforcement and external reinforcement.

CRITICAL REVIEWS IN FOOD SCIENCE AND NUTRITION (2023)

Review Food Science & Technology

Recent advances on food-grade water-in-oil emulsions: Instability mechanism, fabrication, characterization, application, and research trends

Xin Hong, Qiaoli Zhao, Yuanfa Liu, Jinwei Li

Summary: This review provides an overview of the fundamentals and applications of water-in-oil (W/O) emulsions, discussing the challenges in achieving long-term stability and the use of natural stabilizers. The review also proposes promising research trends for W/O emulsions, including the development of high internal phase emulsions (HIPEs) and the search for novel plant-derived stabilizers.

CRITICAL REVIEWS IN FOOD SCIENCE AND NUTRITION (2023)

Article Chemistry, Physical

In vitro applicability of mixed soy lecithin-based liposomes with added several lipophilic agents as novel delivery systems for delivery of quercetin

Sahar Pakbaten Toopkanloo, Tai Boon Tan, Ling-Zhi Cheong, Yuanfa Liu, Chin Ping Tan

Summary: This study evaluated the physical and constitutional changes of liposomes based on mixed soy lecithin by using highly lipophilic compounds. The bio-accessibility of quercetin-loaded liposomes was examined in vitro, and the effects of particle size, polydispersity index, zeta potential, membrane stabilizers, membrane fluidity, and encapsulation efficacy were investigated. The results showed that different membrane additives had a significant impact on the micellization of quercetin in the gastrointestinal tract. The bio-accessibility of quercetin strongly depended on its retention in the liposomal bilayer and the entrapment capacity of the system.

JOURNAL OF DISPERSION SCIENCE AND TECHNOLOGY (2023)

Review Food Science & Technology

Metabolomics identify landscape of food sensory properties

Nanxi Shu, Xiaoying Chen, Xian Sun, Xinyu Cao, Yuanfa Liu, Yong-Jiang Xu

Summary: Sensory evaluation is a crucial part of food production strategy, but the traditional methods are time-consuming and subjective. Metabolomics, as an emerging technology, offers a promising approach for sensory evaluation by providing comprehensive chemical composition information and revealing changes and functions in food sensory properties.

CRITICAL REVIEWS IN FOOD SCIENCE AND NUTRITION (2023)

Article Chemistry, Applied

Migration of gallic acid from the aqueous phase to the oil-water interface using pea protein to improve the physicochemical stability of water-in-oil emulsions

Mi Zhang, Liuping Fan, Yuanfa Liu, Jinwei Li

Summary: The objective of this study was to effectively migrate gallic acid (GA) to the oil-water interface and inhibit lipid oxidation in water-in-oil (W/O) emulsions. The conjugate of GA and a natural emulsifier (pea protein isolate, PPI) showed superior binding efficiency and stability. The conjugate exhibited enhanced functional properties, including antioxidant and interfacial properties. It also improved the physical stability and oxidative stability of the W/O emulsion. These findings have important implications for interface engineering and improving the oxidative stability of W/O emulsions.

FOOD HYDROCOLLOIDS (2023)

Article Chemistry, Applied

Mayonnaise-like high internal phase Pickering emulsions stabilized by co-assembled phosphorylated perilla protein isolate and chitosan for extrusion 3D printing application

Qiaoli Zhao, Liuping Fan, Yuanfa Liu, Jinwei Li

Summary: The study explored the feasibility of preparing mayonnaise-like high internal phase Pickering emulsions (HIPPEs) using phosphorylated perilla protein isolate-chitosan composite nanoparticles (LZPI-CS CNPs) as inks for 3D printing and delivery vehicles for lipid-soluble 8-carotene. Incorporating chitosan into LZPI-CS CNPs significantly enhanced the stability and controllability of HIPPEs during 3D printing, while also improving the stability of encapsulated 8-carotene. This complexation strategy provides a promising approach for constructing HIPPEs as inks and delivery vehicles for hydrophobic bioactive components.

FOOD HYDROCOLLOIDS (2023)

Article Chemistry, Applied

Freeze-thaw stability and rheological properties of high internal phase emulsions stabilized by phosphorylated perilla protein isolate: Effect of tea saponin concentration

Qiaoli Zhao, Xin Hong, Liuping Fan, Yuanfa Liu, Jinwei Li

Summary: This study investigated the interfacial behavior of phosphorylated perilla protein isolate and tea saponin in high internal phase emulsions, and found that the concentration of tea saponin played a crucial role in the performance and stability of the emulsions.

FOOD HYDROCOLLOIDS (2023)

Review Food Science & Technology

Polyphenolic compounds from rapeseeds (Brassica napus L.): The major types, biofunctional roles, bioavailability, and the influences of rapeseed oil processing technologies on the content

Zhan Ye, Yuanfa Liu

Summary: This article reviews the major types and biofunctional roles of rapeseed polyphenols, as well as the influence of rapeseed oil processing technologies on these polyphenols. Future research directions include producing nutritional rapeseed oils with higher levels of polyphenols. Rapeseed polyphenols are classified into phenolic acids and polyphenolic tannins, both of which have various biofunctional roles and beneficial effects on human health. The processing technologies of rapeseed oil significantly affect the polyphenol content and activity, and novel techniques such as aqueous enzymatic extraction and subcritical or supercritical extraction show advantages in producing rapeseed oil with higher polyphenol levels.

FOOD RESEARCH INTERNATIONAL (2023)

Article Biochemistry & Molecular Biology

Sheath-core structured Ca-alginate/PVA aerogel fibers via directed freezing wet-spinning

Fucheng Guan, Zheng Li, Jun Tian, Yihang Zhang, Jianbing Sun, Jing Guo, Yuanfa Liu

Summary: Biomass-based aerogel fibers have been developed using a directed freezing-assisted forced stretching strategy to overcome their disadvantages of low mechanical strength, poor long-range order, and easy combustion. The Ca-alginate/polyvinyl alcohol (Ca-A/PVA) aerogel fibers with long-range-ordered pores exhibit excellent comprehensive mechanical properties. The strategy presented in this study is also applicable to other alginate-based aerogel fibers.

INTERNATIONAL JOURNAL OF BIOLOGICAL MACROMOLECULES (2023)

Article Food Science & Technology

Foodomics Reveals Anti-Obesity Properties of Cannabinoids from Hemp Oil

Ziwen Ding, Fan Jiang, Jiachen Shi, Yanan Wang, Mengxue He, Chin Ping Tan, Yuanfa Liu, Yong-Jiang Xu

Summary: This study developed an MS-MN-based foodomics approach to investigate the composition and anti-obesity activity of cannabinoids in hemp oil. The results showed that cannabinoids can alleviate high glucose-induced increases in lipids and carbohydrates, and decreases in amino acid and nucleic acid. Additionally, they were found to regulate gene expression levels associated with lipid synthesis and kinetism.

MOLECULAR NUTRITION & FOOD RESEARCH (2023)

Article Engineering, Chemical

Effect of Pollutant Species on the Performance of Chelating Membranes for Wastewater Treatment

Miao Xing, Wenwen Zhang, Yuanfa Liu, Jing Guo, Yue Yu

Summary: A chelating membrane was developed for simultaneous removal of metal ions and proteins from simulated wastewater. The membrane exhibited excellent separation performance for a mixture of single ion and protein, with over 90% removal of ions and rejection of proteins (except for Cd2+). Metal ion removal mainly relied on the chelation of amidoxime groups, while protein removal was impacted by the damaging effect of heavy metals. Increasing metal ion content and protein concentration hindered the removal efficiency of each other.

CHEMICAL ENGINEERING & TECHNOLOGY (2023)

Article Chemistry, Applied

Studies on the lipid oxidation and oleosomes behavior in raw pecan kernels during storage

Tian Tian, Farah Zaaboul, Shipeng Yin, Zhan Ye, Yanwen Sun, Jialiang Zhao, Yuanfa Liu

Summary: This study analyzed the oxidative stability of pecan kernels and the behavior of oleosomes during storage. The results showed that the oxidation index of pecan oil increased significantly after 20 days of storage. There was a relationship between the damage of oleosomes in pecans and their oxidative stability. The rupture of oleosomes increased the contact between oil and oxygen, accelerating the oxidation process. Further analysis revealed that the oil content of oleosomes decreased during storage, while their particle size increased significantly. It is likely that the hydrolysis of endogenous proteins, particularly oleosins, caused the rupture of oleosomes. This led to an increase in the content of free fatty acids and oxidized triacylglycerols, while the content of polyunsaturated fatty acids decreased significantly. An in-vitro model confirmed that the rupture of oleosomes resulted in oil leakage and accelerated the oxidation of endogenous oil.

FOOD CHEMISTRY (2023)

Article Food Science & Technology

Tracking the dynamics of epoxy triglycerides during thermal oxidation by liquid chromatography-mass spectrometry

Yu Wang, Xinyu Cao, Jiachen Shi, Xue Li, Yuanfa Liu, Yong-Jiang Xu

Summary: The study identified epoxy triglycerides (ETGs) as the most toxic component in thermally oxidized vegetable oil. A qualitative analysis method using liquid chromatography-mass spectrometry (LC-MS) was developed to track the dynamics of ETGs. The results showed that the generation of ETGs was influenced by heating time, temperature, and the degree of unsaturation of the oil.

FOOD CONTROL (2023)

Article Microbiology

Development of Candida autochthonous starter for cigar fermentation via dissecting the microbiome

Yun Jia, Yuanfa Liu, Wanrong Hu, Wen Cai, Zhaojun Zheng, Cheng Luo, Dongliang Li

Summary: This study used high-throughput sequencing and correlation analysis to examine the microbial community structure and metabolic functions during the fermentation of cigar tobacco leaves. It found that Staphylococcus and Aspergillus were the dominant bacteria and fungi, respectively, during the fermentation process. Furthermore, Candida was identified as a critical microbe that contributed to the degradation of nitrogenous substances, synthesis of flavor components, and stability of the microbial community. In vitro isolation and bioaugmentation experiments demonstrated that Candida parapsilosis and Candida metapsilosis could effectively reduce alkaloid content and increase flavor component content in tobacco leaves. This research provides valuable insights for the development of microbial starters and targeted regulation of cigar tobacco quality.

FRONTIERS IN MICROBIOLOGY (2023)

Article Chemistry, Applied

Effects of alkali treatment on structural and functional properties of chickpea protein isolate and its interaction with gallic acid: To improve the physicochemical stability of water-in-oil emulsions

Mi Zhang, Liuping Fan, Yuanfa Liu, Jinwei Li

Summary: Alkali treatment was used to enhance the functional properties of chickpea protein isolate (CPI) and promote its combination with gallic acid (GA), resulting in increased antioxidant activity and improved structural and functional properties. The addition of alkali-treated CPI and CPI-GA combinations to emulsions improved physical stability and chemical stability.

FOOD HYDROCOLLOIDS (2023)

暂无数据