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Silica immobilized Brønsted-Lewis acidic ionic liquid: heterogeneous catalyst for condensation-aromatization in the synthesis of 2-(4-nitrophenyl)-1H-benzimidazole by cooperative catalysis
发表日期 March 21, 2023 (DOI: https://doi.org/10.54985/peeref.2303p6889123)
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作者
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Rahul Kalel1
- Padmabhushan Dr. Vasantraodada Patil Mahavidhyalaya, Tasgaon, Sangli
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会议/活动
- Third International Conference on Multidiscipilinary Approach In Basic and Applied Science (MABAS-2023), February 2023 (Sangli, India)
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海报摘要
- The silica immobilized 1-methyl-3-(4-sulphobutyl) -1H imidazolium tetrachloroaluminate has been synthesised as a heterogeneous catalyst. The catalyst has been confirmed by several characterizations such as IR, SEM-EDX, TGA and DTA. The formed catalyst effectively catalyzed the condensation aromatization reactions between orthophenylene diaminobenzene (OPD) and 4-nitrobenzaldehyde. The catalyst has been the efficient and green catalyst for the low reaction time, room temperature and non-hazardous solvents contained synthesis of benzimidazoles. Further, the turnover frequency decreases with increases in the polarity of the reaction medium recommending the participation of a different kind of mechanism. The optimum reaction condition, simplicity of catalyst preparation and characterization method and reusability reveal the efficiency of Si-BLAIL as a cooperative catalyst.
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关键词
- Heterogeneous catalyst, Equivalence point, Cooperative catalysis, BLAIL, SEM
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研究领域
- Chemistry, Chemical Engineering
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参考文献
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- J Indian Chem Soc 2022, 99:100550
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基金
- 暂无数据
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补充材料
- 暂无数据
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附加信息
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- 利益冲突
- No competing interests were disclosed.
- 数据可用性声明
- Data sharing not applicable to this poster as no datasets were generated or analyzed during the current study.
- 知识共享许可协议
- Copyright © 2023 Kalel. This is an open access work distributed under the terms of the Creative Commons Attribution License, which permits unrestricted use, distribution, and reproduction in any medium, provided the original work is properly cited.
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引用
Kalel, R. Silica immobilized Brønsted-Lewis acidic ionic liquid: heterogeneous catalyst for condensation-aromatization in the synthesis of 2-(4-nitrophenyl)-1H-benzimidazole by cooperative catalysis [not peer reviewed]. Peeref 2023 (poster).
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