Effect of ruthenium addition to palladium-rhodium nanoalloys on their catalytic performance in CO oxidation

作者

Pavel Plyusnin¹ , Yury Shubin¹ , Igor Asanov¹ , Roman Kenzhin² , Vladimir Stoyanovskii² , Aleksey Vedyagin²

1. Nikolaev Institute of Inorganic Chemistry SB RAS, Novosibirsk, Russia
2. Boreskov Institute of Catalysis SB RAS, Novosibirsk, Russia

会议/活动

8th Asian Symposium on Advanced Materials ASAM-8, July 2023 (Novosibirsk, Russian Federation), July 2023 (Novosibirsk, Russian Federation)

海报摘要

In the present work, alumina-supported trimetallic catalysts containing Rh, Ru and Pd in their composition were synthesized and studied in comparison with bimetallic Pd-Rh/Al2O3 reference sample. The starting compounds were solid solutions of double complex salts of corresponding metals synthesized by known procedures. The single phase of the synthesized complexes was confirmed by X-ray diffraction analysis. The synchronous thermal analysis method was applied to investigate the process of thermolysis of synthesized DCS in both reducing and oxidizing atmospheres. It has been found that in the process of thermal decomposition, it is possible to obtain alloy nanoscale trimetallic (Rh-Ru-Pd) particles of a given composition anchored on the surface of an oxide support. The activity and stability of the catalyst compositions obtained were examined in CO oxidation reaction carried out under prompt thermal aging conditions.

关键词

Rhodium, Palladium, Ruthenium, Nanoalloys, Three-way catalysts

研究领域

Chemistry

参考文献

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基金

1. Ministry of Science and Higher Education (No. 121031700315-2)

补充材料

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附加信息

利益冲突

No competing interests were disclosed.

数据可用性声明

The datasets generated during and / or analyzed during the current study are available from the corresponding author on reasonable request.

知识共享许可协议

Copyright © 2023 Plyusnin et al. This is an open access work distributed under the terms of the Creative Commons Attribution License, which permits unrestricted use, distribution, and reproduction in any medium, provided the original work is properly cited.