4.5 Article

Improved rate performance of LiNi0.5Mn1.5O4 cathode for lithium ion battery by carbon coating

期刊

IONICS
卷 21, 期 5, 页码 1269-1275

出版社

SPRINGER HEIDELBERG
DOI: 10.1007/s11581-014-1286-x

关键词

Lithium nickel manganese oxide; Carbon coating; Phenolic resin; Lithium ion battery

资金

  1. National Natural Science Foundation of China [U1134002, 21273084]
  2. Natural Science Foundation of Guangdong Province [U1134002, 10351063101000001]
  3. Science and Technology in Guangdong Province [2012A010702003]
  4. Department of Education of Guangdong Province [2013CXZDA013]

向作者/读者索取更多资源

Carbon-coated LiNi0.5Mn1.5O4 cathode was prepared using phenolic resin as a carbon precursor. The morphology and structure of the prepared samples were characterized by powder X-ray diffraction, scanning electron microscopy, transmission electron microscopy, and thermogravimetry, and its performance as cathode of lithium ion battery was investigated by electrochemical impedance spectroscopy and charge-discharge test. The results showed that the carbon coating with phenolic resin as precursor could obviously promote the discharge capacity of LiNi0.5Mn1.5O4 cathode, especially at high rate. At 20 C rate, the discharge capacity is 41 mAha (TM) g(-1) for uncoated LiNi0.5Mn1.5O4, while 108 mAha (TM) g(-1) for carbon-coated LiNi0.5Mn1.5O4. The coated sample also exhibited excellent cyclic performance, remaining 95 % of its initial discharge capacity (131 mAha (TM) g(-1)) at 1 C rate after 100 cycles. The interfacial resistance of LiNi0.5Mn1.5O4 with carbon coating was reduced from 90 to 31 Omega.

作者

我是这篇论文的作者
点击您的名字以认领此论文并将其添加到您的个人资料中。

评论

主要评分

4.5
评分不足

次要评分

新颖性
-
重要性
-
科学严谨性
-
评价这篇论文

推荐

Article Engineering, Chemical

Nanoparticle-induced drag reduction for polyacrylamide in turbulent flow with high Reynolds numbers

Xiaoping Li, Jiaxin Pan, Jinwen Shi, Yanlin Chai, Songwei Hu, Qiaorong Han, Yanming Zhang, Xianwen Li, Dengwei Jing

Summary: Despite ongoing research, the use of nanoparticles to enhance the drag reduction performance of polymer drag reducers remains controversial, particularly with regard to the underlying fluid dynamics mechanism. This study investigates the effects of adding SiO2 nanoparticles to various polymer polyacrylamide (PAM) solutions and identifies the optimal combination with cationic polyacrylamide. Results show that the addition of SiO2 nanoparticles efficiently reduces drag at higher flow rates (Reynolds numbers above 6000), but has a negative effect below this range. The dual effects of SiO2 nanoparticles, including increased flow resistance due to Brownian motion and decreased flow resistance by protecting polymer chains under high shear conditions, contribute to the drag reduction performance of polymer drag reducers, particularly at optimal nanoparticle concentrations and higher Reynolds numbers. This research serves as a guide for applications such as natural gas fracturing, where high flow rates are common.

CHINESE JOURNAL OF CHEMICAL ENGINEERING (2023)

Article Geochemistry & Geophysics

A Study of Hypersonic Vehicle-Borne SAR Imaging Under Plasma Sheath

Lihao Song, Bowen Bai, Xiaoping Li, Gezhao Niu, Yanming Liu, Yiding Mao

Summary: Hypersonic vehicle-borne synthetic aperture radar (SAR) imaging has promising application prospects for remote sensing due to its fast response and flexible trajectory. However, the phenomenon of plasma sheath during hypersonic flight has a serious impact on hypersonic vehicle-borne SAR imaging. Therefore, this study systematically investigates the effect of plasma sheath on hypersonic vehicle-borne SAR imaging. Analytical formulas are derived for the phase shift, amplitude attenuation, linear phase errors, and quadratic phase errors, providing insights into the image shift, pulse broadening, submerged point target response, and asymmetric distortion caused by plasma sheath. Quantitative evaluation and analysis of SAR imaging degradation under different conditions are conducted, contributing to the improvement of hypersonic vehicle-borne SAR imaging under plasma sheath in the future.

IEEE TRANSACTIONS ON GEOSCIENCE AND REMOTE SENSING (2023)

Article Physics, Fluids & Plasmas

Polarization Scattering Properties of Inhomogeneous Plasma-Covered Metal Plate

Gezhao Niu, Yanming Liu, Bowen Bai, Yi Ding, Lihao Song, Xiaoping Li

Summary: This article deploys an electromagnetic simulation model of a 3-D inhomogeneous plasma-covered metal plate to study the scattered properties of linear polarization plane waves obliquely incident on the plasma. The effects of plasma parameters and incident angle on the scattered properties are investigated, and the influences of EM wave polarization mode on the polarization properties of the scattered wave are analyzed. The results provide a theoretical basis for research on RCS measurement, polarization matching, and EM stealth of plasma-sheath-covered hypersonic vehicles.

IEEE TRANSACTIONS ON PLASMA SCIENCE (2023)

Article Physics, Fluids & Plasmas

A Radar Detection Method of Reentry Target Based on Frequency-Domain Processing

Yi Ding, Bowen Bai, Gezhao Niu, Xiaoping Li, Yanming Liu

Summary: When the reentry target enters the earth's atmosphere, a plasma sheath forms on its surface. During radar detection, the echo signal couples with different Doppler frequency components, causing mismatches with the matched filter and generating false targets on the range profile. Additionally, the high speed of the reentry target leads to migration through range cells, further impacting detection and recognition. This article proposes an improved frequency-domain compensation method to address false targets and migration, effectively enhancing the detection and tracking of plasma-sheath-covered targets.

IEEE TRANSACTIONS ON PLASMA SCIENCE (2023)

Article Instruments & Instrumentation

Study of plasma parameters in high enthalpy ICP-heated wind tunnel by using single Langmuir probe

Weifeng Deng, Yanming Liu, Rui Li, Jia Zhang, Xiaoping Li, Weimin Bao

Summary: This paper designs a single probe (SP) to study plasma parameters in a high enthalpy ICP-heated wind tunnel. It is discovered that the electron temperature in the core region is about 2.4 eV, while in the edge region it is about 3-4 eV. At the maximum power of the high enthalpy ICP-heated wind tunnel, the electron density reaches 4.34x1013 cm-3. Additionally, the line integral density measured by SP is found to be 0.8 times higher than that measured by the HCN interferometer, indicating a consistent trend between the probe diagnosis and the laser diagnosis results.

JOURNAL OF INSTRUMENTATION (2023)

Article Engineering, Aerospace

High-dynamic intelligent maneuvering guidance strategy via deep reinforcement learning

Sibo Zhao, Jianwen Zhu, Weimin Bao, Xiaoping Li

Summary: This manuscript presents a three-dimensional high-dynamic intelligent maneuvering guidance strategy based on optimal control and deep reinforcement learning (DRL) to address the coordination between maneuvering penetration and high-precision guidance in complex flight missions of high-velocity vehicle. The strategy utilizes a longitudinal maneuvering model with instantaneous miss distance as a control variable and employs the maximum value principle to obtain the optimal maneuver duration and start timing. In the lateral direction, a Markov decision process model is proposed to synthesize guidance error and miss distance and a reward function is designed considering maneuver and guidance performance. The simulation results demonstrate that the intelligent maneuvering guidance strategy can improve penetration performance, reduce the influence of maneuver flight on guidance accuracy, and ensure adaptability under changeable flight missions.

PROCEEDINGS OF THE INSTITUTION OF MECHANICAL ENGINEERS PART G-JOURNAL OF AEROSPACE ENGINEERING (2023)

Article Chemistry, Analytical

Wideband RCS Reduction Based on Hybrid Checkerboard Metasurface

Zhiming Zhao, Xiaoping Li, Guoxiang Dong

Summary: Traditional stealth technologies have problems of high cost and large thickness, which can be solved by using novelty checkerboard metasurface in stealth technology. The hybrid checkerboard metasurface with two types of polarization converter units arranged in turn can effectively reduce radar cross-section (RCS) and be insensitive to the polarization of incoming EM waves. The experiment and simulation results prove the effectiveness of mutual compensation in the field of checkerboard metasurfaces for stealth technology.

SENSORS (2023)

Review Biotechnology & Applied Microbiology

Mesenchymal and Neural Stem Cell-Derived Exosomes in Treating Alzheimer's Disease

Hongmin Wang, Christa C. C. Huber, Xiao-Ping Li

Summary: Alzheimer's disease (AD) is a common form of dementia, affecting over 10% of the population aged 65 and older. AD is characterized by progressive loss of neurons and synapses, formation of amyloid plaques and neurofibrillary tangles, neuroinflammation, blood-brain barrier breakdown, mitochondrial dysfunction, and oxidative stress. Stem cell-derived exosomes show promise in treating AD as they possess anti-apoptotic, anti-inflammatory, and antioxidant properties. These exosomes also promote neurogenesis, angiogenesis, and BBB repair. This review discusses the neuropathological features of AD and explores the use of stem cell-derived exosomes in AD therapy.

BIOENGINEERING-BASEL (2023)

Article Engineering, Aerospace

Estimating 5-year rotation stability of PSR B1937+21 using NICER observations

Haifeng Sun, Dingkai Yao, Lirong Shen, Zhongwen Deng, Weiming Bao, Xiaoping Li, Wencong Wang, Qingyong Zhou

Summary: Using observations of millisecond pulsars, this study compares the 5-year rotation stability between X-ray data from NICER and radio data from NANOGrav. The analysis includes data screening, parameter fitting, and consideration of factors affecting pulsar rotation stability. The results show that the rotation stability of PSR B1937 + 21 based on NICER observations is comparable to NANOGrav data, with an accuracy of 1.7 x 10-14.

ACTA ASTRONAUTICA (2023)

Article Engineering, Chemical

Three-phase contact line confined dense nanoparticle array for high-capacity DNA synthesis

Xiao Su, Xiaoping Li, Yi Zhang, Qing Guo, Xingguo Zhang, Haixia Yu, Dachao Li

Summary: This paper presents a simple and cost-effective method for fabricating a microreactor array chip that enables high-throughput DNA synthesis with a three orders of magnitude enhancement in synthesis capacity. The chip is made by inkjet printing a massive droplet array of silica nanoparticle slurry on a chemically-modified surface. The dense microreactor array is obtained through the three-phase contact line (TCL)-confined nanoparticle aggregating process, controlled by the receding contact angle (RCA) of the modified substrates. The proposed microarray chip shows great potential for high-throughput and high-capacity DNA synthesis.

CHEMICAL ENGINEERING SCIENCE (2023)

Article Engineering, Electrical & Electronic

A New Method of Antenna Height Reduction Based on Half-Sized Full-Wave Dipole

He Huang, Xiaoping Li, Shizhong Liu, Yanming Liu

Summary: This article introduces a new strategy to reduce antenna height. The basic idea is to replace the half-wave dipole with a full-wave dipole to maintain a large input impedance. By adjusting the position and rotation of the arms, a half-sized dipole with an input impedance of 50Ω is obtained. The improved structure allows for wideband applications and expansion into a dual-polarized subarray with a height of only 0.08λ.

IEEE TRANSACTIONS ON ANTENNAS AND PROPAGATION (2023)

Article Physics, Fluids & Plasmas

Three-dimensional reconstruction of the emission field of the inductively coupled plasma jet

Fei Ding, Yanming Liu, Jing Jia, Xiaoping Li, Jiaxin Li, Yingxin Zhao, Rui Li

Summary: This paper studied how to reconstruct the 3D emission field of the inductively coupled plasma (ICP) jet and proposed a multiscale calculation method to reduce the size of the weight matrix. A 3D reconstruction system was eventually established, which demonstrated the non-uniform structure of the ICP jet. The re-projection error of the reconstructed ICP jet verified the high reconstruction accuracy of the proposed method.

PHYSICS OF PLASMAS (2023)

Article Engineering, Electrical & Electronic

Improving Spatial Resolution of GRACE-Derived Water Storage Changes Based on Geographically Weighted Regression Downscaled Model

Zhiwei Chen, Wei Zheng, Wenjie Yin, Xiaoping Li, Meihong Ma

Summary: In order to rationalize the utilization of water resources, it is important to obtain high-resolution products that can accurately estimate the spatiotemporal changes in regional water resources. This study proposes a geographically weighted regression downscaled model (GWRDM) to improve the spatial resolution of terrestrial water storage (TWS) products obtained from the GRACE satellite. The results show that the downscaled TWS based on GWRDM outperforms other downscaled models, and the downscaled groundwater storage (GWS) based on GWRDM agrees well with in situ observations. Therefore, GWRDM provides a practical algorithm for obtaining high-resolution water storage estimates and contributes to small-scale regional water resources management.

IEEE JOURNAL OF SELECTED TOPICS IN APPLIED EARTH OBSERVATIONS AND REMOTE SENSING (2023)

Article Engineering, Aerospace

Grouping bi-chi-squared method for pulsar navigation experiment using observations of Rossi X-ray timing explorer

Haifeng Sun, Jianyu Su, Zhongwen Deng, Lirong Shen, Weimin Bao, Xiaoping LI, Liansheng LI, Zhe Su, Wencong Wang

Summary: X-ray pulsar-based navigation technology provides necessary navigation information in the solar system, with SEPO technique estimating orbital elements and optimizing positioning and velocity accuracy through high-flux observations.

CHINESE JOURNAL OF AERONAUTICS (2023)

Article Green & Sustainable Science & Technology

Tensile Properties and Wear Resistance of Mg Alloy Containing High Si as Implant Materials

Mengqi Cong, Yang Zhang, Yunlong Zhang, Xiao Liu, Yalin Lu, Xiaoping Li

Summary: Magnesium alloy is considered as a promising biomaterial for bone regeneration. In this study, a Mg-6Zn-4Si alloy reinforced with in-situ Mg2Si phase and yttrium (Y) addition was comprehensively investigated. The primary and eutectic Mg2Si phases were significantly modified by the Y addition, leading to a reduction in primary phase size to around 20 μm. The wear resistance and tensile properties of the Mg-Zn-Si alloy were improved by the addition of 0.5 wt.% Y, with 50% higher ultimate tensile strength and 65% higher elongation compared to the ternary alloy. Excessive Y addition (1.0 wt.%) deteriorated the tensile properties. This improvement can be attributed to the modification of Mg2Si phases and solid solution strengthening of Y atoms. This study provides implications for the application of Y-containing Mg-Zn-Si alloys as regeneration implants.

JOURNAL OF RENEWABLE MATERIALS (2023)

暂无数据