Article
Chemistry, Physical
Zehao Zhang, Xiang Liu, Youjun Lu, Haibo Li
Summary: This work proposes a facile covalent self-assemble strategy to prepare the ZrN@rGO composite for enhanced LIB. The results show that a strong Zr-C covalent bond is formed between ZrN and rGO, and electron transfer promotes charge density at the ZrN@rGO heterointerface. The volume change of ZrN can be effectively alleviated by coupling with rGO, leading to a high specific capacity in the lithium-ion battery.
JOURNAL OF ALLOYS AND COMPOUNDS
(2023)
Article
Materials Science, Multidisciplinary
Zhaolin Li, Yaozong Yang, Jie Wang, Zhao Yang, Hailei Zhao
Summary: Silicon suboxide (SiOx) is a potential anode material for high-energy-density lithium ion batteries, but its electrochemical performance is hindered by mechanical instability due to volume variation. In this study, a sandwich-like structure is proposed, where SiOx nanoparticles are sandwiched between graphene sheets and amorphous carbon layer, improving the structural stability. The resulting C/SiOx@graphene material exhibits excellent cyclic performance and rate capability, offering a novel strategy to enhance the stability of high-capacity anode materials for lithium/sodium ion batteries.
INTERNATIONAL JOURNAL OF MINERALS METALLURGY AND MATERIALS
(2022)
Article
Chemistry, Physical
Chen Bai, Yefeng Feng, Jin Ke, Kaidan Wu, Miao He
Summary: In this study, the SnO2@ZrO2/C composite material was successfully prepared through a hydrothermal method and highspeed ball milling, showing desirable cycle stability and high reversible capacity. Graphite nanosheets effectively alleviate the volume expansion of nanoparticles and prevent agglomeration to maintain the structural stability of the electrode.
CHEMICAL PHYSICS LETTERS
(2021)
Article
Chemistry, Physical
Guangxiang Zhang, Yongming Zhu, Shizhong Lv, Zhen Wang, Peng Gao
Summary: The electrochemical performance of LiNiO2 is significantly improved by preoxidation of the precursor with potassium peroxydisulfate in an alkaline medium. The optimized oxidation time is 30 minutes, resulting in denser and more ordered surface structure of LiNiO2 particles. The initial discharge capacity and capacity retention rate of N30 LiNiO2 are greatly enhanced compared to the original LiNiO2.
JOURNAL OF ALLOYS AND COMPOUNDS
(2023)
Article
Nanoscience & Nanotechnology
Yuan Zhang, Jiahao Xu, Shaoxiong Fu, Yuhan Bian, Yaping Wang, Li Wang, Guangchuan Liang
Summary: A series of Li2SiO3-coated LiNi0.5Mn1.5O4 materials were prepared to alleviate rapid capacity decay. The coating thickness was controlled by adjusting the amount of TEOS and lithium acetate. The material with an appropriate thickness exhibited improved structural and electrochemical properties, including larger primary particle size and reduced secondary particle agglomeration, enhanced Li+ ion diffusion kinetics, suppressed side reactions and CEI growth, and reduced electrode corrosion and transition metal ion dissolution through interaction with HF.
ACS APPLIED MATERIALS & INTERFACES
(2023)
Article
Chemistry, Physical
Fangqi Tang, Tingting Jiang, Yu Tan, Xinyi Xu, Yingke Zhou
Summary: Silicon/graphene composites have attracted increasing attention as promising negative electrode materials for lithium-ion batteries, showing excellent electrochemical performance and cycle stability. Silicon offers high specific charge capacity, while graphene provides good electrical conductivity and space for silicon expansion, resulting in stable electrode material.
JOURNAL OF ALLOYS AND COMPOUNDS
(2021)
Article
Energy & Fuels
Eyyup Aslan, Yusuf Aydin, Yusuf Yasa
Summary: Graphene additive has a positive impact on the thermal conductivity of PCM, especially when applied in specific structures, it can significantly improve the heat transfer performance of batteries. In addition, by establishing a thermal equivalent circuit model, it is possible to accurately control the battery temperature and analyze temperature variations under different charge-discharge scenarios.
INTERNATIONAL JOURNAL OF ENERGY RESEARCH
(2022)
Article
Biochemistry & Molecular Biology
Ruye Cong, Hyun-Ho Park, Minsang Jo, Hochun Lee, Chang-Seop Lee
Summary: The self-assembly synthesis of silicon nanoparticles@nitrogen-doped reduced graphene oxide/carbon nanofiber composites optimizes the electrode structure for improved lithium-ion battery performance. Nitrogen atoms generate vacancies on the graphite plane, providing transmission channels for Li+ and enhancing electrode conductivity, while carbon nanofibers maintain electrode stability and prevent silicon detachment.
Article
Chemistry, Physical
Zhaolin Li, Hailei Zhao, Xin Tao, Yaozong Yang, Jie Wang, Zhao Yang
Summary: In this study, a graphene-modified lithium silicate (LS) nanodots decorated SiOx-C material was prepared using a sol-gel approach and subsequent heat treatment. The material exhibited fast Li-ion and electron transport, enhancing the electrode reaction kinetics of SiOx. The highly-conductive network of graphene also mitigated the structural stress of SiOx, resulting in excellent structural durability. The electrode showed a reversible capacity of 400 mAh g-1 at 0.5 A g-1 for 200 cycles without obvious capacity degradation.
JOURNAL OF ALLOYS AND COMPOUNDS
(2022)
Article
Chemistry, Physical
Memona Idrees, Ahmed S. Haidyrah, Ata-ur-Rehman, Qin Zhang, Xuanke Li, Syed Mustansar Abbas
Summary: Fe2N decorated on reduced graphene oxide (rGO) prepared by a hydrothermal reaction showed promising lithium-ion battery performance, with higher capacity and lower capacity fading rate. The conductive graphene network facilitated charge transfer reactions, while mesoporous Fe2N aided in electrolyte penetration and intercalation/deintercalation.
JOURNAL OF ALLOYS AND COMPOUNDS
(2021)
Article
Chemistry, Physical
Siliang Chang, Shuai Han, Sen Ji, Shanshan Liu, Ye Liu, Xin Yang, Kai Feng, Jianjiang Hu
Summary: Niobium-based anode materials show promise for use in lithium-ion batteries due to their high specific capacity and safety. However, their low electronic conductivity limits their performance. In this study, a mixed-valent niobium-based phosphate, K3Nb6P4O26@C, was developed as an anode material. The mixed-valent Nb in KNPO enables multi-electron reactions and higher electronic conductivity. The 3D channels in the crystal structure of KNPO facilitate rapid lithium-ion transport. KNPO@C anode demonstrates a high specific capacity and excellent cycling stability, making it a potential practical material for high-performance LIBs.
JOURNAL OF ALLOYS AND COMPOUNDS
(2023)
Article
Chemistry, Physical
Jun Hui Jeong, Min O. Ju, Kwang Chul Roh
Summary: In this study, the correlation between lithium-ion accessibility and low-temperature electrochemical properties of electrode materials was systematically investigated. Increasing the density of in-plane defects in holey graphene improved the electrochemical performance of Li4Ti5O12/holey graphene composites at low temperatures. The results suggest that improving lithium-ion accessibility to the electrolyte-active material interface is crucial for enhancing electrochemical properties at low operating temperatures.
JOURNAL OF ALLOYS AND COMPOUNDS
(2021)
Article
Chemistry, Multidisciplinary
Xinghua Liang, Yujuan Ning, Linxiao Lan, Guanhua Yang, Minghua Li, Shufang Tang, Jianling Huang
Summary: In this study, a PVDF-HFP-LiClO4-LLZTO composite solid electrolyte was prepared using the solution pouring method, which showed excellent electrochemical performance in the temperature range of 30 to 60 degrees C. This work provides an effective strategy for the design and preparation of solid-state lithium-ion batteries.
Article
Chemistry, Physical
Yang Liu, Cai Qi, Dandan Cai, Xiao Tang, Ying Li, Wenxian Li, Qinsi Shao, Jiujun Zhang
Summary: The development of electrode materials with high capacity and rate capability is necessary for improving the energy density and cycle life of lithium-ion batteries (LIBs). In this study, a cathode material, LiFePO4/C, modified with high electrical conductivity compound tantalum carbide (TaC), was successfully synthesized via hydrothermal method. The co-coating of nano-sized TaC and amorphous carbon layer on the surface of LiFePO4 particles allows for efficient electron and Li ion transfer, resulting in improved electrochemical kinetics. As a cathode material for LIBs, this composite demonstrates excellent electrochemical performances with high reversible capacity (159.0 mAh g(-1), 0.1C) and improved rate capacity. This methodology provides a new prospect for the application of transition metal carbides (TMCs) in modifying battery electrode materials.
Article
Chemistry, Multidisciplinary
Mansoureh Nematzadeh, Mahya Nangir, Abouzar Massoudi, Xiaobo Ji, Ali Khanlarkhani, Jozsef Toth
Summary: This study investigates the electrochemical performance of nitrogen-doped graphene/silicene composite. The results suggest that nitrogen doping can enhance the performance of silicene as an anode for lithium-ion batteries. The pyrrolic and graphitic sites in the composite play different roles in facilitating the diffusion and kinetics of Li+ ions.
Article
Materials Science, Multidisciplinary
Deyong Zheng, Huihui Jin, Yucong Liao, Pengxia Ji
Summary: In this study, a highly stable and efficient catalyst, fluorine-doped Co3O4 (F-Co3O4), was developed for hydrogen production by water electrolysis. The F-Co3O4 catalyst exhibited a remarkable reduction in overpotential and demonstrated excellent stability for over 100 hours.
Article
Materials Science, Multidisciplinary
Ziwen Lv, Jintao Wang, Fengyi Wang, Jianqiang Wang, Fuquan Li, Hongtao Chen
Summary: Adding Cu6Sn5 nano particles can effectively inhibit the overgrowth of intermetallic compounds at the interfaces of solder joints in electronic devices, providing a solution to this issue. A new growth mechanism of intermetallic compounds at the interfaces was identified.
Article
Materials Science, Multidisciplinary
Jun Wang, Jiawei Chen, Wanru Liao, Fangyang Liu, Min Liu, Liangxing Jiang
Summary: A BiOI/AgI/Ag plasmonic heterostructure photocathode was successfully designed through electrodeposition, ion-exchange, and illumination methods. This photocathode exhibits superior performance in photoelectrochemical water splitting.
Article
Materials Science, Multidisciplinary
Xiaoxiao Liu, Xianxian Zhou, Xiaotao Ma, Qinbo Yuan, Shibin Liu
Summary: In this study, the authors propose a method to accelerate the reaction of polysulfides in lithium-sulfur batteries using a Ni@OC Mott-Schottky heterojunction as a catalyst. The experimental results demonstrate that the charge redistribution at the Ni@OC interface accelerates electron transfer and enhances catalytic activity, leading to improved reaction kinetics and battery performance.
Article
Materials Science, Multidisciplinary
Dayou Ma, Mohammad Rezasefat, Joziel Aparecido da Cruz, Sandro Campos Amico, Marco Giglio, Andrea Manes
Summary: The matrix has a significant effect on the impact resistance of composite materials. Replacing a brittle polymer with a more flexible one can improve impact resistance, but it poses challenges to standard testing methods. This study designs a new fixture for testing the low-velocity impact of soft composites and investigates the effect of the fixture on the mechanical performance.
Article
Materials Science, Multidisciplinary
Lingchang Wang, Qihang Yang, Huzhen Li, Ming Wei, Qian Wang, Zhenzhong Hu, Mengmeng Zhen
Summary: Bronze titanium dioxide (TiO2(B)) is a promising anode material for lithium-ion batteries due to its high specific capacity. However, its practical applications are hindered by poor conductivity and limited electrochemical kinetics. In this study, TiO2(B)-carbon nanosheets heterostructures are synthesized to enhance the cycling performance and rate capability of TiO2(B).
Article
Materials Science, Multidisciplinary
Atul Thakur, Ritesh Verma, Ankush Chauhan, Fayu Wan, Preeti Thakur
Summary: In this study, BaFe12O19 and BaFe12O19: Epoxy (50:50) nanocomposites were synthesized using the co-precipitation method. The structural information and material properties, such as crystallite size and electrical conductivity, were characterized by XRD, FESEM, EDX, and TEM techniques.
Article
Materials Science, Multidisciplinary
Jingyu Wu, Xinyan Ma, Yong Yang
Summary: A well-defined CoS2@NC(CS-500) hierarchical binder-free catalyst cathode is constructed through in-situ grown of ZIF-67 on carbon cloth and high-temperature carbonization. The cathode shows excellent reaction kinetics and electrochemical performance, providing inspiration for developing advanced Li-CO2 battery catalysts.
Article
Materials Science, Multidisciplinary
Svetlana M. Posokhova, Vladimir A. Morozov, Kirill N. Boldyrev, Dina Deyneko, Erzhena T. Pavlova, Bogdan I. Lazoryak
Summary: This study explores the impact of synthesis method and composition on the structure and luminescence properties of K5Eu1-xHox(MoO4)4 with the palmierite-type matrix. The co-doping of Eu3+ and Ho3+ ions plays a critical role in manipulating charge transfer and luminescence efficiency in the visible and infrared regions.
Article
Materials Science, Multidisciplinary
Jian Wang, Yeting Tao, Jingsheng Wang, Youtian Tao
Summary: A new electron-transport material iTPyBI-CN is developed through non-catalytic C-N coupling reaction. It exhibits better electroluminescence efficiency in organic light-emitting diodes compared to the commercial material TPBI, due to its twisted geometry and higher energy levels.
Article
Materials Science, Multidisciplinary
Tao Zhu, Feng Huang, Shuo Li, Yang Zhou
Summary: This article combines XRD analysis and microscopic structural observation to investigate the changes in limestone after high-temperature treatment. It finds that 500 degrees C is the critical temperature for crystalline and spatial arrangement changes in limestone, and the thermal conductivity, specific heat capacity, and heat storage coefficient gradually decrease after thermal treatment.
Article
Materials Science, Multidisciplinary
Muhammad Haekal Habibie, Fransiska Sri Herwahyu Krismastuti, Abdi Wira Septama, Faiza Maryani, Vivi Fauzia
Summary: This study focuses on the synthesis of zinc oxide nanostructure from zinc recovered from galvanization ash and highlights its potential as a sustainable source of zinc and as an antibacterial agent.
Article
Materials Science, Multidisciplinary
Jingyi Li, Yixin Xing, Wei Gu, Shousi Lu
Summary: In this study, PC@CaP microparticles were fabricated using biomimetic mineralization. The results showed that under environmental stress, PC@CaP exhibited improved stability and antioxidative activity, indicating its potential use in high-added value fields.
Article
Materials Science, Multidisciplinary
Yan Liu, Shunyou Chen
Summary: In this study, TNTs were used as a drug carrier and modified with ZIF-8 and silk fibroin to obtain a new drug loading platform. The results showed that this drug-loaded platform had a good drug release effect in vitro and could promote cell proliferation and osteogenic differentiation.
Article
Materials Science, Multidisciplinary
Chunhui Zhu, Wentao Wang, Qing Zhen, Xinning Huang, Shixin Li, Shaochang Wang, Xiaoping Ma, Xiaoxia Liu, Yalong Jiao, Kai Sun, Zhuangzhi Li, Huaixin Yang, Jianqi Li
Summary: A type of stacking fault is revealed in e-InSe crystal, which is associated with a small stacking-fault energy and shows exceptional plasticity.