Phase separation in pre-ceramic polymers blends and its influence on the microstructure of ZrC/SiC ceramic derivatives

Ultra-high temperature ceramics (UHTCs) composed of ZrC and SiC were fabricated via pyrolysis of hybrid polymeric precursors comprising of polycarbosilane (PCS) and polyzirconobutanediol (PZC). Phase separation in these polymers blends during different removal methods of toluene solution by freezing drying, vacuum drying and rotary evaporation was studied. Elements and phase distribution as well as molecular aggregation state in the hybrid polymeric precursors and the pyrolyzed composite ceramics were characterized with AFM and SEM. It was found that macromolecules of pre-ceramic polymers aggregated spontaneously in the hybrid precursor solution and formed molecular clusters within dozens of nanometers, and the resultant phase separation during removal of toluene solution exhibits strongly impact on the microstructure of the derived UHTCs after being pyrolyzed at temperature above 1000 degrees C which was controlled by solvent removing time. (C) 2015 Elsevier B.V. All rights reserved.